公开(公告)号：US20240327570A1

公开(公告)日：2024-10-03

申请号：US18199029

申请日：2023-05-18

申请人： Yijin Kang ,  Ruya Zhang

发明人： Yijin Kang ,  Ruya Zhang

IPC分类号： C08G63/16 ,  C07D307/68 ,  C08G63/83

CPC分类号： C08G63/16 ,  C07D307/68 ,  C08G63/83

摘要： Herein, we enable a record-high FDCA reaction rate of 416 μmol h-1 cm-2 (1872 μmol h-1) at 100% FDCA selectivity using a ZnCo2O4 electrocatalyst in a near-neutral media that allows high concentration (i.e. 1M) of HMF, with assistance of an in-situ alkaline modification strategy that further enhances the reaction rate. In the light of the significantly improved FDCA production, we demonstrate production of PEF bioplastic from a biomass-derivative fructose, highly competitive to the petroleum-based production of PET plastics as indicated by our techno-economic analysis.

公开(公告)号：US20160089658A1

公开(公告)日：2016-03-31

申请号：US14502825

申请日：2014-09-30

申请人： Nemanja Danilovic ,  Yijin Kang ,  Nenad Markovic ,  Vojislav Stamenkovic ,  Deborah J. Myers ,  Ram Subbaraman

发明人： Nemanja Danilovic ,  Yijin Kang ,  Nenad Markovic ,  Vojislav Stamenkovic ,  Deborah J. Myers ,  Ram Subbaraman

IPC分类号： B01J23/46 ,  B01J37/12 ,  B01J37/08 ,  C25B13/04 ,  B01J37/14 ,  B01J37/03 ,  B01J35/02 ,  C25B9/08 ,  B01J37/16 ,  B01J37/18

CPC分类号： B01J23/468 ,  B01J35/0013 ,  B01J35/0033 ,  B01J35/008 ,  B01J35/023 ,  B01J37/031 ,  B01J37/08 ,  B01J37/12 ,  B01J37/14 ,  B01J37/16 ,  B01J37/18 ,  C25B9/08 ,  C25B11/04 ,  C25B13/04

摘要： A surface segregated bimetallic composition of the formula Ru1-xIrx wherein 0.1≦x≦0.75, wherein a surface of the material has an Ir concentration that is greater than an Ir concentration of the material as a whole is provided. The surface segregated material may be produced by a method including heating a bimetallic composition of the formula Ru1-xIrx, wherein 0.1≦x≦0.75, at a first temperature in a reducing environment, and heating the composition at a second temperature in an oxidizing environment. The surface segregated material may be utilized in electrochemical devices.

摘要翻译： 提供式Ru1-xIrx的表面偏析的双金属组合物，其中0.1和nlE; x和nlE; 0.75，其中材料的表面的Ir浓度大于整个材料的Ir浓度。 表面偏析材料可以通过包括在还原环境中的第一温度下加热式Ru1-xIrx的双金属组合物，其中0.1＆lt; 1E＆gt; x＆nlE; 0.75的方法制备，并且在第二温度下在氧化 环境。 表面分离的材料可用于电化学装置中。