公开(公告)号：US20180369790A1

公开(公告)日：2018-12-27

申请号：US16063922

申请日：2016-12-20

Applicant: SHELL OIL COMPANY

Inventor： Andreas KLEMT ,  László DOMOKOS ,  Frank Peter FRIEDEL ,  Stefan BOETTCHER ,  Erwin Roderick STOBBE

IPC: B01J23/75 ,  B01J37/06 ,  B01J37/04 ,  B01J37/03 ,  B01J37/08 ,  B01J37/18 ,  B01J35/00 ,  B01J35/10

Abstract: The invention relates to a method for preparing a hydrogenation catalyst or catalyst precursor comprising a catalytically active material and a carrier material. The method involves the mixing of an acidic solution comprising metal ions of a metal selected from the IUPAC group 8, 9 or 10 metals, preferably cobalt, a suspension comprising the carrier material and an alkaline solution. The invention also relates to a precursor of a hydrogenation catalyst wherein the precursor comprises crystallites of metal oxides having an average size of max. 8 nm.

公开(公告)号：US20180369753A1

公开(公告)日：2018-12-27

申请号：US16064200

申请日：2016-12-20

Applicant: SHELL OIL COMPANY

Inventor： Wassim KLINK ,  Guido SENG ,  Wenzhong ZHANG ,  Andreas KLEMT ,  Paul Benjerman HIMELFARB

IPC: B01D53/86 ,  F01N3/28 ,  B01J35/04 ,  B01J21/16 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30

Abstract: A reactor for reducing the concentration of NO x in a stream comprising: an inlet for the stream; an outlet for a stream containing a reduced concentration of NOx; one or more catalyst beds comprising a ceramic or metallic foam with a NOx reduction catalyst; one or more flow paths from the inlet to the outlet that passes through at least one catalyst bed wherein the catalyst beds are closed at the top and bottom so that the flow path through the catalyst bed passes through the sides of the catalyst bed in a lateral flow is described.

公开(公告)号：US20180369800A1

公开(公告)日：2018-12-27

申请号：US16064240

申请日：2016-12-20

Applicant: SHELL OIL COMPANY

Inventor： Wassim KLINK ,  Guido SENG ,  Wenzhong ZHANG ,  Andreas KLEMT ,  Paul Benjerman HIMELFARB

IPC: B01J35/04 ,  B01J37/00 ,  B01J21/16 ,  B01J21/06 ,  B01J21/04 ,  B01J23/745 ,  B01J23/755 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01D53/86

Abstract: A catalyst bed comprising a ceramic or metallic foam comprising one or more NOx reduction catalysts is described. A method for reducing the concentration of NOx in a dust containing gas stream comprising: a) passing a first gas stream containing NOx into a contacting zone; b) contacting the first gas stream with a ceramic or metallic foam catalyst bed having one or more flow paths through the catalyst bed wherein the ceramic or metallic foam comprises a NOx reduction catalyst to produce a second gas stream with a reduced NOx concentration; and c) passing the second gas stream out of the contacting zone wherein the first gas stream has a dust concentration of at least 5 mg/Nm3 and the pressure drop of the foam catalyst bed increases by 300% or less relative to the initial pressure drop of the foam catalyst bed due to dust accumulation, measured under the same conditions is also described.

公开(公告)号：US20170348677A1

公开(公告)日：2017-12-07

申请号：US15536231

申请日：2015-12-21

Applicant: SHELL OIL COMPANY

Inventor： Andreas KLEMT ,  László DOMOKOS ,  Frank Peter FRIEDEL ,  Stefan BOETTCHER ,  Erwin Roderick STOBBE

IPC: B01J23/889 ,  B01J37/08 ,  B01J37/06 ,  B01J37/04 ,  B01J37/03 ,  B01J37/02 ,  B01J37/00 ,  C10G2/00 ,  B01J35/02

CPC classification number: B01J23/8892 ,  B01J23/74 ,  B01J23/745 ,  B01J23/75 ,  B01J35/023 ,  B01J37/0072 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/035 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/088 ,  B01J37/16 ,  C10G2/332

Abstract: The invention relates to a method for preparing a catalyst or catalyst precursor comprising a catalytically active material and a carrier material. The invention relates to a catalyst particle and catalyst precursor thereof obtainable by said method. The catalyst may be used in a process for synthesising hydrocarbons.

公开(公告)号：US20230374209A1

公开(公告)日：2023-11-23

申请号：US18042613

申请日：2021-09-29

Applicant: SHELL OIL COMPANY

Inventor： Nicoleta Cristina NENU ,  Jieheng GUO ,  Andreas KLEMT ,  Sven SCHOLZ

IPC: C08G64/30 ,  B01J23/44 ,  B01J27/053

CPC classification number: C08G64/305 ,  B01J23/44 ,  B01J27/053 ,  C08G2210/00

Abstract: The present disclosure relates to a method for generating a hydrogel from a CO2 gas stream. The method for converting a CO2 gas stream comprising a CO2 into an ester, comprises the conversion of CO2 into a (COOH)2 preferably by passing the CO2 through a water bath to produce a carbonated water; and passing the carbonated water through a metal ion exchange bubble column comprising a M2(COO)2 to produce the (COOH)2 and a MHCO3; reacting the (COOH)2 with a mono-alcohol to obtain the ester. The invention further relates to a system for converting CO2.

公开(公告)号：US20190001266A1

公开(公告)日：2019-01-03

申请号：US16064169

申请日：2016-12-20

Applicant: SHELL OIL COMPANY

Inventor： Guido SENG ,  Wassim KLINK ,  Wenzhong ZHANG ,  Andreas KLEMT ,  Paul Benjerman HIMELFARB

IPC: B01D53/86

Abstract: A catalyst bed comprising a ceramic or metallic foam comprising one or more NOx reduction catalysts is described. Further, a method for reducing the concentration of NOx in a dust containing gas stream comprising: a) passing a first gas stream containing NOx into a contacting zone; b) contacting the first gas stream with a ceramic or metallic foam catalyst bed having one or more flow paths through the catalyst bed wherein the ceramic or metallic foam comprises a NOx reduction catalyst to produce a second gas stream with a reduced NOx concentration; and c) passing the second gas stream out of the contacting zone wherein the first gas stream has a dust concentration of at least 5 mg/Nm3 and the second gas stream comprises at least 50% of the amount of dust in the first gas stream.

公开(公告)号：US20220177399A1

公开(公告)日：2022-06-09

申请号：US17523161

申请日：2021-11-10

Applicant: SHELL OIL COMPANY

Inventor： Andreas KLEMT ,  Sven SCHOLZ

IPC: C07C51/02 ,  C01D7/07 ,  C07C51/41 ,  C25B1/04 ,  C25B1/26

Abstract: A method for generating a carboxylic acid from carbon dioxide (CO2), the method includes (a) feeding a gas stream having the CO2 to a first reactor having a base (MOH) to produce bicarbonate (MHCO3) and (b) feeding the MHCO3 generated in the first reactor to a second reactor disposed downstream from the first reactor. The second reactor includes a catalyst. The method also includes (c) contacting the MHCO3 with hydrogen gas in the presence of the catalyst in the second reactor to produce formate (HCOOM) and (d) electrolysing an aqueous solution of a metal halide (MCl) in a chloro-alkali electrolysis reactor fluidly coupled to the first reactor, the second reactor, or both to produce at least a portion of the MOH, the hydrogen gas and Cl2. The portion of the MOH is used in step (a) and the carboxylic acid is formic acid (HCOOH).

公开(公告)号：US20220111334A1

公开(公告)日：2022-04-14

申请号：US17466206

申请日：2021-11-22

Applicant: SHELL OIL COMPANY

Inventor： Wassim KLINK ,  Guido SENG ,  Wenzhong ZHANG ,  Andreas KLEMT ,  Paul Benjerman HIMELFARB

IPC: B01D53/86 ,  B01D53/94 ,  B01J21/16 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/04 ,  F01N3/28

Abstract: A reactor for reducing the concentration of NOx in a stream comprising: an inlet for the stream; an outlet for a stream containing a reduced concentration of NOx ; one or more catalyst beds comprising a ceramic or metallic foam with a NOx reduction catalyst; one or more flow paths from the inlet to the outlet that passes through at least one catalyst bed wherein the catalyst beds are closed at the top and bottom so that the flow path through the catalyst bed passes through the sides of the catalyst bed in a lateral flow is described.

公开(公告)号：US20200230580A1

公开(公告)日：2020-07-23

申请号：US16743693

申请日：2020-01-15

Applicant: SHELL OIL COMPANY

Inventor： Tobias HERZFELD ,  Andreas KLEMT ,  Sven SCHOLZ

IPC: B01J23/66 ,  B01J23/44 ,  B01J37/02 ,  B01J35/08 ,  C10G45/34 ,  B01J35/02

Abstract: Presented is a selective hydrogenation catalyst and a method of making the catalyst. The catalyst comprises a carrier containing bi-metallic nanoparticles. The nanoparticles comprise a silver component and a palladium component. The catalyst is made by incorporating an aqueous dispersion of the bi-metallic nanoparticles onto a catalyst carrier followed by drying and calcining the carrier having incorporated therein the dispersion. The catalyst is used in the selective hydrogenation of highly unsaturated hydrocarbons contained olefin product streams.

公开(公告)号：US20180141032A1

公开(公告)日：2018-05-24

申请号：US15580482

申请日：2016-06-07

Applicant: SHELL OIL COMPANY

Inventor： Frank Peter FRIEDEL ,  Wolfgang Dirk LOSE ,  Andreas KLEMT

IPC: B01J37/03 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  B01J37/18 ,  B01J23/72 ,  B01J21/06 ,  C07C29/145 ,  C07C33/22

CPC classification number: B01J37/031 ,  B01J21/06 ,  B01J23/72 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/18 ,  B01J2231/643 ,  C07C29/145 ,  C07C33/22 ,  C07C2523/72

Abstract: The invention relates to a process for preparing a catalyst, which comprises: mixing a copper salt containing solution with a silicate salt containing composition resulting in a precipitated solid; and subjecting the precipitated solid to a temperature in the range of from 150 to 500° C. Further, the invention relates to a copper containing catalyst obtainable by said process. Still further, the invention relates to a hydrogenation process wherein such copper containing catalyst is used, more in particular a process wherein methyl phenyl ketone is hydrogenated into methyl phenyl carbinol.