Synthetic polyamides stabilized against the action of light and heat
    1.
    发明授权
    Synthetic polyamides stabilized against the action of light and heat 失效
    稳定的合成聚酰胺对光和热的作用

    公开(公告)号:US3108091A

    公开(公告)日:1963-10-22

    申请号:US8544961

    申请日:1961-01-30

    Applicant: BASF AG

    Abstract: A stabilized polyamide contains as stabilizers 0,5 to 2% by weight of hypophosphoric acid and/or a hypophosphate and 0,001 to 1% by weight of a water soluble cerium (III) salt and/or a water-soluble titanium (III) salt. Specified hydrophosphates are lithium, sodium, potassium, magnesium, calcium, barium, aluminium, cerium, thorium, copper, zinc, titanium, iron, nickel and cobalt hypophosphates. Specified water-soluble cerium (III) and titanium (III) salts are the chlorides, bromides, halides, sulphonates, formates and acetates. Specified polyamides are those derived from caprolactam, caprylic lactam, o -amino-undecanoic acid, the salts of adipic, suberic, sebacic or decamethylene dicarbonic acid with hexamethylene or decamethylene diamine, of heptane dicarboxylic acid with bis-(4-aminocyclohexyl)-methane, of tetramethylene diisocyanate and adipic acid and of aliphatic w-aminoalcohols and dicarboxylic acids each with 4 to 34 carbon atoms between the functional groups. The stabilizers may be added to the polyamides during or after the polycondensation reaction. Delustrants, e.g. cerium dioxide, titanium dioxide, thorium dioxide or ytrium trioxide may also be added to the polyamides. Examples (1) and (2) describe the polymerization of:-(1) hexamethylene diammonium adipate in the presence of disodium dihydrogen hypophosphate hexahydrate and (a) titanium (III) chloride hexahydrate, (b) cerium (III) chloride; (2) caprolactam in the presence of (a) thorium hypophosphate and titanium (III) chloride hexahydrate, whilst in Example (3) polycaprylic lactam is mixed with tetrasodium hypophosphate, titanium (III) acetate and titanium dioxide.

    One-can moisture-curing urethane compositions
    4.
    发明授权
    One-can moisture-curing urethane compositions 失效
    单罐湿润聚氨酯组合物

    公开(公告)号:US06180713B2

    公开(公告)日:2001-01-30

    申请号:US09403276

    申请日:1999-10-18

    CPC classification number: C08G18/12 C08L75/04 C08G18/307 C08L2666/82

    Abstract: A one-pack type moisture curable urethane composition comprising a urethane prepolymer and an amine catalyst, wherein 0.002 to 50 parts by weight, based upon 100 parts by weight of the urethane prepolymer, of phosphonic ester compounds, phosphonous ester compounds, phosphinous ester compounds or phosphine compounds or any mixture thereof is compounded to give the urethane composition having an improved storage stability, without decreasing the catalyst activity even when an amine catalyst having a high catalytic activity dimethylamino group structure etc. is used.

    Abstract translation: 包含氨基甲酸酯预聚物和胺催化剂的单组分湿气固化型氨基甲酸酯组合物,其中,相对于100重量份的氨基甲酸酯预聚物为0.002〜50重量份的膦酸酯化合物,膦酸酯化合物,次膦酸酯化合物或 配合膦化合物或其任何混合物,即使使用具有高催化活性二甲基氨基结构等的胺催化剂,也不降低催化剂活性,得到具有改善的储存稳定性的氨基甲酸酯组合物。

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