公开(公告)号：US3734684A

公开(公告)日：1973-05-22

申请号：US3734684D

申请日：1971-05-07

申请人： US AGRICULTURE

发明人： DONALDSON D ,  DAIGLE D ,  DRAKE G ,  REEVES W ,  BENINATE J

IPC分类号： C14C9/00 ,  D06M15/431 ,  D06M15/667 ,  D06M13/28

CPC分类号： C14C9/00 ,  D06M15/431 ,  D06M15/667

摘要： METHYLOL PHOSPHINE, METHYLOL PHOSPHINES IN COMBINATION WITH NITROGENOUS COMPOUNDS OR WATER SOLUBLE ADDUCTS OF THE PHOSPHINE AND NITROGENOUS COMPOUNDS ARE USED TO TREAT ORGANIC FIBROUS DERIVATIVES CONTAINING PRIMARY AND/OR SECONDARY AMINO GROUPS SUCH AS WOOL, LEATHER, NYLON AND AMINIZED COTTONS, ETC., TO PRODUCE FIBROUS DERIVATIVES WHICH ARE FLOW-, WRINKLE-, ROT- AND SHRINK-RESISTANT.

公开(公告)号：US3844824A

公开(公告)日：1974-10-29

申请号：US30677472

申请日：1972-11-15

申请人： US AGRICULTURE

发明人： REEVES W ,  DONALDSON D ,  BENINATE J ,  DAIGLE D ,  DRAKE G

IPC分类号： C07F9/50 ,  C07F9/53 ,  C08G79/02 ,  D06M15/431 ,  D06M15/673 ,  C09D5/18

CPC分类号： D06M15/673 ,  C07F9/5004 ,  C07F9/5304 ,  C08G79/02 ,  D06M15/431 ,  Y10S428/921 ,  Y10T442/268

摘要： Soluble methylol phosphine adducts which contain one or more methylol phosphine radicals (PCH2OH) are prepared by reacting in a suitable solvent tris(hydroxymethyl)phosphine with an amide or amine which contains one or more hydrogens attached to trivalent nitrogen. These soluble adducts are particularly valuable for the preparation of thermosetting flame resistant polymers by reacting them with nitrogenous compounds which contain two or more hydrogen and methylol groups attached to trivalent nitrogen. The adducts are also valuable for the preparation of flame-, glow-, wrinkle-, and shrink-resistant knit and woven textiles by causing the adducts to react with nitrogenous compounds in or on the textile structure by application of heat.

摘要翻译： 含有一个或多个羟甲基膦基（PCH 2 OH）的可溶性羟甲基膦加合物通过在合适的溶剂中将三（羟甲基）膦与含有一个或多个与三价氮连接的氢的酰胺或胺反应来制备。 这些可溶性加合物通过与含有两个或多个连接到三价氮的氢和羟甲基的含氮化合物反应来制备热固性阻燃聚合物是特别有价值的。 加合物对于制备阻燃，发光，抗皱和抗收缩的针织和纺织织物也是有价值的，它们通过加热使加合物与织物结构中或其上的含氮化合物反应。