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公开(公告)号:US11139479B2
公开(公告)日:2021-10-05
申请号:US16672333
申请日:2019-11-01
IPC分类号: H01M4/62 , H01M4/131 , H01M10/0525 , H01M4/36 , H01M10/056 , H01M50/46 , H01M10/0562 , H01M4/136 , H01M4/505 , H01M4/525 , H01M4/58 , C01B33/00
摘要: The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. In an example, the catholyte material comprises a lithium, germanium, phosphorous, and sulfur (“LGPS”) containing material configured in a polycrystalline state. The device has an oxygen species configured within the LGPS containing material, the oxygen species having a ratio to the sulfur species of 1:2 and less to form a LGPSO material. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the LiaMPbSc (LMPS) [M=Si,Ge, and/or Sn] containing material.
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公开(公告)号:US11211611B2
公开(公告)日:2021-12-28
申请号:US16421383
申请日:2019-05-23
IPC分类号: H01M4/62 , H01M4/131 , H01M10/0525 , H01M4/36 , H01M10/056 , H01M50/46 , H01M10/0562 , H01M4/136 , H01M4/505 , H01M4/525 , H01M4/58 , C01B33/00
摘要: The present invention provides an energy storage device comprising a cathode region or other element. The device has a major active region comprising a plurality of first active regions spatially disposed within the cathode region. The major active region expands or contracts from a first volume to a second volume during a period of a charge and discharge. The device has a catholyte material spatially confined within a spatial region of the cathode region and spatially disposed within spatial regions not occupied by the first active regions. In an example, the catholyte material comprises a lithium, germanium, phosphorous, and sulfur (“LGPS”) containing material configured in a polycrystalline state. The device has an oxygen species configured within the LGPS containing material, the oxygen species having a ratio to the sulfur species of 1:2 and less to form a LGPSO material. The device has a protective material formed overlying exposed regions of the cathode material to substantially maintain the sulfur species within the catholyte material. Also included is a novel dopant configuration of the LiaMPbSc (LMPS) [M=Si, Ge, and/or Sn] containing material.
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