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公开(公告)号:US20210348285A1
公开(公告)日:2021-11-11
申请号:US17383436
申请日:2021-07-23
申请人: NEMASKA LITHIUM INC.
摘要: There are provided system for preparing lithium hydroxide from an aqueous composition comprising a lithium compound and use of the system thereof to prepare lithium hydroxide, the system comprising an electrochemical cell, a pH probe and at least one inlet for receiving acid or base for maintaining pH. For example, the lithium compound can be lithium sulphate and the aqueous composition can be at least substantially maintained at a pH having a value of about 2 to about 4.
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公开(公告)号:US20200087804A1
公开(公告)日:2020-03-19
申请号:US16579173
申请日:2019-09-23
申请人: NEMASKA LITHIUM INC.
摘要: There are provided processes for preparing lithium hydroxide that comprise submitting an aqueous composition comprising a lithium compound to an electrolysis or an electrodialysis under conditions suitable for converting at least a portion of the lithium compound into lithium hydroxide. For example, the lithium compound can be lithium sulphate and the aqueous composition can be at least substantially maintained at a pH having a value of about 1 to about 4.
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公开(公告)号:US20180222762A1
公开(公告)日:2018-08-09
申请号:US15861587
申请日:2018-01-03
申请人: NEMASKA LITHIUM INC.
摘要: There are provided methods for preparing lithium carbonate. For example, such methods can comprise reacting an aqueous composition comprising lithium hydroxide with CO2 by sparging the CO2 the said composition, thereby obtaining a precipitate comprising the lithium carbonate. The methods can also comprise inserting at least a portion of the precipitate into a clarifier and obtaining a supernatant comprising lithium bicarbonate and a solid comprising the lithium carbonate, separating the solid from the supernatant; and heating the supernatant at a desired temperature so as to at least partially convert the lithium bicarbonate into lithium carbonate.
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公开(公告)号:US20230382753A1
公开(公告)日:2023-11-30
申请号:US18138421
申请日:2023-04-24
申请人: NEMASKA LITHIUM INC.
摘要: There are provided methods for preparing lithium carbonate. For example, such methods can comprise reacting an aqueous composition comprising lithium hydroxide with CO2 by sparging the CO2 the said composition, thereby obtaining a precipitate comprising the lithium carbonate. The methods can also comprise inserting at least a portion of the precipitate into a clarifier and obtaining a supernatant comprising lithium bicarbonate and a solid comprising the lithium carbonate, separating the solid from the supernatant; and heating the supernatant at a desired temperature so as to at least partially convert the lithium bicarbonate into lithium carbonate.
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公开(公告)号:US20230416874A1
公开(公告)日:2023-12-28
申请号:US18213844
申请日:2023-06-25
申请人: NEMASKA LITHIUM INC.
发明人: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , J. David GENDERS , Jean-François MAGNAN , Geneviève CLAYTON
IPC分类号: C22B26/12 , B01D61/42 , C22B3/44 , C01D7/07 , C25B1/16 , B01D61/44 , C25B9/70 , C25B9/19 , C22B4/02 , C25B1/14
CPC分类号: C22B26/12 , B01D61/422 , C22B3/44 , C01D7/07 , C25B1/16 , B01D61/445 , C25B9/70 , C25B9/19 , C22B4/02 , C25B1/14 , Y02E60/36 , C01B2203/0283 , B01D2311/2684
摘要: There are provided processes comprising submitting an aqueous composition comprising lithium sulphate and/or bisulfate to an electrolysis or an electrodialysis for converting at least a portion of said sulphate into lithium hydroxide. During electrolysis or electrodialysis, the aqueous composition is at least substantially maintained at a pH having a value of about 1 to about 4; and converting said lithium hydroxide into lithium carbonate. Alternatively, lithium sulfate and/or lithium bisulfate can be submitted to a first electromembrane process that comprises a two-compartment membrane process for conversion of lithium sulfate and/or lithium bisulfate to lithium hydroxide, and obtaining a first lithium-reduced aqueous stream and a first lithium hydroxide-enriched aqueous stream; and submitting said first lithium-reduced aqueous stream to a second electromembrane process comprising a three-compartment membrane process to prepare at least a further portion of lithium hydroxide and obtaining a second lithium-reduced aqueous stream and a second lithium-hydroxide enriched aqueous stream.
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公开(公告)号:US20190136392A1
公开(公告)日:2019-05-09
申请号:US16053796
申请日:2018-08-03
申请人: Nemaska Lithium Inc.
发明人: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , J. David GENDERS , Jean-François MAGNAN
摘要: There are provided methods for preparing lithium hydroxide. For example, such methods can comprise submitting an aqueous composition comprising a lithium compound to an electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide. There are also provided methods for preparing lithium sulphate.
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公开(公告)号:US20170342573A1
公开(公告)日:2017-11-30
申请号:US15615280
申请日:2017-06-06
申请人: Nemaska Lithium Inc.
发明人: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , J. David GENDERS , Jean-François MAGNAN
CPC分类号: C25B1/16 , B01D61/422 , B01D61/44 , C22B7/006 , C22B26/12
摘要: There are provided methods for preparing lithium hydroxide. For example, such methods can comprise submitting an aqueous composition comprising a lithium compound to an electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide. There are also provided methods for preparing lithium sulphate.
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公开(公告)号:US20160265085A1
公开(公告)日:2016-09-15
申请号:US15031746
申请日:2014-10-23
申请人: NEMASKA LITHIUM INC.
发明人: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , David J. GENDERS , Jean-Frangois MAGNAN , Geneviève CLAYTON
CPC分类号: C22B26/12 , B01D61/422 , B01D61/445 , B01D2311/2684 , C01B2203/0283 , C01D7/07 , C22B3/44 , C22B4/02 , C25B1/14 , C25B1/16 , C25B9/08 , C25B9/18 , Y02E60/366
摘要: There are provided processes comprising submitting an aqueous composition comprising lithium sulphate and/or bisulfate to an electrolysis or an electrodialysis for converting at least a portion of said sulphate into lithium hydroxide. During electrolysis or electrodialysis, the aqueous composition is at least substantially maintained at a pH having a value of about 1 to about 4; and converting said lithium hydroxide into lithium carbonate. Alternatively, lithium sulfate and/or lithium bisulfate can be submitted to a first electromembrane process that comprises a two-compartment membrane process for conversion of lithium sulfate and/or lithium bisulfate to lithium hydroxide, and obtaining a first lithium-reduced aqueous stream and a first lithium hydroxide-enriched aqueous stream; and submitting said first lithium-reduced aqueous stream to a second electromembrane process comprising a three-compartment membrane process to prepare at least a further portion of lithium hydroxide and obtaining a second lithium-reduced aqueous stream and a second lithium-hydroxide enriched aqueous stream.
摘要翻译: 提供的方法包括将包含硫酸锂和/或硫酸氢盐的含水组合物递送到电解或电渗析中,以将至少一部分所述硫酸盐转化为氢氧化锂。 在电解或电渗析期间,水性组合物至少基本上保持在pH为约1至约4的pH; 并将所述氢氧化锂转化为碳酸锂。 或者,硫酸锂和/或硫酸氢锂可以进行第一电子过程,其包括用于将硫酸锂和/或硫酸氢锂转化为氢氧化锂的双室膜工艺,并获得第一锂还原水流和 第一个富含氢氧化锂的水流; 以及将所述第一锂还原水流提交到包括三室膜方法的第二电解方法中,以制备至少另一部分氢氧化锂并获得第二锂还原水流和第二富含氢氧化锂的水流。
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公开(公告)号:US20240229266A1
公开(公告)日:2024-07-11
申请号:US18391687
申请日:2023-12-21
申请人: NEMASKA LITHIUM INC.
发明人: Jean-François MAGNAN , Guy BOURASSA , Gary PEARSE , Peter SYMONS , J. David GENDERS , Daniel BAR , Marie-Eve LANGEVIN
IPC分类号: C25B15/02 , B01D61/44 , C25B1/00 , C25B1/16 , C25B1/22 , C25B9/19 , C25B9/21 , C25B13/02 , C25B13/04 , C25B15/023 , C25B15/027 , C25B15/029 , C25B15/031
CPC分类号: C25B15/02 , B01D61/44 , B01D61/445 , C25B1/00 , C25B1/16 , C25B1/22 , C25B9/19 , C25B9/21 , C25B13/02 , C25B13/04 , C25B15/023 , C25B15/027 , C25B15/029 , C25B15/031 , Y02E60/36
摘要: There are provided system for preparing lithium hydroxide from an aqueous composition comprising a lithium compound and use of the system thereof to prepare lithium hydroxide, the system comprising an electrochemical cell, a pH probe and at least one inlet for receiving acid or base for maintaining pH. For example, the lithium compound can be lithium sulphate and the aqueous composition can be at least substantially maintained at a pH having a value of about 2 to about 4.
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公开(公告)号:US20230080642A1
公开(公告)日:2023-03-16
申请号:US17988957
申请日:2022-11-17
申请人: NEMASKA LITHIUM INC.
发明人: Jean-François MAGNAN , Guy BOURASSA , Nicolas LAROCHE , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , J. David GENDERS , Geneviève CLAYTON , Pierre BOUCHARD
IPC分类号: C25B1/16 , B01D61/42 , B01D61/44 , B01D61/58 , C01D15/02 , C01D15/06 , C22B1/02 , C22B1/06 , C22B3/04 , C22B3/08 , C22B3/20 , C22B3/22 , C22B26/12 , C25B9/70 , B01D61/02
摘要: The present disclosure relates to a method for treating an electromembrane process aqueous composition comprising sodium and/or potassium sulfate, said process comprising removing water from said electromembrane process aqueous composition under conditions suitable for substantially selectively precipitating sodium and/or potassium sulfate monohydrate.
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