Formulation for use in chrome or chrome-free tannage
    1.
    发明申请
    Formulation for use in chrome or chrome-free tannage 失效
    用于铬或无铬鞣革的配方

    公开(公告)号:US20060101584A1

    公开(公告)日:2006-05-18

    申请号:US10524047

    申请日:2003-08-14

    IPC分类号: C14C3/00

    CPC分类号: C14C3/16 C14C3/28

    摘要: A formulation for use in chrome-free or chrome tanning is proposed, comprising a clay mineral which, after vigorous stirring for 30 minutes in water at 50° C., has a number average particle diameter of less than 2 μm or a bimodal size distribution with a first, finely divided fraction whose number average particle diameter is less than 0.5 μm and a second, coarser fraction whose number average particle diameter is less than 5 μm, determined in each case by the method according to ISO 13320-1, by combined laser light diffraction and light scattering, the amount of the first, finely divided fraction being from 10 to 90% by weight, and one or more substances from one or more of the following groups: organic polymers, aldehyde tanning agents, sulfone tanning agents, resin tanning agents, phenol tanning agents, fatliquoring agents, vegetable tanning agents, dyes and pigments.

    摘要翻译: 提出了用于无铬或铬鞣制剂的制剂,其包含粘土矿物,其在50℃下在水中剧烈搅拌30分钟后具有小于2μm的数均粒径或双峰尺寸分布 具有数均粒径小于0.5μm的第一细碎部分和数均粒径小于5μm的第二粗纱部分,通过组合的方法按照ISO 13320-1的方法确定 激光衍射和光散射,第一细分的份数为10至90重量%,以及一种或多种下列一种或多种物质:​​有机聚合物,醛鞣剂,砜鞣剂, 树脂鞣剂,苯酚鞣剂,加脂剂,植物鞣剂,染料和颜料。

    CHROME-FREE TANNING PROCESS OF ECOLOGICAL LEATHER

    公开(公告)号:US20240263257A1

    公开(公告)日:2024-08-08

    申请号:US18681096

    申请日:2022-05-11

    摘要: A chrome-free tanning process of an ecological leather is characterized by a TWS+sodium lignosulfonate+TWLZ ternary tanning process system. The sodium lignosulfonate added can not only have a fixation effect on a TWS tanning agent to make the TWS tanning not undergo detanning at a low pH, but also significantly improve the uniformity of distribution of a TWLZ tanning agent in a hide/skin and promote the formation of a stable cross-linked network structure by the TWLZ tanning agent in a collagen fiber, which effectively overcomes the defects of tanning performance of the existing tanning systems to obtain a leather with uniform and sufficient tanning, a high isoelectric point, a strong electropositivity, excellent absorption for post-tanning chemicals, and a prominent softness, and gives a leather a wide use range and a high quality.

    CHROME-FREE LEATHER RETANNING
    5.
    发明申请
    CHROME-FREE LEATHER RETANNING 有权
    无铬皮革返修

    公开(公告)号:US20150107028A1

    公开(公告)日:2015-04-23

    申请号:US14514582

    申请日:2014-10-15

    IPC分类号: C14C3/22 C14C3/26 C14C3/28

    摘要: A method for forming chrome-free retanned leather including: (a) contacting wet white with from 1% to 8%, by solids weight, based on the wet weight of wet white, retanning agent selected from the group consisting of: i) an aqueous emulsion polymer including, as copolymerized units, from 2% to 35%, by weight, based on the weight of the emulsion polymer, ethylenically-unsaturated monomer bearing at least one epoxy group, the emulsion polymer having a weight average molecular weight of from 2,000 to 100,000; ii) a compound selected from the group comprising piperazine, piperazine hydrates, salts of piperazine, and combinations thereof; and iii) combinations of i) and ii); (b) heating the contacted wet white; and (c) drying the contacted, heated wet white is provided. The present application also relates to chrome-free retanned leather formed by the method of the invention.

    摘要翻译: 一种形成无铬复鞣革的方法,其包括:(a)基于潮湿白色复鞣剂的湿重,将湿白色与1%至8%的固体重量相接触,所述湿白色复鞣剂选自:i) 水乳液聚合物,其包含基于乳液聚合物的重量比为2%至35%的共聚单元,所述烯属不饱和单体具有至少一个环氧基,所述乳液聚合物的重均分子量为 2,000至100,000; ii)选自哌嗪,哌嗪水合物,哌嗪盐及其组合的化合物; 和iii)i)和ii)的组合; (b)加热接触的湿白色; 和(c)提供干燥接触的加热的湿白色。 本申请还涉及通过本发明的方法形成的无铬鞣革。

    Leather
    6.
    发明授权
    Leather 失效
    皮革

    公开(公告)号:US08481169B2

    公开(公告)日:2013-07-09

    申请号:US12666806

    申请日:2008-06-27

    IPC分类号: C14C9/00 C14C3/16 C14C3/28

    摘要: A leather obtained by a (1) pre-treatment before tanning, (2) tanning process where glutaraldehyde is used as a tanning agent, (3) process where a re-tanning agent is used which is constituted by synthetic tannin, resin and aluminum, of which the synthetic tannin is constituted by (a) condensation product of aromatic sulfonic acid with formaldehyde or mixture of aromatic sulfonic acid and condensation product of aromatic sulfonic acid with formaldehyde, (b) methylene cyclic polymer of aromatic sulfonic acid with hydroxy aromatic compound or mixture of aromatic sulfonic acid and methylene cyclic polymer of aromatic sulfonic acid with hydroxy aromatic compound and (c) glyoxal, while the resin is constituted by (a) acrylic acid, methacrylic acid, acrylic acid ester or methacrylic acid ester polymer(s) and mixture thereof, and copolymer(s) thereof or mixture thereof and (b) polycondensation product of melamine with formaldehyde, wherein the re-tanning agent having the aforementioned composition is used to perform re-tanning, followed by dyeing as well as fatliquoring treatment using a fatliquoring agent constituted by (a) synthetic oil and natural oil and (b) mixture of synthetic oil and natural constituent, and (4) post-treatment after re-tanning; wherein said leather is characterized in that it is flexible and has unique elasticity and softness beyond what is presented by the material hide and has restorability that prevents the leather from stretching more than it should, and also in that its conditions include a BLC stiffness/softness of 4.42 mm or more but 4.90 mm or less and maximum set ratio of 10.7 or more but 13.9 or less.

    摘要翻译: (1)在鞣制前预处理得到的皮革,(2)将戊二醛用作鞣剂的鞣制过程,(3)使用由合成鞣酸,树脂和铝构成的再鞣剂的方法 ,其中合成单宁由(a)芳族磺酸与甲醛或芳族磺酸的混合物与芳族磺酸与甲醛的缩合产物的缩合产物,(b)芳族磺酸与羟基芳族化合物的亚甲基环状聚合物 或芳族磺酸与羟基芳族化合物的亚甲基环状聚合物的混合物和(c)乙二醛,而树脂由(a)丙烯酸,甲基丙烯酸,丙烯酸酯或甲基丙烯酸酯聚合物构成, 及其混合物及其共聚物或其混合物,和(b)三聚氰胺与甲醛的缩聚产物,其中具有上述组合物的再鞣剂 使用由(a)合成油和天然油构成的加脂剂和(b)合成油和天然成分的混合物进行染色和加脂处理,以及(4)后处理 经鞣制后; 其中所述皮革的特征在于它是柔性的并且具有超越由材料皮肤呈现的弹性和柔软度,并且具有防止皮革拉伸超过其应力的可恢复性,并且其条件包括BLC刚度/柔软度 4.42mm以上但4.90mm以下,最大设定比例为10.7以上且13.9以下。

    Leather
    7.
    发明申请
    Leather 失效
    皮革

    公开(公告)号:US20100325811A1

    公开(公告)日:2010-12-30

    申请号:US12666806

    申请日:2008-06-27

    IPC分类号: C14C3/18

    摘要: A leather is obtained by a process where a re-tanning agent is used which is constituted by synthetic tannin, resin and aluminum. The synthetic tannin is constituted by (a) condensation product of aromatic sulfonic acid with formaldehyde, (b) methylene cyclic polymer of aromatic sulfonic acid with hydroxy aromatic compound, and (c) glyoxal. The resin is constituted by (a) acrylic acid, methacrylic acid, acrylic acid ester or methacrylic acid ester polymer(s), and copolymer(s) thereof, and (b) polycondensation product of melamine with formaldehyde.

    摘要翻译: 通过使用由合成鞣酸,树脂和铝构成的再鞣剂的方法获得皮革。 合成单宁由(a)芳族磺酸与甲醛的缩合产物,(b)芳族磺酸与羟基芳族化合物的亚甲基环状聚合物和(c)乙二醛构成。 树脂由(a)丙烯酸,甲基丙烯酸,丙烯酸酯或甲基丙烯酸酯聚合物及其共聚物,(b)三聚氰胺与甲醛的缩聚产物构成。

    Composition for the Pretanning of Pelts
    8.
    发明申请
    Composition for the Pretanning of Pelts 审中-公开
    用于预胶囊的组合物

    公开(公告)号:US20080276378A1

    公开(公告)日:2008-11-13

    申请号:US10574913

    申请日:2004-10-07

    申请人: Jens Fennen

    发明人: Jens Fennen

    IPC分类号: C14C3/22

    CPC分类号: C14C3/16

    摘要: Compositions comprising a) 5 to 50% by weight of an aliphatic dialdehyde having 2 to 10 carbon atoms; b) 2-5 to 20% by weight of at least one reductive saccharide having a dextrose equivalent of 10 to 100; c) 2.5 to 20% by weight of at least one water-soluble, optionally monoetherified polyoxaalkylene glycol having a molecular weight of more than 100 and not more than 2000; and d) 90 to 10% by weight of water, 0.05 to 0.19 mole of the components b) and c) being added per mole of the component a), outstandingly suitable for the pretanning of pelts and subsequent production of leathers free of heavy metals.

    摘要翻译: 组合物,其包含a)5至50重量%的具有2至10个碳原子的脂族二醛; b)2-5至20重量%的至少一种葡萄糖当量为10至100的还原糖; c)2.5至20重量%的至少一种分子量大于100且不大于2000的水溶性,任选单醚化的聚氧亚烷基二醇; 和d)90至10重量%的水,0.05至0.19摩尔的组分b)和c)每摩尔组分a)加入,显着地适用于预先研磨毛皮和随后生产不含重金属的皮革 。

    Method for Producing Leather
    9.
    发明申请
    Method for Producing Leather 审中-公开
    生产皮革的方法

    公开(公告)号:US20090172890A1

    公开(公告)日:2009-07-09

    申请号:US11995511

    申请日:2006-07-06

    IPC分类号: C14C1/08

    CPC分类号: C14C3/16

    摘要: Process for the production of leather, wherein, after liming, deliming and, if appropriate, pickling, animal hides are pretanned or tanned with a mixture of compounds comprising(a) at least one organic tanning agent and (b) a mixture of (b1) at least one C3-C12-dicarboxylic acid (b2) and at least one further acidic compound selected from C1-C3-mono- or C3-C12-dicarboxylic acids, or salts thereof.

    摘要翻译: 用于生产皮革的方法,其中,在石灰化,分层,如果适用的酸洗后,用包含(a)至少一种有机鞣剂和(b)(b1)的混合物的混合物混合物将动物皮革预先或鞣制 )至少一种C 3 -C 12二羧酸(b2)和至少一种选自C 1 -C 3 - 单 - 或C 3 -C 12 - 二羧酸的其它酸性化合物或其盐。

    Method for the production of leather and semifinished products, and formulations that are suitable therefor
    10.
    发明申请
    Method for the production of leather and semifinished products, and formulations that are suitable therefor 审中-公开
    用于生产皮革和半成品的方法,以及适用于其的制剂

    公开(公告)号:US20070101509A1

    公开(公告)日:2007-05-10

    申请号:US10572547

    申请日:2004-09-17

    IPC分类号: C14C1/00

    CPC分类号: C14C3/16 C14C3/22

    摘要: Semifinished products or leather are or is produced by a process in which pelts, pickled pelts or semifinished products are treated with a) at least one sheet silicate and b) at least one copolymer which is obtainable by copolymerization of at least one ethylenically unsaturated dicarboxylic anhydride (A), derived from at least one dicarboxylic acid of 4 to 8 carbon atoms, at least one vinylaromatic compound (B1) or at least one oligomer (B2) of branched or straight-chain C2-C10-alkene, at least one oligomer having an average molecular weight Mn of from 300 to 5 000 g/mol or being obtainable by oligomerization of at least 3 equivalents of C2-C10-alkene, and optionally at least one ethylenically unsaturated monomer (C) differing from (A) and having at least one hetero atom, and reaction with at least one compound (D) of the formula I a or I b and optionally hydrolysis with water or aqueous alkaline solution, where, in formula I a and I b, A1 are identical or different and are C2-C6-alkylene R1 is linear or branched C1-C20-alkyl and n is an integer from 1 to 200.

    摘要翻译: 半成品或皮革是通过以下工艺生产的:其中用a)至少一种片状硅酸盐处理毛皮,腌制的毛皮或半成品,和b)至少一种共聚物,其可通过至少一种烯键式不饱和二羧酸酐 (A),衍生自至少一个4至8个碳原子的二羧酸,至少一种乙烯基芳族化合物(B1)或至少一种支链或直链C 2 - C 10 - 亚烷基,至少一种平均分子量为N 3〜5 000g / mol的低聚物或可通过将至少3当量的 C 2 -C 10 - 烯烃,以及任选至少一种不同于(A)并且具有至少一个杂原子的烯属不饱和单体(C),并且与 至少一种式I a或I b的化合物(D),并且任选地用水或碱性水溶液水解,其中在式I中a a d I b,A 1相同或不同,为C 2 -C 6 - 亚烷基,R 1为 直链或支链C 1 -C 20 - 烷基,n为1至200的整数。