公开(公告)号：US08524839B2

公开(公告)日：2013-09-03

申请号：US13290403

申请日：2011-11-07

申请人： Yoshinobu Kadowaki ,  Satoshi Niiyama ,  Naoko Aoki

发明人： Yoshinobu Kadowaki ,  Satoshi Niiyama ,  Naoko Aoki

IPC分类号： C08F283/12 ,  C08G59/02

CPC分类号： C09J4/06 ,  B32B17/10697 ,  B32B17/10706 ,  B32B17/1077 ,  B32B17/10908 ,  C08F283/008 ,  C08G18/4833 ,  C08G18/4841 ,  C08G18/4866 ,  C08G18/672 ,  C08G18/73 ,  C08G18/755 ,  Y10T428/31551 ,  C08G18/48

摘要： A transparent laminate having good transparency and good adhesion to transparent substrates, and containing a cured resin layer having excellent tear resistance. A process of producing a transparent laminate by interposing a curable resin composition containing an unsaturated urethane oligomer (A) which is a reaction product of a polyol component (A1) containing a polyol (a1) having from 2 to 3 hydroxy groups, a hydroxy value of 15 to 30 mgKOH/g and an oxyethylene group content of 8 to 50 mass %, a polyisocyanate (A2) and an unsaturated hydroxy compound (A3) or a reaction product of a polyol component (A1) and an unsaturated isocyanate (A4), and a monomer (B) represented by CH2═C(R)C(O)O—R2 (wherein R is a hydrogen atom or a methyl group, and R2 is a C3-4 hydroxyalkyl group having 1 to 2 hydroxy groups), between a pair of transparent substrates, and curing the curable resin composition.

摘要翻译： 透明的层叠体，透明性好，对透明基板的附着性良好，并且含有耐撕裂性优良的固化树脂层。 通过插入含有不饱和氨基甲酸酯低聚物（A）的固化性树脂组合物制造透明层压体的方法，该不饱和聚氨酯低聚物（A）是含有具有2-3个羟基的多元醇（a1）的多元醇组分（A1）的反应产物，羟值 15〜30mgKOH / g，氧化乙烯基含量为8〜50质量％，多异氰酸酯（A2）和不饱和羟基化合物（A3）或多元醇成分（A1）和不饱和异氰酸酯（A4）的反应产物， 和由CH 2 = C（R）C（O）O-R 2（其中R为氢原子或甲基，R 2为具有1〜2个羟基的C 3-4的羟基烷基）表示的单体（B） 在一对透明基板之间，并固化该可固化树脂组合物。

公开(公告)号：US20120183721A1

公开(公告)日：2012-07-19

申请号：US13428388

申请日：2012-03-23

申请人： Satoshi Niiyama ,  Hiroshige Ito ,  Mika Kambe ,  Naoko Aoki ,  Hitoshi Tsushima

发明人： Satoshi Niiyama ,  Hiroshige Ito ,  Mika Kambe ,  Naoko Aoki ,  Hitoshi Tsushima

IPC分类号： B32B3/08 ,  B29C45/14

CPC分类号： C08F290/067 ,  B32B2457/20 ,  C08F220/00 ,  Y10T428/239 ,  C08F220/28 ,  C08F220/62

摘要： Provided is a process for producing a display apparatus, which comprises (a) a step of forming a seal part made of e.g. a double-sided adhesive tape 12 on the edge of a surface of a display device 50 (a first plate), (b) a step of supplying a liquid photocurable resin composition 14 to a region enclosed by the seal part, (c) a step of laminating, in a reduced-pressure atmosphere of not more than 100 Pa, a transparent plate 10 (a second plate) on the photocurable resin composition 14 thereby to obtain a laminated precursor having the photocurable resin composition 14 hermetically sealed, and (d) a step of curing the photocurable resin composition 14 in such a state that the laminated precursor is placed in a pressure atmosphere of not less than 50 kPa to form a resin layer.

摘要翻译： 本发明提供一种显示装置的制造方法，其特征在于，包括：（a） 在显示装置50（第一板）的表面的边缘上的双面胶带12，（b）将液体光固化性树脂组合物14供给到由密封部包围的区域的步骤，（c） 在光固化树脂组合物14上的透明板10（第二板）中，在不大于100Pa的减压气氛中层压步骤，得到密封有光固化性树脂组合物14的层叠前体，（d ）在将层压前体置于不低于50kPa的压力气氛中形成树脂层的状态下固化光固化性树脂组合物14的工序。

公开(公告)号：US08592039B2

公开(公告)日：2013-11-26

申请号：US13555778

申请日：2012-07-23

申请人： Satoshi Niiyama ,  Naoko Aoki

发明人： Satoshi Niiyama ,  Naoko Aoki

IPC分类号： B32B27/40 ,  B32B37/12

CPC分类号： C08F290/06 ,  B32B17/10293 ,  B32B17/10697 ,  B32B17/1077 ,  B32B17/10816 ,  C03C27/10 ,  C08F283/006 ,  C08F290/062 ,  Y10T428/31551 ,  Y10T428/31601 ,  C08F220/26 ,  C08F220/18

摘要： To provide a transparent laminate having a pair of transparent substrates integrated via an adhesive layer, in which the adhesive layer has good tear resistance and good adhesion to the transparent substrates and has excellent transparency.In a first atmosphere, a sealed space having a curable resin composition 14 accommodated between a pair of transparent substrates 10a and 10b, is formed, and then the curable resin composition 14 is cured in a state where the outside of the sealed space is made to be a second atmosphere having a pressure higher than the first atmosphere. As the above curable resin composition, a curable resin composition comprising a urethane oligomer (a) having from 1.8 to 4 curable functional groups on average which are either or both of an acryloyloxy group and a methacryloyloxy group, per molecule, and a hydroxyalkyl methacrylate (b) having a C3-8 hydroxyalkyl group having 1 or 2 hydroxy groups, is used.

摘要翻译： 为了提供一种具有通过粘合剂层一体化的一对透明基板的透明层压体，其中粘合剂层具有良好的抗撕裂性和对透明基材的良好粘附性并且具有优异的透明度。 在第一气氛中，形成容纳在一对透明基板10a和10b之间的具有固化性树脂组合物14的密封空间，然后在使密封空间的外部成为 是具有高于第一气氛的压力的第二气氛。 作为上述固化性树脂组合物，可以使用含有平均具有丙烯酰氧基和甲基丙烯酰氧基的丙烯酰氧基和甲基丙烯酰氧基的平均1.8〜4个固化性官能团的氨基甲酸酯低聚物（a）和甲基丙烯酸羟烷基酯（ b）具有具有1或2个羟基的C 3-8羟基烷基。

公开(公告)号：US08268447B2

公开(公告)日：2012-09-18

申请号：US12692701

申请日：2010-01-25

申请人： Satoshi Niiyama ,  Naoko Aoki

发明人： Satoshi Niiyama ,  Naoko Aoki

IPC分类号： B32B27/40 ,  B32B37/12 ,  C08F20/34 ,  C08F2/46

CPC分类号： C08F290/06 ,  B32B17/10293 ,  B32B17/10697 ,  B32B17/1077 ,  B32B17/10816 ,  C03C27/10 ,  C08F283/006 ,  C08F290/062 ,  Y10T428/31551 ,  Y10T428/31601 ,  C08F220/26 ,  C08F220/18

摘要： To provide a transparent laminate having a pair of transparent substrates integrated via an adhesive layer, in which the adhesive layer has good tear resistance and good adhesion to the transparent substrates and has excellent transparency.In a first atmosphere, a sealed space having a curable resin composition 14 accommodated between a pair of transparent substrates 10a and 10b, is formed, and then the curable resin composition 14 is cured in a state where the outside of the sealed space is made to be a second atmosphere having a pressure higher than the first atmosphere. As the above curable resin composition, a curable resin composition comprising a urethane oligomer (a) having from 1.8 to 4 curable functional groups on average which are either or both of an acryloyloxy group and a methacryloyloxy group, per molecule, and a hydroxyalkyl methacrylate (b) having a C3-8 hydroxyalkyl group having 1 or 2 hydroxy groups, is used.

摘要翻译： 为了提供一种具有通过粘合剂层一体化的一对透明基板的透明层压体，其中粘合剂层具有良好的抗撕裂性和对透明基材的良好粘附性并且具有优异的透明度。 在第一气氛中，形成容纳在一对透明基板10a和10b之间的具有固化性树脂组合物14的密封空间，然后在使密封空间的外部成为 是具有高于第一气氛的压力的第二气氛。 作为上述固化性树脂组合物，可以使用含有平均具有丙烯酰氧基和甲基丙烯酰氧基的丙烯酰氧基和甲基丙烯酰氧基的平均1.8〜4个固化性官能团的氨基甲酸酯低聚物（a）和甲基丙烯酸羟烷基酯（ b）具有具有1或2个羟基的C 3-8羟基烷基。

公开(公告)号：US20060291030A1

公开(公告)日：2006-12-28

申请号：US11472349

申请日：2006-06-22

申请人： Satoshi Niiyama ,  Hiroshige Ito ,  Naoko Aoki

发明人： Satoshi Niiyama ,  Hiroshige Ito ,  Naoko Aoki

IPC分类号： G02B26/00

CPC分类号： G02F1/133502 ,  E06B9/24 ,  G02F1/133305 ,  G02F1/13336 ,  G02F1/15 ,  G02F1/153 ,  G02F2202/025 ,  G02F2202/28

摘要： The light control device can improve visibility at the side faces of the pair of transparent substrates with transparent electrodes held in the gap between two transparent plates, irrespective of the number of the optical elements installed in the light control device. A light control device 10 according to the present invention comprises a plurality of optical elements 3 between two transparent plates 1, 2, in each of which a pair of transparent substrates 31, 32 with transparent electrodes 33, 34 are located so as to face each other and a light control layer 35 capable of changing the light transmitting state by electrically controlling the pair of transparent electrodes 33, 34 is disposed between the pair of transparent electrodes, wherein a transparent solid layer 8 is filled in a space formed in the gap between the two transparent plates 1, 2 and the transparent substrates 31, 32 have taper-shaped side faces.

摘要翻译： 光控制装置可以在保持在两个透明板之间的间隙中的透明电极的一侧的透明基板的侧面上的可视性提高，而与安装在光控制装置中的光学元件的数量无关。 根据本发明的光控制装置10包括在两个透明板1,2之间的多个光学元件3，每个透明板1,2中的每一个具有透明电极33,34的透明基板31,32分别位于每个 通过电气控制一对透明电极33,34能够改变透光状态的光控制层35设置在一对透明电极之间，其中透明固体层8填充在形成在间隙中的空间中 两个透明板1,2和透明基板31,32具有锥形侧面。

公开(公告)号：US08310649B2

公开(公告)日：2012-11-13

申请号：US13428388

申请日：2012-03-23

申请人： Satoshi Niiyama ,  Hiroshige Ito ,  Mika Kambe ,  Naoko Aoki ,  Hitoshi Tsushima

发明人： Satoshi Niiyama ,  Hiroshige Ito ,  Mika Kambe ,  Naoko Aoki ,  Hitoshi Tsushima

IPC分类号： G02F1/13

CPC分类号： C08F290/067 ,  B32B2457/20 ,  C08F220/00 ,  Y10T428/239 ,  C08F220/28 ,  C08F220/62

摘要： Provided is a process for producing a display apparatus, which comprises (a) a step of forming a seal part made of e.g. a double-sided adhesive tape 12 on the edge of a surface of a display device 50 (a first plate), (b) a step of supplying a liquid photocurable resin composition 14 to a region enclosed by the seal part, (c) a step of laminating, in a reduced-pressure atmosphere of not more than 100 Pa, a transparent plate 10 (a second plate) on the photocurable resin composition 14 thereby to obtain a laminated precursor having the photocurable resin composition 14 hermetically sealed, and (d) a step of curing the photocurable resin composition 14 in such a state that the laminated precursor is placed in a pressure atmosphere of not less than 50 kPa to form a resin layer.

摘要翻译： 本发明提供一种显示装置的制造方法，其特征在于，包括：（a） 在显示装置50（第一板）的表面的边缘上的双面胶带12，（b）将液体光固化性树脂组合物14供给到由密封部包围的区域的步骤，（c） 在光固化树脂组合物14上的透明板10（第二板）中，在不大于100Pa的减压气氛中层压步骤，得到密封有光固化性树脂组合物14的层叠前体，（d ）在将层压前体置于不低于50kPa的压力气氛中形成树脂层的状态下固化光固化性树脂组合物14的工序。

公开(公告)号：US20120121914A1

公开(公告)日：2012-05-17

申请号：US13290403

申请日：2011-11-07

申请人： Yoshinobu Kadowaki ,  Satoshi Niiyama ,  Naoko Aoki

发明人： Yoshinobu Kadowaki ,  Satoshi Niiyama ,  Naoko Aoki

IPC分类号： B32B27/40 ,  B29C65/48 ,  C09J175/04

CPC分类号： C09J4/06 ,  B32B17/10697 ,  B32B17/10706 ,  B32B17/1077 ,  B32B17/10908 ,  C08F283/008 ,  C08G18/4833 ,  C08G18/4841 ,  C08G18/4866 ,  C08G18/672 ,  C08G18/73 ,  C08G18/755 ,  Y10T428/31551 ,  C08G18/48

摘要： A transparent laminate having good transparency and good adhesion to transparent substrates, and containing a cured resin layer having excellent tear resistance. A process of producing a transparent laminate by interposing a curable resin composition containing an unsaturated urethane oligomer (A) which is a reaction product of a polyol component (A1) containing a polyol (a1) having from 2 to 3 hydroxy groups, a hydroxy value of 15 to 30 mgKOH/g and an oxyethylene group content of 8 to 50 mass %, a polyisocyanate (A2) and an unsaturated hydroxy compound (A3) or a reaction product of a polyol component (A1) and an unsaturated isocyanate (A4), and a monomer (B) represented by CH2═C(R)C(O)O—R2 (wherein R is a hydrogen atom or a methyl group, and R2 is a C3-4 hydroxyalkyl group having 1 to 2 hydroxy groups), between a pair of transparent substrates, and curing the curable resin composition.

摘要翻译： 透明的层叠体，透明性好，对透明基板的附着性良好，并且含有耐撕裂性优良的固化树脂层。 通过插入含有不饱和氨基甲酸酯低聚物（A）的固化性树脂组合物制造透明层压体的方法，该不饱和聚氨酯低聚物（A）是含有具有2-3个羟基的多元醇（a1）的多元醇组分（A1）的反应产物，羟值 15〜30mgKOH / g，氧化乙烯基含量为8〜50质量％，多异氰酸酯（A2）和不饱和羟基化合物（A3）或多元醇成分（A1）和不饱和异氰酸酯（A4）的反应产物， ，和由CH 2 = C（O）O-R 2（其中R为氢原子或甲基，R 2为具有1〜2个羟基的C 3-4的羟基烷基）表示的单体（B） 在一对透明基板之间，并固化该可固化树脂组合物。

公开(公告)号：US20100189932A1

公开(公告)日：2010-07-29

申请号：US12692701

申请日：2010-01-25

申请人： Satoshi Niiyama ,  Naoko Aoki

发明人： Satoshi Niiyama ,  Naoko Aoki

IPC分类号： B32B3/06 ,  C08F20/34 ,  C08F2/46 ,  B32B37/12

CPC分类号： C08F290/06 ,  B32B17/10293 ,  B32B17/10697 ,  B32B17/1077 ,  B32B17/10816 ,  C03C27/10 ,  C08F283/006 ,  C08F290/062 ,  Y10T428/31551 ,  Y10T428/31601 ,  C08F220/26 ,  C08F220/18

摘要： To provide a transparent laminate having a pair of transparent substrates integrated via an adhesive layer, in which the adhesive layer has good tear resistance and good adhesion to the transparent substrates and has excellent transparency.In a first atmosphere, a sealed space having a curable resin composition 14 accommodated between a pair of transparent substrates 10a and 10b, is formed, and then the curable resin composition 14 is cured in a state where the outside of the sealed space is made to be a second atmosphere having a pressure higher than the first atmosphere. As the above curable resin composition, a curable resin composition comprising a urethane oligomer (a) having from 1.8 to 4 curable functional groups on average which are either or both of an acryloyloxy group and a methacryloyloxy group, per molecule, and a hydroxyalkyl methacrylate (b) having a C3-8 hydroxyalkyl group having 1 or 2 hydroxy groups, is used.

摘要翻译： 为了提供一种具有通过粘合剂层一体化的一对透明基板的透明层压体，其中粘合剂层具有良好的抗撕裂性和对透明基材的良好粘附性并且具有优异的透明度。 在第一气氛中，形成容纳在一对透明基板10a和10b之间的具有固化性树脂组合物14的密封空间，然后在使密封空间的外部成为 是具有高于第一气氛的压力的第二气氛。 作为上述固化性树脂组合物，可以使用含有平均具有丙烯酰氧基和甲基丙烯酰氧基的丙烯酰氧基和甲基丙烯酰氧基的平均1.8〜4个固化性官能团的氨基甲酸酯低聚物（a）和甲基丙烯酸羟烷基酯（ b）具有具有1或2个羟基的C 3-8羟基烷基。

公开(公告)号：US07505188B2

公开(公告)日：2009-03-17

申请号：US11472349

申请日：2006-06-22

申请人： Satoshi Niiyama ,  Hiroshige Ito ,  Naoko Aoki

发明人： Satoshi Niiyama ,  Hiroshige Ito ,  Naoko Aoki

IPC分类号： G02B26/00 ,  G09G3/36

CPC分类号： G02F1/133502 ,  E06B9/24 ,  G02F1/133305 ,  G02F1/13336 ,  G02F1/15 ,  G02F1/153 ,  G02F2202/025 ,  G02F2202/28

摘要： A light control device according to the present invention comprises a plurality of optical elements between two transparent plates in each of which a pair of transparent substrates having taper-shaped side faces with transparent electrodes are located so as to face each other, and a light control layer capable of changing the light transmitting state by electrically controlling the pair of transparent electrodes is disposed between the pair of transparent electrodes, and further, a transparent solid layer is filled in a space formed in the gap between the two transparent plates.

摘要翻译： 根据本发明的光控制装置包括在两个透明板之间的多个光学元件，每个透明板之间具有一对具有带有透明电极的锥形侧面的透明基板以彼此面对，并且光控制 通过电控制一对透明电极而能够改变透光状态的层被设置在一对透明电极之间，此外，透明固体层填充在形成在两个透明板之间的间隙中的空间中。

公开(公告)号：US07011870B2

公开(公告)日：2006-03-14

申请号：US10780643

申请日：2004-02-19

申请人： Satoshi Niiyama ,  Shinya Tahara

发明人： Satoshi Niiyama ,  Shinya Tahara

IPC分类号： C09K19/38 ,  C09K19/52

CPC分类号： C09K19/0403 ,  C09K19/12 ,  C09K19/3852 ,  C09K19/542 ,  C09K2019/0444 ,  C09K2019/0448 ,  G02F2001/13347 ,  Y10T428/10

摘要： A liquid crystal/cured composite layer is formed by sandwiching a mixture of a liquid crystal with an uncured curable compound i.e. a curable compound represented by a structure of an acryloyl group-(OR1)n—O-mesogen structural portion-O—(R2O)m-acryloyl group structure (wherein each of R1 and R2 is a C2-6 alkylene group, and each of n and m is from 1 to 10), between a pair of substrates provided with transparent electrodes, and curing the curable compound.

摘要翻译： 通过将液晶与未固化的固化性化合物的混合物即由丙烯酰基的结构表示的可固化化合物（OR 1 N 1）n n来形成液晶/固化复合层 -O-介晶结构部分-O-（R 2 O）m - 丙烯酰基结构（其中R 1，R 2， R 2是C 2-6亚烷基，n和m各自为1〜10），设置有透明电极的一对基板之间，以及 固化可固化化合物。