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    COMPOSITIONS AND METHODS FOR OLEFIN RECOVERY
    1.
    发明申请
    COMPOSITIONS AND METHODS FOR OLEFIN RECOVERY 审中-公开
    烯烃回收的组合物和方法

    公开(公告)号：US20110213191A1

    公开(公告)日：2011-09-01

    申请号：US12997148

    申请日：2009-06-08

    申请人： Robert C. Schucker ,  Michael F. Lynch

    发明人： Robert C. Schucker ,  Michael F. Lynch

    IPC分类号： C07C7/156 ,  C07C7/152 ,  C09K3/00

    CPC分类号： C07C7/152 ,  C07C7/156 ,  C10G70/002

    摘要： The present invention is directed to compositions and methods for the recovery of olefins from a mixture. The compositions of the present invention comprise: (1) a transition metal ion; (2) a counter anion; (3) a ligand selected from the group consisting of a bidentate ligand and a tridentate ligand, wherein the ligand comprises at least two nitrogen atoms, and wherein each of the nitrogen atoms comprises a lone pair of electrons; and (4) a polar solvent with a boiling point of at least about 200° C. The methods of the present invention comprise: (1) providing the aforementioned compositions; (2) bonding at least a portion of the olefins in a mixture to the transition metal ion in the composition to form a complex; (3) separating the complex from the mixture; and (4) recovering the olefins from the complex.

    摘要翻译： 本发明涉及从混合物中回收烯烃的组合物和方法。 本发明的组合物包含：（1）过渡金属离子; （2）抗衡阴离子; （3）选自二齿配体和三齿配体的配体，其中所述配体包含至少两个氮原子，并且其中每个氮原子包含一对电子; （4）沸点至少为约200℃的极性溶剂。本发明的方法包括：（1）提供上述组合物; （2）将组合物中的至少一部分烯烃与混合物中的过渡金属离子键合以形成络合物; （3）将混合物与混合物分离; 和（4）从络合物中回收烯烃。

    Alkene separation process
    2.
    发明申请
    Alkene separation process 失效
    烯酸分离过程

    公开(公告)号：US20050148791A1

    公开(公告)日：2005-07-07

    申请号：US10502940

    申请日：2003-02-12

    申请人： Andrew Lucy

    发明人： Andrew Lucy

    IPC分类号： C07C5/333 ,  C07B61/00 ,  C07C5/327 ,  C07C7/11 ,  C07C7/148 ,  C07C7/152 ,  C07C11/04 ,  C07C51/215 ,  C07C53/08 ,  C07C67/05 ,  C07C67/39 ,  C07C69/01 ,  C07C69/15

    CPC分类号： C07C7/152 ,  C07C5/48 ,  C07C7/156 ,  C07C51/215 ,  C07C67/055 ,  C07C2523/20 ,  C07C2523/22 ,  C07C2523/28 ,  Y02P20/125 ,  Y02P20/582 ,  C07C11/04 ,  C07C53/08 ,  C07C69/15

    摘要： A process for the oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid which process comprises separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solution, and recovery of an alkene-rich stream from the metallic salt solution. Integrated processes for the production of alkyl carboxylate and alkenyl carboxylate, which processes comprise oxidation of a C2 to C4 alkane to produce the corresponding alkene and carboxylic acid, separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solution, and recovery of an alkene-rich stream from the metallic salt solution for use in production of alkyl carboxylate or alkenyl carboxylate.

    摘要翻译： 将C 2 O 3氧化成C 4烷烃以产生相应的烯烃和羧酸的方法，该方法包括从烯烃的混合物中分离烯烃， 烷烃和氧气通过在金属盐溶液中吸收，并从金属盐溶液中回收富烯烃流。 用于生产羧酸烷基酯和羧酸酯的综合方法，该方法包括将C 2 O 3氧化成C 4链烷烃以产生相应的烯烃和羧酸，分离 通过在金属盐溶液中吸收从烯烃，烷烃和氧气的混合物中获得烯烃，以及从用于生产羧酸烷基酯或链烯基羧酸酯的金属盐溶液中回收富含烯烃的物流。

    Cuprous aluminum cyano trichloride: CuAl(CN)Cl.sub.3 : its preparation and use for the reversible complexing of unsaturated ligands
    5.
    发明授权
    Cuprous aluminum cyano trichloride: CuAl(CN)Cl.sub.3 : its preparation and use for the reversible complexing of unsaturated ligands 失效
    氰化三氯化铝：CuAl（CN）Cl 3：其制备和用于不饱和配体的可逆络合

    公开(公告)号：US4545966A

    公开(公告)日：1985-10-08

    申请号：US535165

    申请日：1983-09-23

    申请人： David G. Walker

    发明人： David G. Walker

    IPC分类号： B01D53/14 ,  C01B32/40 ,  C01C3/11 ,  C07C7/156

    CPC分类号： C01B31/18 ,  B01D53/1493 ,  C01C3/11 ,  C07C7/156

    摘要： An aromatic solution of the compound CuAl(CN)Cl.sub.3 alone or with additional solid CuAl(CN)Cl.sub.3 is used for the separation of some unsaturated compound (olefin, acetylene or carbon monoxide) from a feedstream.The feedstream is contacted with the solvent to form a complex of the ligand (olefin, acetylene or carbon monoxide). The feedstream is then separated from the solvent. The solvent is then treated with some combination of heat and lowered pressure to separate the ligand from the solvent. The ligand poor solvent is then recycled to contact fresh feedstream.

    摘要翻译： 化合物CuAl（CN）Cl3单独或附加固体CuAl（CN）Cl 3的芳香溶液用于从进料流中分离出一些不饱和化合物（烯烃，乙炔或一氧化碳）。 使原料流与溶剂接触以形成配体（烯烃，乙炔或一氧化碳）的络合物。 然后将原料流与溶剂分离。 然后用热和低压的一些组合处理溶剂以将配体与溶剂分离。 然后将配体不良溶剂再循环以接触新鲜进料流。

    Hydrocarbon separations
    6.
    发明授权
    Hydrocarbon separations 失效
    烃分离

    公开(公告)号：US4025574A

    公开(公告)日：1977-05-24

    申请号：US633885

    申请日：1975-11-20

    申请人： Donald C. Tabler ,  Marvin M. Johnson

    发明人： Donald C. Tabler ,  Marvin M. Johnson

    IPC分类号： C07C7/156 ,  C07C7/16

    CPC分类号： C07C7/156 ,  Y02P20/582

    摘要： A process for the separation and recovery of unsaturated aliphatic hydrocarbons from admixture with saturated aliphatic hydrocarbons which comprises contacting such a mixture with a complexing agent comprising cuprous salts of sulfonic acids and dialkyl phosphates under such conditions that the unsaturated hydrocarbons are preferentially complexed with the cuprous salts. In one embodiment, olefins are separated from paraffins by using a cuprous sulfonate dissolved in an aromatic solvent to form a complex with the olefin. The olefin can be separated from the resulting complex and the cuprous salt recycled for reuse.

    摘要翻译： 一种从饱和脂肪烃混合物中分离和回收不饱和脂族烃的方法，包括使这种混合物与包含磺酸和磷酸二烷基酯的亚铜盐的络合剂接触，使得不饱和烃优先与亚铜盐络合 。 在一个实施方案中，通过使用溶解在芳族溶剂中的亚磺酸盐与烯烃分离烯烃，以与烯烃形成络合物。 烯烃可以从所得的络合物中分离出来，再加入亚铜盐再利用。

    Concentrated cuprous nitrate/propionitrile solutions as complexing agents for olefin separations
    7.
    发明授权
    Concentrated cuprous nitrate/propionitrile solutions as complexing agents for olefin separations 失效
    浓缩的硝酸铵/丙酮溶液作为烯烃分离的复合剂

    公开(公告)号：US3801666A

    公开(公告)日：1974-04-02

    申请号：US3801666D

    申请日：1973-03-16

    申请人： SHELL OIL CO

    发明人： BLYTAS G

    IPC分类号： C01G3/08 ,  C07C7/156 ,  C07C11/00

    CPC分类号： C01G3/08 ,  C07C7/156

    摘要： ANHYDROUS CUPROUS NITRATE/PROPIONITRILE SOLUTIONS HAVING HIGH CONCENTRATIONS OF CUPROUS ION, E.G., 15-26% BY WEIGHT CUPROUS ION, AND CORRESPONDINGLY LOW CONCENTRATIONS OF CUPRIC ION, E.G., 2-5% BY WEIGHT CUPRIC ION, AND THE PREPARATION THEREOF BY (1) CONTACTING QUANTITIES OF CUPRIC NITRATE AND METALLIC COPPER SUFFICIENT TO YIELD NO MORE THAN ABOUT 4% CUPROUS ION IN PROPIONITRILE SOLVENT AT ELEVATED TEMPERATURES TO PRODUCE A DILUTE PROPIONITRILE SOLVEN SOLUTION WHEREIN THE COPPER IS PRESENT SUBSTANTIALLY IN THE CUPROUS FORM AND (2) CONCENTRATING THE DILUTE/PROPIONITRILE SOLUTION. THE CONCENTRATED CUPROUS NITRATE/PROPIONITRILE SOLUTIONS, THUSLY PREPARED, ARE USEFUL IN AFFECTING THE SEPARATION OF OLEFINICALLY UNSATURATED HYDROCARBONS FROM HYDROCARBONS OF LESSER DEGREES OF UNSATURATION.

    Olefin complexing process
    8.
    发明授权
    Olefin complexing process 失效
    OLEFIN复合工艺

    公开(公告)号：US3755487A

    公开(公告)日：1973-08-28

    申请号：US3755487D

    申请日：1972-06-02

    申请人： EXXON RESEARCH ENGINEERING CO

    发明人： JAHNING C ,  SAVAGE D ,  HOROWITZ H

    IPC分类号： C07C7/152 ,  C07C7/156 ,  C07C7/00

    CPC分类号： C07C7/156 ,  C07C7/152 ,  C07C11/02 ,  C07C11/06

    摘要： A PROCESS IS DESCRIBED FOR SEPARATING AND RECOVERING COMPLEXIBLE LIQUIDS FROM FEEDSTREAMS CONTAINING THEM, COMPRISING THE STEPS OF COMPLEXING THE LIGANDS WITH A COMPLEXING SOLUTION, STRIPPING IMPURTIES OUT OF SOLUTION, DECOMPLEXING BY FLASHING AT PRESSURES OF FROM 1 ATMOSPHERE TO ABOUT 40 ATMOSPHERES, RECYCLING SOLVENT TO THE

    COMPLEXER AND THEREAFTER RECOVERING SAID LIGANDS AS A HIGH PURITY PRODUCT. THE COMPLEXING SOLUTION COMPRISES GROUP I-B METAL SALTS DISSOLVED IN LOW VOLATILITY AROMATIC SOLVENTS. THE LIGANDS ARE DECOMPLEXED BY EITHER FLASHING OFF A HIGH PRESSURES OR BY MULTIPLE STAGE FLASHING.