Method for disposal of waste printed circuit board thermal cracking slag and smelting soot

    公开(公告)号:US11692238B2

    公开(公告)日:2023-07-04

    申请号:US17625746

    申请日:2020-11-11

    CPC classification number: C22B1/06 C22B7/007 C22B11/042 C22B15/0071 C22B19/30

    Abstract: The invention discloses a method for cracking slag and smelting soot of the waste circuit board, belongs to the field of comprehensive recycling of valuable elements from typical soot of waste circuit boards, and particularly relates to a method for cracking slag and smelting soot of the waste circuit board for debromination and comprehensive recovery of copper and zinc. The method includes the following steps of: crushing and sorting, mixture roasting, reinforced leaching, replacement and silver precipitation, sulfuration and copper precipitation, and evaporation crystallization. Compared to traditional recycling technology, the purpose of treating two kinds of solid waste in a coupling mode through one recycling technology is achieved. Through mixed sulfuric acid roasting, the requirement of bromide synergistic removal of the waste circuit board cracking slag and smelting soot is met, and the purpose of selective conversion of copper and zinc is achieved.

    METHOD FOR LEACHING COPPER FROM COPPER SULFIDE ORE

    公开(公告)号:US20180187287A1

    公开(公告)日:2018-07-05

    申请号:US15737513

    申请日:2016-09-12

    CPC classification number: C22B15/0071 C22B3/44 Y02P10/234 Y02P10/236

    Abstract: The present invention provides a method for efficiently leaching copper from copper sulfide ore by separating and recovering iodine, and iron(III) ions to be used are regenerated by a heap of stacked ore in the method for leaching copper from copper sulfide using a sulfuric acid solution containing iodide ions and iron(III) ions as a leaching solution. The present invention relates to a method for leaching copper from copper sulfide, comprising the following steps: a copper leaching step for leaching copper from copper sulfide ore using a sulfuric acid solution containing iodide ions and iron(III) ions as a leaching solution to yield a first solution; an iodine separation treatment step for separating iodine in the first solution to yield a second solution having a lowered concentration of iodine therein; and an iron oxidation step for oxidizing the second solution to yield a third solution, leaching the copper sulfide ore or another copper sulfide using the third solution and an aqueous solution containing iodine, wherein the iron oxidation step comprises irrigating the solution after iodine separation treatment onto stacked ore, thereby oxidizing iron(II) ions existing in the solution after iodine treatment and generated by copper leaching.

    Leaching process for copper concentrates with a carbon catalyst
    9.
    发明授权
    Leaching process for copper concentrates with a carbon catalyst 有权
    铜精矿的浸出工艺与碳催化剂

    公开(公告)号:US08968442B2

    公开(公告)日:2015-03-03

    申请号:US13503338

    申请日:2010-10-20

    Abstract: A method of recovering copper from a copper sulfide concentrate comprising a copper arsenic sulfosalt or a copper antimony sulfosalt, using carbon as a catalyst. The concentrate and carbon are added to an acidic sulfate leach solution. The copper is leached from the concentrate, in the presence of an oxygen-containing gas. The operating potential is maintained above a selected level. The carbon copper sulfide ratio of the carbon being added to the copper sulfide present in the concentrate being added is at least 1:20. The carbon may be maintained above a selected concentration in the leach solution. The leached copper is recovered from the solution by conventional methods.

    Abstract translation: 使用碳作为催化剂从铜硫化物浓缩物中回收铜的方法,其包含铜砷磺酸盐或铜锑磺酸盐。 将浓缩物和碳添加到酸性硫酸盐浸出溶液中。 在含氧气体的存在下,从浓缩物中浸出铜。 工作电位维持在选定的水平以上。 加入到加入浓缩物中的硫化铜中的碳的碳化铜比例至少为1:20。 可以在浸出溶液中将碳保持在选定浓度以上。 通过常规方法从溶液中回收浸出的铜。

    Metathetic copper concentrate enrichment
    10.
    发明授权
    Metathetic copper concentrate enrichment 有权
    富含铜精矿富集

    公开(公告)号:US08741238B2

    公开(公告)日:2014-06-03

    申请号:US13965960

    申请日:2013-08-13

    Abstract: In one aspect, the invention provides processes for producing an enriched copper concentrate from a copper-and-nickel-containing ore. Processes of the invention may include an initial step of comminuting the ore, to provide a ground ore comprising copper minerals and nickel minerals. The ground ore may be subjected to a floatation process, to separate the ground ore into distinct fractions, such as first and second concentrates. A first concentrate may for example be made up of copper-enriched-and-nickel-containing solids, while a second concentrate is made up of nickel-enriched-and-copper-containing solids. The floatation process may for example fractionate the ore so that the concentration of copper minerals is higher in the first concentrate than in the ore, and the concentration of the nickel minerals is higher in the second concentrate than the ore.

    Abstract translation: 一方面,本发明提供了从含铜和镍的矿石生产富集的铜精矿的方法。 本发明的方法可以包括粉碎矿石的初始步骤,以提供包含铜矿物和镍矿物的研磨矿石。 研磨矿石可以进行漂浮工艺,将研磨的矿石分离成不同的馏分,例如第一和第二浓缩物。 第一浓缩物可以例如由富含铜和含镍的固体组成,而第二浓缩物由富含镍和含铜的固体组成。 浮选过程可以例如将矿石分馏,使得第一浓缩物中的铜矿物质的浓度高于矿石,并且第二浓缩物中的镍矿物质的浓度高于矿石。

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