Polyol composition containing a hydrocarbon blowing agent
    2.
    发明授权
    Polyol composition containing a hydrocarbon blowing agent 有权
    含有烃发泡剂的多元醇组合物

    公开(公告)号:US06476091B2

    公开(公告)日:2002-11-05

    申请号:US09995947

    申请日:2001-11-28

    IPC分类号: C08G1848

    摘要: The present invention discloses a polyol resin composition containing a polyether polyol blend, a polyester polyol, and a hydrocarbon blowing agent. The polyether polyol blend has at least a diamine initiated polyol, a propylene oxide polyol, and a polyethylene terephthalate initiated polyol having a functionality of from 2.3 to 3.0. The polyester polyol is preferably a phthalic anhydride initiated polyester polyol. The blowing agent is a C4-C6 hydrocarbon. Also disclosed is a method of producing a polyurethane foam combining the above mentioned polyol resin and an isocyanate component.

    摘要翻译: 本发明公开了含有聚醚多元醇共混物,聚酯多元醇和烃发泡剂的多元醇树脂组合物。 聚醚多元醇共混物具有至少二胺引发的多元醇,环氧丙烷多元醇和官能度为2.3至3.0的聚对苯二甲酸乙二醇酯引发的多元醇。 聚酯多元醇优选为邻苯二甲酸酐引发的聚酯多元醇。 发泡剂是C4-C6烃。 还公开了一种组合上述多元醇树脂和异氰酸酯组分的聚氨酯泡沫的制备方法。

    Isocyanate-based rigid foam
    5.
    发明授权
    Isocyanate-based rigid foam 失效
    异氰酸酯基硬质泡沫

    公开(公告)号:US06245826B1

    公开(公告)日:2001-06-12

    申请号:US09245630

    申请日:1999-02-05

    IPC分类号: C08G1814

    摘要: An isocyanate-based rigid foam comprising the reaction product of an organic and/or modified organic polyisocyanate, a resin blend and, optionally, a relatively low molecular weight chain extender or crosslinker in the presence of a catalyst, and, optionally, further auxiliaries and/or additives, wherein the resin blend comprises a phthalic anhydride-initiated polyester polyol, a blowing agent comprising a C4-C6 hydrocarbon, and a fatty acid or fatty alcohol ethoxylate compatibilizing agent. The blowing agent is soluble in the polyol composition, thereby reducing the risks associated with such blowing agents in processes for making rigid polymer foam articles and providing rigid foams having good dimensional stability and improved insulation properties.

    摘要翻译: 一种基于异氰酸酯的刚性泡沫,其包含有机和/或改性的有机多异氰酸酯,树脂共混物和任选的相对低分子量的增链剂或交联剂在催化剂存在下的反应产物,以及任选的其它助剂和 /或添加剂,其中树脂共混物包含邻苯二甲酸酐引发的聚酯多元醇,包含C 4 -C 6烃的发泡剂和脂肪酸或脂肪醇乙氧基化物相容剂。 发泡剂可溶于多元醇组合物中,从而在制备刚性聚合物泡沫制品的方法中提供与这种发泡剂相关的风险,并提供具有良好尺寸稳定性和改进的绝缘性能的刚性泡沫。

    Stable polyester polyol composition
    6.
    发明授权
    Stable polyester polyol composition 有权
    稳定的聚酯多元醇组合物

    公开(公告)号:US06461536B2

    公开(公告)日:2002-10-08

    申请号:US09246045

    申请日:1999-02-05

    IPC分类号: C08K506

    摘要: A polyester polyol composition comprising a phthalic anhydride-initiated polyester polyol, a C4-C6 hydrocarbon blowing agent, and an oxyethylated fatty acid or fatty alcohol compatibilizing agent having an HLB of from about 7 to about 12. The blowing agent is soluble in the polyol composition, thereby reducing the risks associated with such blowing agents in processes for making rigid polymer foam articles and providing rigid foams having good dimensional stability and improved insulation properties.

    摘要翻译: 包含邻苯二甲酸酐引发的聚酯多元醇,C 4 -C 6烃发泡剂和HLB为约7至约12的氧乙基化脂肪酸或脂肪醇相容剂的聚酯多元醇组合物。发泡剂可溶于多元醇 从而降低与制造刚性聚合物泡沫制品的方法中的这种发泡剂相关的风险,并提供具有良好的尺寸稳定性和改进的绝缘性能的刚性泡沫。

    Process for making isocyanate-based rigid foam
    8.
    发明授权
    Process for making isocyanate-based rigid foam 失效
    制造异氰酸酯类硬质泡沫的方法

    公开(公告)号:US06268402B1

    公开(公告)日:2001-07-31

    申请号:US09245211

    申请日:1999-02-05

    IPC分类号: C08G1814

    摘要: A process for producing a rigid foam based on isocyanate comprises reacting an organic and/or modified organic polyisocyanate with a polyol composition and, optionally, a relatively low molecular weight chain extender or crosslinker in the presence of a catalyst, and, optionally, further auxiliaries and/or additives, wherein the polyol composition comprises a phthalic anhydride-initiated polyester polyol, a blowing agent comprising C4-C6 hydrocarbon, and a fatty acid or fatty alcohol ethoxylate compatibilizing agent. The blowing agent is soluble in the polyol composition, thereby reducing the risks associated with such blowing agents in processes for making rigid polymer foam articles and providing rigid foams having good dimensional stability and improved insulation properties.

    摘要翻译: 一种用于生产基于异氰酸酯的硬质泡沫的方法包括使有机和/或改性的有机多异氰酸酯与多元醇组合物和任选的相对低分子量的增链剂或交联剂在催化剂存在下反应,和任选的其它助剂 和/或添加剂,其中所述多元醇组合物包含邻苯二甲酸酐引发的聚酯多元醇,包含C4-C6烃的发泡剂和脂肪酸或脂肪醇乙氧基化物相容剂。 发泡剂可溶于多元醇组合物中,从而在制备刚性聚合物泡沫制品的方法中提供与这种发泡剂相关的风险,并提供具有良好尺寸稳定性和改进的绝缘性能的刚性泡沫。

    Polyoxyalkylene polyether monool polyurethane foam additive

    公开(公告)号:US5488071A

    公开(公告)日:1996-01-30

    申请号:US510985

    申请日:1995-08-03

    摘要: There is now provided a polyol composition containing a polyol having polyester linkages, an aliphatic or cycloaliphatic C.sub.4 -C.sub.7 hydrocarbon blowing agent, and a polyoxyalkylene polyether monool initiated with a C.sub.8 -C.sub.24 fatty hydrocarbon having one alkylene oxide active hydrogen atom. We have found that the monool emulsifies the C.sub.4 -C.sub.7 blowing agent in the compound having polyester linkages, to form an emulsified polyol composition, after which an organic aromatic isocyanate may be reacted with the emulsified polyol composition to form a closed cell polyurethane foam.The polyol composition is used to make rigid closed cell polyisocyanate based foams which are dimensionally stable, and have good insulation values and flame retardance. Combining the monool with the polyester based polyol produces a foam having a density lower than that of a reference foam made with the same ingredients and amounts except in the absence of the monool. Whether the monool is merely mixed with the polyol or used to form an emulsion with the hydrocarbon blowing agent and the polyol, the foam density may be lowered when the monool is used.