Abstract:
An ultrasonic measurement system performs a signal path measurement by directing ultrasonic signals through a gaseous material in a conduit, and processing the detected signals to determine sound speed and to derive the average molecular weight of an unknown hydrocarbon mixture present in the material. The processor includes a plurality of stored tables of critical constants of hydrocarbon mixtures as a function of the average molecular weight of the mixture, and is configured to iteratively set a hypothetical molecular weight, determine the corresponding critical properties, and compute a predicted sound speed. If the two speeds differ, a new weight is set and the procedure is repeated until the predicted sound speed matches the measured speed, indicating that the current estimate is the correct average molecular weight. Once the processor has determined the critical constants from its stored tables, it applies the virial equation of state and mixing rules to determine the predicted sound speed for each hypothetical molecular weight of an unknown mixture of hydrocarbons present, together with one or more known inorganic components, in the fluid material. The processor may be configured for user input of known quantities of one or more gases such as nitrogen, hydrogen, sulfur dioxide, carbon dioxide or other inorganic or non-hydrocarbon gases present in the conduit. Alternatively, all or some of this data may be provided in an automated manner from suitable signals, settings or measurements from upstream conduits, valves or measurement and control instrumentation.
Abstract:
A thin film of material having a rock-salt-like structure is deposited on a smooth amorphous substrate surface by ion beam assisted deposition.
Abstract:
The present invention is directed towards a process and apparatus for epitaxial deposition of a material, e.g., a layer of MgO, onto a substrate such as a flexible metal substrate, using dual ion beams for the ion beam assisted deposition whereby thick layers can be deposited without degradation of the desired properties by the material. The ability to deposit thicker layers without loss of properties provides a significantly broader deposition window for the process.
Abstract:
A method for determining the presence, during deposition of a first thin m layer, of a substance which escapes when the layer is cooled and transferred from its deposition environment for analysis to determine the presence of the substance. The layer is first covered with a second layer of a material which captures the escaping substance. This second layer is then covered with a cap layer of a substance which seals the second layer against contamination, as from the atmosphere during transfer. The layered structure, with the escaped substance retained in the second layer, is then analyzed, as by sputter depth profiling and Auger electron spectroscopy, to determine the presence in the second layer of the escaped substance and thus determine the presence of this substance during deposition of the first layer.
Abstract:
An oxygen sensor has a sensor body formed of a crystalline material, such as zirconia, with first and second electrodes disposed on a single surface thereof. The electrodes are arranged to induce superionic oxygen transport in the body along current paths extending at a shallow depth in the crystalline material at the electrode surface. The electrodes may be interdigitated or juxtaposed porous electrodes that define an exposed surface pattern of ionic conduction for sensing, and the electrodes are preferably poisoned to inhibit cross sensitivity to reactive components, such as hydrogen, that may be present in the environment. The electrodes may effect electrode-limited superionic conduction in a thin slice of single crystal material, or a polycrystalline yttria-stabilized zirconia film sensing body, and operate at a relatively low temperature in the range of 250-400° C., preferably about 300-350° C., with negligible leakage current or cross sensitivity, allowing reliable measurement of oxygen concentrations in the ppb range. The oxygen sensor may be fabricated together with a heater, such as a resistive heating element, deposited on the back face of the sensor body, or the sensor body may be attached to a heater chip. One such heater chip includes both a heating electrode, and a resistive thermal device that may, for example, provide a feedback or control signal for controlling heater temperature in the desired range. The sensors may be lithographically formed in arrays with suitable lead pads, then scored and separated, and mounted on heater chips, providing a self-contained integrated unit of versatile application.
Abstract:
An atomic absorption apparatus using a laser for producing a light beam having a characteristic frequency f, typically ranging from several MHz to several GHz, and a characteristic polarization for measuring the absorption of that light beam by atoms of interest. The apparatus has a modulator to generate a modulating signal to modulate the characteristic frequency f and produce a phase-modulated light beam. The apparatus includes a domain where the specific atoms are located. This domain is positioned in the path of the phase-modulated light beam such that the phase-modulated light beam encounters the specific atoms when passing through the domain and some of the specific atoms absorb a portion of the phase-modulated light beam. Typically, the domains containing the atoms of interest include process chambers for vacuum coating, ion milling, sputtering, mass spectroscopy vapor coating or deposition, and the like. The amount of light absorbed depends on the motion of the atoms relative to the phase-modulated light beam.
Abstract:
Flow is described by first variables related to a coordinate system, and by at least one second flow-related variable such as friction factor or Reynolds number unrelated to the coordinate system, wherein the first variables are separable or substantially separable from the second variables. The method includes determining average velocities of the fluid on two paths, or taking a first path measurement and at least one point measurement, selected such that combining the first path measurement and the second measurement forms an expression independent of the second variable. In one embodiment, first and second path measurements are combined in accordance with the velocity relationships given by the Pao equation to produce a flow measurement which is independent of the friction factor. A single calibration then allows the meter to be used on diverse conduits with different wall roughness or friction factor. The system also yields a non-invasive measure of the friction factor. A conventional flow meter may be set up by solving for flow profile and analytically determining a meter factor or appropriate measurement path. The measurements may be combined to eliminate the second variable, or to determine a chord on which the measured velocity equals the mean flow velocity across the conduit cross-sectional area. Alternatively, the two transit times may combined to determine a meter factor, or a known flow profile may be used to determine a single chord along which the transit time measurements relate to flow in a manner independent of the second variable.
Abstract:
A method of forming a superconducting YBa.sub.2 Cu.sub.3 O.sub.7-x thin film with selected crystal orientation is described which comprises the steps of sputtering simultaneously Y, Ba and Cu onto the surface of a substrate, introducing oxygen at said surface during deposition, controlling the stoichiometry of the elements Y, Ba or both richer or poorer than the 1:2:3 stoichiometry within a few atom percent and followed by annealing to selectively grow an a-axis or a c-axis oriented film of YBa.sub.2 Cu.sub.3 O.sub.7-x.