Process for the simultaneous preparation of aromatic acid chlorides and
aliphatic acid chlorides
    4.
    发明授权
    Process for the simultaneous preparation of aromatic acid chlorides and aliphatic acid chlorides 失效
    同时制备芳香族酰氯和脂族酰氯的方法

    公开(公告)号:US4163753A

    公开(公告)日:1979-08-07

    申请号:US768330

    申请日:1977-02-14

    CPC classification number: C07C51/60 C07C51/58 C07C51/64

    Abstract: By reacting an aromatic compound containing at least one trichloromethyl group bonded to an aromatic carbon atom with an aliphatic acid anhydride in the presence of a catalyst, an aromatic acid chloride and an alkyl carboxylic acid chloride are produced. The desirable products are preferably obtained through distillation at ambient conditions. Although various catalysts can be employed, an acid catalyst, such as sulphuric acid is preferred.

    Abstract translation: 通过在催化剂存在下使包含至少一个与芳族碳原子键合的三氯甲基的芳族化合物与脂族酸酐反应,生成芳族酰氯和烷基酰氯。 优选的产物优选通过在环境条件下蒸馏获得。 尽管可以使用各种催化剂,但优选酸催化剂,例如硫酸。

    Production of alpha-chlorocarboxylic acid chlorides
    5.
    发明授权
    Production of alpha-chlorocarboxylic acid chlorides 失效
    生产α-氯代羧酸氯化物

    公开(公告)号:US3880923A

    公开(公告)日:1975-04-29

    申请号:US42637273

    申请日:1973-12-19

    Applicant: BASF AG

    CPC classification number: C07C51/62 C07C53/48

    Abstract: An improved process for the production of Alpha chlorocarboxylic acid chlorides by reaction of a carboxylic acid chloride with chlorine at elevated temperature, wherein the improvement consists in carrying out the reaction in the presence of sulfuric acid. Alpha -chlorocarboxylic acid chlorides are suitable for the production of plant protection agents.

    Abstract translation: 通过羧酸酰氯与氯在升高的温度下反应制备α-氯代羧酸氯化物的改进方法,其中改进在于在硫酸存在下进行反应。 α-氯代羧酸氯化物适用于生产植物保护剂。

    2-(n-acetyl-n-acetoxyamino) acetyl chloride
    6.
    发明授权
    2-(n-acetyl-n-acetoxyamino) acetyl chloride 失效
    2-(N-乙酰基-N-乙酰氨基)乙酰氯

    公开(公告)号:US3632644A

    公开(公告)日:1972-01-04

    申请号:US3632644D

    申请日:1969-10-14

    CPC classification number: C07C205/59

    Abstract: HOOC-CH2-NH-OH (I)--> HOOC-CH2-N(-CO-CH3)-OOC-CH3 (II)-->

    D R A W I N G
    1. 2-(N-ACETYL-N-ACETOXYAMINO)ACETYL CHLORIDE.

    (I) --> CH3-COO-CO-CH2-N(-CO-CH3)-OOC-CH3 (VI) --> (IV)

    3H-1,4-BENZODIAZEPINE (V)

    2-(O=),4-(O=),5-PHENYL,7-(CL-)-1,2-DIHYDRO-

    BENZENE (IV)-->

    1-(PHENYL-CO-),3-(CL-),6-(CH3-COO-N(-CO-CH3)-CH2-CO-NH-)

    CL-CO-CH2-N(-CO-CH3)-OOC-CH3 (III)-->

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