摘要:
The present invention is a method of treating nitrogen oxides using an ozone and catalyst hybrid system, as well as an apparatus, specifically relating to a method of treating nitrogen oxide using an ozone and catalyst hybrid system comprising:1) removing moisture from the nitrogen oxide polluted air to be treated; 2) contacting the moisture-removed nitrogen oxide polluted air with ozone to oxidize NO in said polluted air to NO2; 3) reacting the residual ozone with a catalyst to generate oxygen radicals and then, reacting the oxygen radicals with the nitrogen oxide polluted air from step 2) to oxidize NO2 in the polluted air to NO3−. The nitrogen oxide treatment method and apparatus according to the present invention can effectively treat harmful nitrogen oxides, such as NO, NO2, using an ozone and catalyst hybrid system at room temperature without requiring a high temperature reaction or an ammonia gas as a reducing agent. In addition, the method and apparatus according to the present invention can be useful in the removal of nitrogen oxides in various areas because they can prevent secondary air pollution resulting from the use of ozone.
摘要:
The present invention relates to a method for preparing a vanadia-titania catalyst having a core-shell structure, which is highly active in decomposing chlorinated organic compounds such as dioxin present in the exhaust of an incinerator.
摘要:
The present invention is a method of treating nitrogen oxides using an ozone and catalyst hybrid system, as well as an apparatus, specifically relating to a method of treating nitrogen oxide using an ozone and catalyst hybrid system comprising: 1)removing moisture from the nitrogen oxide polluted air to be treated; 2) contacting the moisture-removed nitrogen oxide polluted air with ozone to oxidize NO in said polluted air to NO2; 3) reacting the residual ozone with a catalyst to generate oxygen radicals and then, reacting the oxygen radicals with the nitrogen oxide polluted air from step 2) to oxidize NO2 in the polluted air to NO3−. The nitrogen oxide treatment method and apparatus according to the present invention can effectively treat harmful nitrogen oxides, such as NO, NO2, using an ozone and catalyst hybrid system at room temperature without requiring a high temperature reaction or an ammonia gas as a reducing agent. In addition, the method and apparatus according to the present invention can be useful in the removal of nitrogen oxides in various areas because they can prevent secondary air pollution resulting from the use of ozone.
摘要:
The present invention relates to a method for preparing a vanadia-titania catalyst having a core-shell structure, which is highly active in decomposing chlorinated organic compounds such as dioxin present in the exhaust of an incinerator.
摘要:
Disclosed are an apparatus and a method for manufacturing composite nanoparticles. The apparatus comprises: a first precursor supply unit vaporizing a first precursor and supplying it to a reaction unit; a second precursor supply unit vaporizing a second precursor and supplying it to the reaction unit; the reaction unit producing composite nanoparticles by reacting the vaporized first precursor with the vaporized second precursor; an oxygen supply line supplying an oxygen source to the reaction unit; and a collection unit collecting the composite nanoparticles produced by the reaction unit. Since gas phase synthesis occurs in different stages using the U-shaped reaction chamber, aggregation is prevented and composite nanoparticles of uniform size and high specific surface area can be produced easily.
摘要:
Provided is a method for preparing a vanadia-titania catalyst, comprising: vaporizing a titanium precursor; conveying the vaporized titanium precursor to a reaction unit together with an oxygen supplying source; reacting the vaporized titanium precursor conveyed to the reaction unit with the oxygen supplying source to produce titania particles; condensing the titania particles, collecting and recovering them; mixing the recovered titania particles with a vanadium precursor solution; drying the mixture of the titania particles with the vanadium precursor solution; and calcining the dried mixture under oxygen atmosphere or air. Provided also is a vanadia-titania catalyst obtained by the method. In the vanadia-titania catalyst, titania particles (carriers) are prepared by chemical vapor condensation, and then vanadia is supported on the titania particles (carriers) through impregnation and calcining. Therefore, the vanadia-titania catalyst has a large specific surface area, uniform and fine nano-scaled size, and high dispersibility, thereby providing excellent nitrogen oxide removal efficiency, particularly in a low temperature range of 200° C.-250° C.
摘要:
Disclosed are an apparatus and method for preparing a manganese oxide-titania catalyst. The apparatus for preparing a manganese oxide-titania catalyst includes: a vaporizer vaporizing a manganese precursor and a titanium precursor; a carrier gas supply line supplying a carrier gas, which carries precursor vapors vaporized by the vaporizer to a reactor, to the vaporizer; an oxygen supply line supplying an oxygen source to the reactor; the reactor reacting the precursor vapors with the oxygen source to synthesize a manganese oxide-titania catalyst; and a collector condensing and collecting the manganese oxide-titania catalyst synthesized in the reactor. And, the method for preparing a manganese oxide-titania catalyst includes: 1) vaporizing a manganese precursor and a titanium precursor; 2) carrying precursor vapors (vapors of the manganese precursor and the titanium precursor) and an oxygen source to a reactor; 3) reacting the precursor vapors and the oxygen source to synthesize a manganese oxide-titania catalyst; and 4) condensing and collecting the manganese oxide-titania catalyst. According to the present disclosure, mass production of manganese oxide-titania catalysts with high decomposition efficiency of organic compounds can be prepared through fewer and continuous processes.
摘要:
The present invention relates to a water-cooled grate, which can be cooled while avoiding high and low temperature corrosions. The water-cooled grate comprises: at least one cooling pipe for guiding flow of cooling water; a grate body for placing waste matters to be burned, said grate body being formed with a pipe-receiving portion for receiving the cooling pipe; and a heat transfer controlling member fixed to the pipe-receiving portion for increasing and decreasing heat transfer between the grate body and the cooling pipe by varying thermal resistance to the cooling pipe through thermal deformation according to temperature change of the grate body.
摘要:
Provided are a titania carrier for supporting a catalyst for removing nitrogen oxides, a manganese oxide-titania catalyst comprising the same, an apparatus and a method for preparing the same, and a method for removing nitrogen oxides. More particularly, provided are a titania carrier having a specific surface area of 100 m2/g-150 m2/g, an average pore volume of 0.1 cm3/g-0.2 cm3/g, and an average particle size of 5 nm-20 nm, and an apparatus and method for preparing the same. Provided also are a manganese oxide-titania catalyst comprising the titania carrier and manganese oxide supported thereon, a method for preparing the same, and a method for removing nitrogen oxides using the catalyst. The catalyst has high activity and dispersibility, and thus provides excellent denitrogenation efficiency even in a low temperature range of about 200° C.
摘要:
The present invention relates to a water-cooled grate, which can be cooled while avoiding high and low temperature corrosions. The water-cooled grate comprises: at least one cooling pipe for guiding flow of cooling water; a grate body for placing waste matters to be burned, said grate body being formed with a pipe-receiving portion for receiving the cooling pipe; and a heat transfer controlling member fixed to the pipe-receiving portion for increasing and decreasing heat transfer between the grate body and the cooling pipe by varying thermal resistance to the cooling pipe through thermal deformation according to temperature change of the grate body.