公开(公告)号：US20130045906A1

公开(公告)日：2013-02-21

申请号：US13641931

申请日：2011-05-12

申请人： Anthony A. Birkbeck

发明人： Anthony A. Birkbeck

IPC分类号： C07C49/21 ,  A61Q13/00 ,  C11D3/50 ,  C07C49/115 ,  A61K8/35

CPC分类号： C11B9/0046 ,  C07C49/115 ,  C07C49/21 ,  C07C49/557

摘要： A compound and a method to confer, enhance, improve or modify the odor properties of a perfuming composition or of a perfumed article, to confer a green allylic, glycolate and fruity-pineapple odor, by adding the compound thereto. The compound has formula (I): wherein the dotted line represents a carbon-carbon single bond or a carbon-carbon double bond; one R1 represents a hydrogen atom and the other represents a hydrogen atom or a methyl or ethyl group; X representing a C═CH2 or C═CHCH3 group or a CHR2 group, each R2 representing a hydrogen atom or a methyl or ethyl group; and R3 represents a a group of formula CR4═C(R4)2, or a group of formula each R4 representing a hydrogen atom or a methyl or ethyl group. The compound is in the form of a pure enantiomer or a mixture thereof.

摘要翻译： 通过向其中加入化合物，赋予，增强，改善或改善加香组合物或香料制品的气味性质以赋予绿色烯丙基，乙醇酸和果香 - 菠萝气味的化合物和方法。 该化合物具有式（I）：其中虚线表示碳 - 碳单键或碳 - 碳双键; 一个R 1表示氢原子，另一个表示氢原子或甲基或乙基; X表示C = CH 2或C = CHCH 3基或CHR 2基，每个R 2表示氢原子或甲基或乙基; 并且R 3表示式CR 4 = C（R 4）2的基团，或者各自表示氢原子或甲基或乙基的式的基团。 化合物为纯对映异构体或其混合物的形式。

公开(公告)号：US4091020A

公开(公告)日：1978-05-23

申请号：US716411

申请日：1976-08-23

申请人： Nathaniel Grier ,  Richard A. Dybas

发明人： Nathaniel Grier ,  Richard A. Dybas

IPC分类号： A01N33/04 ,  A01N33/06 ,  A01N33/08 ,  C07C45/48 ,  C07C45/62 ,  C07C45/67 ,  C07C45/74 ,  C07C49/115 ,  C07C49/21 ,  C07C49/323 ,  C07D295/13 ,  C07C45/18

CPC分类号： C07D295/13 ,  A01N33/04 ,  A01N33/06 ,  A01N33/08 ,  C07C45/004 ,  C07C45/48 ,  C07C45/62 ,  C07C45/74 ,  C07C49/115

摘要： Novel di-bicyclo[3.1.1] and [2.2.1]heptyl and dibicyclo[3.1.1] and [2.2.1]heptenyl ketones are useful as intermediates for preparing novel polyamines useful as antimicrobial agents, as well as algae inhibitors.

摘要翻译： 新的二 - 双环[3.1.1]和[2.2.1]庚基和二环[3.1.1]和[2.2.1]庚烯基酮可用作制备用作抗微生物剂的新型多胺以及藻类抑制剂的中间体。

公开(公告)号：US4090985A

公开(公告)日：1978-05-23

申请号：US819951

申请日：1977-07-28

申请人： William L. Schreiber ,  James N. Siano ,  Manfred Hugo Vock ,  Edward J. Shuster

发明人： William L. Schreiber ,  James N. Siano ,  Manfred Hugo Vock ,  Edward J. Shuster

IPC分类号： C07C45/00 ,  C07C49/115 ,  C11B9/00

CPC分类号： C11B9/0046 ,  C07C45/00 ,  C07C49/115

摘要： Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma and perfume aroma augmenting, enhancing, modifying and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of 1-(3,3-dimethyl-2-norbornyl)-2-propanone (hereinafter referred to as the "norbornylpropanone derivative") having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof). Addition of the said "norbornylpropanone derivative" to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavorings, chewing gums, toothpastes and medicinal products, fruity/berry, pine needle-like aromas and sweet, fruity/berry, blueberry-like, pine needle-like, pine balsam flavor characteristics; and(b) In perfumes, colognes and perfumed articles sweet, berry, weody, piney, mint aroma notes with a damascenone-like character and buttery and minty nuances.

公开(公告)号：US4139559A

公开(公告)日：1979-02-13

申请号：US869879

申请日：1978-01-16

申请人： Nathaniel Grier ,  Richard A. Dybas ,  Robert A. Strelitz

发明人： Nathaniel Grier ,  Richard A. Dybas ,  Robert A. Strelitz

IPC分类号： A01N33/04 ,  C07C31/137 ,  C07C49/115 ,  C07C53/136 ,  C07C87/40

CPC分类号： A01N33/04 ,  C07C31/137 ,  C07C49/115 ,  C07C53/136

摘要： A process for preparing 1-[1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentyl]-1,5,9-triazanonane from 1,5-di-(3,3-dimethylnorborn-2-yl)-3-pentanone by reaction with ammonia to form, after reduction, 3-amino-[1,5-di-(3,3-dimethylnorborn-2-yl)pentane]. This latter compound is reacted with acrylonitrile, reduced, and the diamine product again reacted with acrylonitrile and again reduced. Alternative routes wherein the ketone is reduced to the novel alcohol and optionally the novel halide and either then reacted with 3,3'-iminobispropylamine to form the desired polyamine are also shown.

摘要翻译： 从1,5-二（3,3-二甲基牛磺酸）制备1- [1,5-二（3,3-二甲基牛磺-2-基）-3-戊基] -1,5,9-三氮杂壬烷的方法 -2-基）-3-戊酮通过与氨反应，在还原后形成3-氨基 - [1,5-二（3,3-二甲基牛磺酸-2-基）戊烷]。 后一种化合物与丙烯腈反应，还原，二胺产物再次与丙烯腈反应并再次还原。 还示出了替代途径，其中酮被还原成新的醇和任选的新型卤化物，然后与3,3'-亚氨基双丙胺反应以形成所需的多胺。

公开(公告)号：US3944621A

公开(公告)日：1976-03-16

申请号：US556862

申请日：1975-03-10

申请人： Braja Dulal Mookherjee ,  Venkatesh Kamath ,  Edward J. Shuster

发明人： Braja Dulal Mookherjee ,  Venkatesh Kamath ,  Edward J. Shuster

IPC分类号： A23L27/20 ,  C07C1/32 ,  C07C47/115 ,  C07C49/115 ,  C07C49/21 ,  C11B9/00 ,  C11D9/44 ,  C07C45/21 ,  C07C45/00 ,  C07C49/61

CPC分类号： C11D9/444 ,  A23L27/203 ,  C07C1/328 ,  C07C47/115 ,  C07C49/115 ,  C07C49/21 ,  C11B9/0042 ,  C11D9/442 ,  C07C2103/64

摘要： A process for the preparation of a mixture of compounds of the structure ##SPC1##Is disclosed whereby a Pi-halotricyclene having the structure ##SPC2##Where Y is chloro, bromo or iodo is reacted with an alkali metal cyanide to prepare the corresponding nitrile; the nitrile is reacted with diisobutylaluminum hyhdride to prepare the corresponding aldehyde, a nortricycloekasantalal which is then condensed with butanone to prepare the above mentioned mixture of compounds. Also claimed are the product ketones which are useful for altering the aroma of consumable products including perfumes, perfume compositions and perfumed articles.

摘要翻译： 一种制备结构化合物的混合物的方法，其中包括具有Y为氯，溴或碘的结构的靛红三环与碱金属氰化物反应以制备相应的腈; 腈与二异丁基铝化合物反应以制备相应的醛，一种北方环己酮，然后与丁酮缩合以制备上述化合物的混合物。 还要求的是产品酮，其可用于改变消费品的香气，包括香料，香料组合物和香料制品。

公开(公告)号：US3845131A

公开(公告)日：1974-10-29

申请号：US23754272

申请日：1972-03-23

申请人： LILLY CO ELI

发明人： SZINAI S

IPC分类号： C07C49/115 ,  C07C45/14 ,  C07C49/43

CPC分类号： C07C49/115

摘要： 1. A PROCESS FOR THE PREPARATION OF ADAMANTYLACETONES OF THE FORMULA

1,5,7-TRI(R-),3-(H3C-CO-CH2-)-ADAMANTANE

WHEREIN R IS HYDROGEN OR METHYL, WHICH COMPRISES REACTING AN ADAMANTLY HALIDE OF THE FORMULA

1,5,7-TRI(R-),3-X-ADAMANTANE

WHEREIN X IS CHLORINE, BROMINE OR IODINE WITH AN ENOL ESTER OF THE FORMULA

H2C=C(-O-Y)-CH3

WHEREIN Y PHENYL

-CO- OR C1-C6 ALKYL-CO-

IN THE PRESENCE OF A FRIEDEL-CRAFTS CATALYST AND AN INERT SOLVENT AND AT A TEMPERATURE IN THE RANGE-70*C. TO +40*C.

公开(公告)号：US08445727B2

公开(公告)日：2013-05-21

申请号：US13641931

申请日：2011-05-12

申请人： Anthony A. Birkbeck

发明人： Anthony A. Birkbeck

IPC分类号： C07C49/115

CPC分类号： C11B9/0046 ,  C07C49/115 ,  C07C49/21 ,  C07C49/557

摘要： A compound and a method to confer, enhance, improve or modify the odor properties of a perfuming composition or of a perfumed article, to confer a green allylic, glycolate and fruity-pineapple odor, by adding the compound thereto. The compound has formula (I): wherein the dotted line represents a carbon-carbon single bond or a carbon-carbon double bond; one R1 represents a hydrogen atom and the other represents a hydrogen atom or a methyl or ethyl group; X representing a C═CH2 or C═CHCH3 group or a CHR2 group, each R2 representing a hydrogen atom or a methyl or ethyl group; and R3 represents a a group of formula CR4═C(R4)2, or a group of formula each R4 representing a hydrogen atom or a methyl or ethyl group. The compound is in the form of a pure enantiomer or a mixture thereof.

摘要翻译： 通过向其中加入化合物，赋予，增强，改善或改善加香组合物或香料制品的气味性质，赋予绿色烯丙基，乙醇酸和果香 - 菠萝气味的化合物和方法。 该化合物具有式（I）：其中虚线表示碳 - 碳单键或碳 - 碳双键; 一个R 1表示氢原子，另一个表示氢原子或甲基或乙基; X表示C = CH 2或C = CHCH 3基或CHR 2基，每个R 2表示氢原子或甲基或乙基; 并且R 3表示式CR 4 = C（R 4）2的基团，或者各个R 4表示氢原子或甲基或乙基的基团。 化合物为纯对映异构体或其混合物的形式。

公开(公告)号：US4191660A

公开(公告)日：1980-03-04

申请号：US932615

申请日：1978-08-10

申请人： William L. Schreiber ,  James N. Siano ,  Manfred H. Vock ,  Edward J. Shuster

发明人： William L. Schreiber ,  James N. Siano ,  Manfred H. Vock ,  Edward J. Shuster

IPC分类号： C07C45/00 ,  C07C49/115 ,  C11B9/00 ,  C11D3/50 ,  C11D9/44

CPC分类号： C11D3/50 ,  C07C45/00 ,  C07C49/115 ,  C11B9/0046

摘要： Processes and compositions are described for the use in cationic, anionic and nonionic detergents and soaps of 1-(3,3-dimethyl-2-norbornyl)-2-propanone (hereinafter referred to as the "norbornylpropanone derivatives") having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof). Addition of the said "norbornylpropanone derivative" to soaps and cationic, anionic and nonionic detergents is indicated to produce sweet, berry, woody, piney, mint aroma notes with a damascenone-like character and buttery and minty nuances.

摘要翻译： 描述了用于具有以下结构的1-（3,3-二甲基-2-降冰片基）-2-丙酮（以下称为“降冰片基丙酮衍生物”）的阳离子，阴离子和非离子洗涤剂和皂的方法和组合物， （该结构旨在涵盖“endo”和“exo”异构体）。 将所述“降冰片基丙酮衍生物”加入到皂和阳离子，阴离子和非离子洗涤剂中可以产生甜味，浆果，木质，松树，薄荷香气，具有大马士革样特征和黄油和细小的细微差别。

公开(公告)号：US4102763A

公开(公告)日：1978-07-25

申请号：US819952

申请日：1977-07-28

申请人： William L. Schreiber ,  James N. Siano ,  Manfred Hugo Vock ,  Edward J. Shuster

发明人： William L. Schreiber ,  James N. Siano ,  Manfred Hugo Vock ,  Edward J. Shuster

IPC分类号： C07C45/00 ,  C07C49/115 ,  C11B9/00 ,  B01J1/10

CPC分类号： C11B9/0046 ,  C07C45/00 ,  C07C49/115

摘要： Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma and perfume aroma augmenting, enhancing, modifying and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of 1-(3,3-dimethyl-2-norbornyl)-2-propanone (hereinafter referred to as the "norbornylpropanone derivative") having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof). Addition of the said "norbornylpropanone derivative" to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavorings, chewing gums, toothpastes and medicinal products, fruity/berry, pine needle-like aromas and sweet, fruity/berry, blueberry-like, pine needle-like, pine balsam flavor characteristics; and(b) In perfumes, colognes and perfumed articles, sweet, berry, woody, piney, mint aroma notes with a damascenone-like character and buttery and minty nuances.

摘要翻译： 描述了用于食品，口香糖，牙膏和药用产品风味和芳香和香料香气的方法和组合物，其增强，增强，改性和赋予组合物以及作为食品，口香糖，牙膏，药用产品，香料和香料制品香气赋予 具有以下结构的1-（3,3-二甲基-2-降冰片基）-2-丙酮（以下称为“降冰片基丙酮衍生物”）的材料（其结构旨在涵盖“内在”和“ 其“外”异构体）。 将所述“降冰片基丙酮衍生物”添加到消耗材料中可以产生：

公开(公告)号：US07550417B2

公开(公告)日：2009-06-23

申请号：US12065390

申请日：2006-09-08

申请人： Jerzy A. Bajgrowicz ,  Iris Frank

发明人： Jerzy A. Bajgrowicz ,  Iris Frank

IPC分类号： C11D3/50

CPC分类号： C07C33/14 ,  C07C43/162 ,  C07C47/115 ,  C07C47/225 ,  C07C49/115 ,  C07C49/21 ,  C07C2603/66 ,  C07D311/96

摘要： The use as fragrance ingredient of a compound of formula (I) wherein R1 and Y have the same meaning as given in the description, and fragrance applications comprising them.

摘要翻译： 用作式（I）化合物的芳香成分，其中R1和Y具有与说明书中给出的相同的含义，以及包含它们的香料应用。