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    Metallized formazan compounds containing a reactive group
    5.
    发明授权
    Metallized formazan compounds containing a reactive group 失效
    含有反应性基团的金属化合物

    公开(公告)号：US3926942A

    公开(公告)日：1975-12-16

    申请号：US38772773

    申请日：1973-08-13

    申请人： ICI LTD

    发明人： YELLAND MICHAEL

    IPC分类号： C09B50/00 ,  C09B62/018 ,  C09B62/04 ,  C09B62/44 ,  C09B62/08 ,  C09B62/24 ,  D06P1/382

    CPC分类号： C09B62/4407 ,  C09B62/018

    摘要： WHEREIN D is the N-linked radical of a metal complex formazan compound containing a single amino group, n is 1 or 2, and X is the residue of a colorless organic acid containing a cellulosereactive substituent. These compounds provide bright blue or green shades on cellulose textile materials of good fastness to washing or to light. They are notable for the high proportion which fixes on the fibre and for the low degree of staining of adjacent undyed material in washing.

    Dyestuffs represented by the general formula:

    摘要翻译： 由以下通式表示的染料：N ANGLE D-CC-NH | PARALLEL NN ANGLE -NH-X（1）C || Cl（SO 3 H）n WHEREIN D是金属络合物甲az化合物的N-连接基团，其含有 单个氨基，n为1或2，X为含有纤维素反应性取代基的无色有机酸的残基。 这些化合物在纤维素纺织材料上提供明亮的蓝色或绿色色调，具有良好的耐洗牢度或耐光性。 它们对于固定在纤维上的高比例和在洗涤中相邻未染色材料的低染色程度是显着的。

    Reactive formazan dyestuffs
    7.
    发明授权
    Reactive formazan dyestuffs 失效
    活性甲an染料

    公开(公告)号：US06407220B1

    公开(公告)日：2002-06-18

    申请号：US10014597

    申请日：2001-12-14

    申请人： Huei Ching Huang ,  Wen-Jang Chen

    发明人： Huei Ching Huang ,  Wen-Jang Chen

    IPC分类号： C09B5000

    CPC分类号： C09B62/4407 ,  C09B62/463

    摘要： The present invention provides reactive formazan dyestuffs of the general formula (I), Wherein A, B, D, Me, Q, R, and Z are defined in this document. The dyes according to the invention are distinguished by high fixation and a very good build-up. They are distinguished also by a low substantivity and a high exhaustion, and they have fiber-reactive properties and are very highly suitable for dyeing and printing of materials containing either cellulose fibers.

    摘要翻译： 本发明提供了通式（I）的反应性甲an染料，其中A，B，D，Me，Q，R和Z在本文中定义。 根据本发明的染料通过高定影和非常好的聚集来区分。 它们的特征还在于低亲和性和高耗尽性，并且它们具有纤维反应性，并且非常适用于含有纤维素纤维的材料的染色和印花。

    Copper complex formazan compounds containing a cyanamido-S-triazinylamino radical and a fiber-reactive group of the vinylsulfone series, suitable as dyes
    8.
    发明授权
    Copper complex formazan compounds containing a cyanamido-S-triazinylamino radical and a fiber-reactive group of the vinylsulfone series, suitable as dyes 失效
    含有氰氨基-S-三嗪基氨基的铜络合甲an化合物和乙烯基砜系列的纤维反应性基团，适合作为染料

    公开(公告)号：US5015731A

    公开(公告)日：1991-05-14

    申请号：US474531

    申请日：1990-02-02

    申请人： Gunther Schwaiger ,  Hartmut Springer

    发明人： Gunther Schwaiger ,  Hartmut Springer

    IPC分类号： C09B62/44 ,  C09B62/503

    CPC分类号： C09B62/5036 ,  C09B62/4407

    摘要： Copper complex formazan compounds which have fiber-reactive properties and are very highly suitable for use as dyes for dyeing carboxamido-containing and/or hydroxy-containing material, such as fiber material, for example wool and cellulose fiber materials, have the general formula (1) ##STR1## where A is a benzene or naphthylene ring which may be substituted by substituents customary in dyes, such as halogen, nitro, alkyl and alkoxy,B is alkylene of 1 to 8 carbon atoms or alkenylene of 2 to 8 carbon atoms which may each be substituted by phenyl which in turn may contain the substituents customary in dyes, or is alkylene-phenylene or alkenylene-phenylene having lower alkylene and alkenylene radicals, while the phenylene radicals may in turn contain the substituents customary in dyes, or is a phenylene or naphthylene radical which may contain substituents customary in dyes, or is the bivalent radical of a heterocycle, such as furan, thiophene or benzimidazole, or--B--Z together is hydrogen,Z is a water-solubilizing group, such as sulfo,k is 1 or 2,m is 0, 1 or 2,n is 0, 1 or 2, the sum (m+n) is 1 to 4;X is oxygen or carbonyloxy,R is hydrogen or substituted or unsubstituted lower alkyl,D is substituted or unsubstituted phenylene or naphthylene,Y is vinyl or an ethyl group which contains in the .beta.-position a substituent which is eliminatable under alkaline conditions, andM is hydrogen, an alkali metal or an alkaline earth metal.

    摘要翻译： 具有纤维反应性并且非常适合用作染色含有羧酰胺的和/或含羟基的材料如纤维材料（例如羊毛和纤维素纤维材料）的铜复合甲an化合物具有通式（ 1）（1）D（SO 2 Y）k其中A是可以被染料中常规取代基取代的苯或亚萘基环，例如卤素，硝基，烷基和烷氧基，B是1至8个碳原子的亚烷基 或2至8个碳原子的亚烯基，其可以各自被苯基取代，苯基又可以含有染料中常规的取代基，或者是具有低级亚烷基和亚烯基的亚烷基亚苯基或亚烯基亚苯基，而亚苯基可以依次含有 染料中常用的取代基，或是可能含有染料常规取代基的亚苯基或亚萘基，或是呋喃，噻吩或苯并咪唑等杂环的二价基团，或-BZ toget 她是氢，Z是一个水溶性基团，如磺基，k是1或2，m是0,1或2，n是0,1或2，和（m + n）是1到4; X是氧或羰氧基，R是氢或取代或未取代的低级烷基，D是取代或未取代的亚苯基或亚萘基，Y是乙烯基或在β-位上含有在碱性条件下可消除的取代基的乙基，M 是氢，碱金属或碱土金属。

    Copper complex formazan compounds containing a phenylaminotriazinylamino group with a fiber-reactive group of the vinylsulfone series and an alkyl amino substituent in the phenyl moiety suitable as fiber-reactive dyestuffs
    9.
    发明授权
    Copper complex formazan compounds containing a phenylaminotriazinylamino group with a fiber-reactive group of the vinylsulfone series and an alkyl amino substituent in the phenyl moiety suitable as fiber-reactive dyestuffs 失效
    含有乙烯基砜系列的纤维反应性基团的苯基氨基三嗪基氨基和适合作为纤维反应性染料的苯基部分中的烷基氨基取代基的铜络合甲an化合物

    公开(公告)号：US4906736A

    公开(公告)日：1990-03-06

    申请号：US159188

    申请日：1988-02-23

    申请人： Gunther Schwaiger ,  Hartmut Springer ,  Werner H. Russ

    发明人： Gunther Schwaiger ,  Hartmut Springer ,  Werner H. Russ

    IPC分类号： C09B62/503 ,  C09B62/44 ,  D06P3/24 ,  D06P3/66

    CPC分类号： C09B62/4407

    摘要： Water-soluble copper complex formazan compounds which conform to the general formula (1) below and have useful fiber-reactive dye properties and dye carboxamido- and/or hydroxy-containing material, in particular cellulose fibers, in fast blue shades. ##STR1## in which: M is hydrogen or a salt-forming metal atom,k, m and n each denote the number zero, 1 or 2, the sum (k+m+n) being equal to 1 to 4,A is a benzene or napththalene ring which additionally can contain the fiber-reactive group --NH--Q and further substituents,B is a benzene or naphthalene ring which additionally contains the fiber-reactive group --NH--Q and further substituents,D is substituted or unsubstituted alkylene of 1 to 8 carbon atoms or is a benzene or naphthalene ring having optionally additional substituents or is a heterocyclic radical,X is a sulfo group or an oxy or carbonyloxy group,r is the number 1 or 2,Q is a radical of the formula (2) ##STR2## in which Y is halogen, Z is vinyl or a .beta.-substituted ethyl,G is the thio or an amino group --N(R)-- where R is equal to hydrogen or to low, substituted or unsubstituted alkyl or a group --K--W.sub.p defined hereinafter, K is alkylene or arylene or arylene-alkylene or alkylene-arylene whose arylene and alkylene radicals can be substituted and/or interrupted by a hetero group, W is a water-solubilizing group and p is the number 1, 2 or 3,the group --NH--Q is bonded to an aromatic carbon atom of A or B or D or to an aliphatic carbon atom of D or of a substituent on A or B, in the case of r=2, however, not simultaneously to A, B or D.

    摘要翻译： 符合以下通式（1）的水溶性铜络合物甲an化合物，具有有用的纤维反应性染料性质，并具有染料甲酰胺基和/或羟基的材料，特别是纤维素纤维，具有快速的蓝色色调。 其中：M是氢或成盐金属原子，k，m和n分别表示数字零，1或2，总和（k + m + n）等于 在图1至图4中，A是苯或萘环，其另外可以含有纤维反应性基团-NH-Q和另外的取代基，B是另外含有纤维反应性基团-NH-Q的苯或萘环， D为1至8个碳原子的取代或未取代的亚烷基，或具有任选另外的取代基的苯或萘环，或为杂环基，X为磺基或氧基或羰氧基，r为数1或2， Q是式（2）的基团，其中Y是卤素，Z是乙烯基或β-取代的乙基，G是硫基或氨基-N（R） - ，其中R等于 氢或低级取代或未取代的烷基或下文定义的基团-K-Wp，K是亚芳基和亚芳基或亚芳基或亚芳基 - 亚烷基或亚烷基 - 亚芳基 亚烷基可以被杂基取代和/或中断，W是水溶性基团，p是数字1,2或3，基团-NH-Q键合到A或B的芳族碳原子上，或 D或D的脂族碳原子或A或B上的取代基，在r = 2的情况下，然而，不能同时对A，B或D。

    MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING
    10.
    发明申请
    MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING 有权
    反应性染料的混合物及其在三色染色或印刷方法中的应用

    公开(公告)号：US20100077555A1

    公开(公告)日：2010-04-01

    申请号：US12513464

    申请日：2007-10-30

    申请人： Georg Roentgen ,  Athanassios Tzikas ,  Hubert Jean Luc Christnacher

    发明人： Georg Roentgen ,  Athanassios Tzikas ,  Hubert Jean Luc Christnacher

    IPC分类号： C09B62/095 ,  C09B62/012

    CPC分类号： C09B62/4407 ,  C09B62/4413 ,  C09B62/4415 ,  C09B67/005 ,  C09B67/0059

    摘要： Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein Q1 is C1-C4alkyl, halogen or a radical —SO2—Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo, Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2 and R3 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2 and X3 are each independently of the others halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl or a non-fibre-reactive substituent, and T1, T2 and T3 are each independently of the others a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R4)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Q is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.

    摘要翻译： 染料混合物，其包含至少一种下式的染料和至少一种下式基团的染料，其中Q 1是C 1 -C 4烷基，卤素或基团-SO 2 -Z，Q 2和Q 3各自独立地为C 1 -C 4烷氧基，Q 4 C1-C4烷氧基，C1-C4烷基，卤素或磺基，Q5是C1-C4烷氧基，C1-C4烷基，C1-C4烷酰基氨基，脲基，卤素或磺基，R1，R2和R3各自独立地是氢或未取代的或取代的C1 -C 1-4烷基，k和q各自独立于数字0或1中的另一个，n和p各自独立于数字0,1或2中的另一个，m是数字0,1,2或3，t是 1,2或3个，X1，X2和X3各自独立地为卤素，3-羧基吡啶-1-基，3-氨基甲酰基吡啶-1-基或非纤维反应性取代基，T1，T2和T3 各自独立地为非纤维反应性取代基或具有下式的纤维反应性基团其中（R4）0-2表示0至2个相同或不同的取代基，基团卤素 ，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z是乙烯基或基团-CH 2 -CH 2 -U，U是在碱性条件下可除去的基团，Q是基团-CH（Hal）-CH 2 - Hal或-C（ Hal）= CH2，Hal是卤素，特别适用于纤维素纤维材料的二色或三色染色或印花，并且具有良好的再现性和良好的全面牢固性的产量染色或印花。