METHOD FOR PRODUCING ALIPHATIC-AROMATIC POLYESTER

    公开(公告)号:US20220356301A1

    公开(公告)日:2022-11-10

    申请号:US17868319

    申请日:2022-07-19

    IPC分类号: C08G63/78 C08G63/183

    摘要: Provided is a method for producing an aliphatic-aromatic polyester, such as PBST, by an esterification and/or transesterification reaction and a polycondensation reaction, the method being capable of reducing the insufficiency in the degree of crystallization in the related art and capable of producing an aliphatic-aromatic polyester having a high degree of crystallinity. A method for producing an aliphatic-aromatic polyester, the method including subjecting an aliphatic diol component, an aliphatic dicarboxylic acid component, and an aromatic dicarboxylic acid component that serve as raw materials to an esterification and/or transesterification reaction and a polycondensation reaction subsequent to the esterification and/or transesterification reaction in a presence of a catalyst, wherein, while the aliphatic-aromatic polyester is produced, a nucleating agent that satisfies a condition represented by Formula (1) below is present in a reaction system. 0° C.

    ALIPHATIC-AROMATIC POLYESTER RESIN AND MOLDED ARTICLE THEREOF

    公开(公告)号:US20230140076A1

    公开(公告)日:2023-05-04

    申请号:US18091448

    申请日:2022-12-30

    IPC分类号: C08G63/183 C08G63/85 C08J5/18

    摘要: An aliphatic-aromatic polyester resin comprising principal structural units that includes aliphatic dicarboxylic acid units, aromatic dicarboxylic acid units, and aliphatic diol units and/or alicyclic diol units, wherein an abundance ratio (molar ratio) between the aliphatic dicarboxylic acid units and the aromatic dicarboxylic acid units is 15:85 to 85:15; the aliphatic-aromatic polyester resin has a glass transition temperature of −25° C. or more; and the aliphatic-aromatic polyester resin has branched structures represented by formulae (1) to (4) below: where Ar1, Ar2, and Ar3 each independently represent an optionally substituted divalent group having 4 to 12 carbon atoms, the optionally substituted divalent group being a divalent aromatic hydrocarbon group or a divalent aromatic heterocyclic group; R represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and n, m, and r are each independently an integer of 2 to 10.