摘要:
A magnetic recording medium protected by a very thin, composite low surface energy covering is disclosed. The covering comprises a primer layer of a polymerized phosphorylated monomer or oligomer and an outer lubricant layer of perfluoropolyether polymer. The two layers may be polymerized in situ. The primer layer is made from monomers such as phosphorylated bis[4-methacryloyloxyhydroxypropylcarbamato-cyclohexyl]methane. The outer layer is made from a polymerizable perfluoropolyether monomer such as ##STR1## The composite low surface energy covering is especially useful for providing lubricity and corrosion resistance to a metallic thin-film magnetic recording coating.
摘要:
Polymeric compositions are provided in which perfluoropolyethers have been solubilized in non-fluorinated solvents by combining them with a solubilizing agent such as azotic conjugated compounds, and phosphorylated compounds. Typical of the perfluoropolyethers is ##STR1## Typical of the solubilizing agents is phosphorylated methacryloyloxyhydroxypropylisophthalate. The perfluoropolyether and the solubilizing agent are mixed to form a paste which is soluble in organic solvents such as methylethylketone. These compositions find utility as protective lubricant coatings for thin film magnetic recording media. They have the advantage that only one coating step is required in order to apply both the phosphorylated compound and the lubricating polyether. Recording media lubricated with these compositions have demonstrated excellent wear characteristics.
摘要:
Polymeric compositions are provided in which perfluoropolyethers have been solubilized in non-fluorinated solvents by combining them with a solubilizing agent such as azotic conjugated compounds, and phosphorylated compounds. Typical of the perfluoropolyethers is ##STR1## Typical of the solubilizing agent is phosphorylated methacryloyloxyhydroxypropylisophthalate. The perfluoropolyether and the solubilizing agent are mixed to form a paste which is soluble in organic solvents such as methylethylketone. These compositions find utility as protective lubricant coatings for thin film magnetic recording media. They have the advantage that only one coating step is required in order to apply both the phosphorylated compound and the lubricating polyether. Recording media lubricated with these compositions have demonstrated excellent wear characteristics.
摘要:
Polymeric compositions are provided in which perfluoropolyethers have been solubilized in non-fluorinated solvents by combining them with a solubilizing agent such as azotic conjugated compounds, and phosphorylated compounds. Typical of the perfluoropolyethers is ##STR1## Typical of the solubilizing agents is phosphorylated methacryloyloxyhydroxypropylisophthalate. The perfluoropolyether and the solubilizing agent are mixed to form a paste which is soluble in organic solvents such as methylethylketone. These compositions find utility as protective lubricant coatings for thin film magnetic recording media. They have the advantage that only one coating step is required in order to apply both the phosphorylated compound and the lubricating polyether. Recording media lubricated with these compositions have demonstrated excellent wear characteristics.
摘要:
Electron-beam sensitive monomers contain two to three terminal acryloxy and one intermediate divalent or trivalent hydrocarbylene group the valences of which are respectively linked in each case by at least one of acyloxylene and alkoxycarbonylamidolene units.