公开(公告)号：US4449820A

公开(公告)日：1984-05-22

申请号：US299109

申请日：1981-09-03

申请人： Hideaki Koizumi ,  Hideo Yamada ,  Kounosuke Oishi

发明人： Hideaki Koizumi ,  Hideo Yamada ,  Kounosuke Oishi

IPC分类号： G01N21/31 ,  G01N21/72

CPC分类号： G01N21/3103

摘要： A Zeeman atomic absorption spectrophotometer which monitors atomic absorption signals after a sample is introduced into the chemical flame atomizing portion. A signal peak value is measured in the portion of atomic absorption signals rising after the sample is introduced, or in the portion of atomic absorption signals breaking after the introduction of the sample is discontinued. A relation between the peak value and the sample concentration establishes a monovalent function. According to the conventional method, a relation between an average value of atomic absorption signals within a predetermined period of time and the concentration of specimen establishes a divalent function, and it is difficult to measure the samples, particularly in high-concentration regions. According to the present invention, however, it is possible to measure the samples of even high concentrations without having to dilute the samples.

摘要翻译： 塞曼原子吸收分光光度计，其在样品被引入化学火焰雾化部分之后监测原子吸收信号。 在引入样品的原子吸收信号的上升部分或在导入样品的原子吸收信号断开部分之后测量信号峰值。 峰值与样品浓度之间的关系建立了一价函数。 根据常规方法，在预定时间段内的原子吸收信号的平均值与样品浓度之间的关系建立二值函数，并且难以测量样品，特别是在高浓度区域中。 然而，根据本发明，可以测量甚至高浓度的样品，而不必稀释样品。

公开(公告)号：US4165937A

公开(公告)日：1979-08-28

申请号：US746831

申请日：1976-12-02

申请人： Seiichi Murayama ,  Masaru Ito ,  Manabu Yamamoto ,  Kunifusa Kayama ,  Kounosuke Oishi

发明人： Seiichi Murayama ,  Masaru Ito ,  Manabu Yamamoto ,  Kunifusa Kayama ,  Kounosuke Oishi

IPC分类号： G01J4/04 ,  G01N21/21 ,  G01N21/31 ,  G01J3/42

CPC分类号： G01N21/3103 ,  G01N21/21

摘要： A magneto-optic spectrophotometer for detection or identification of atoms or molecules contained in the sample by utilizing phenomena of birefringence or rotation of polarization caused by the atoms or the molecules in a magnetic field is constructed as follows. Linearly polarized lights are incident on a space where atoms or molecules to be detected exist in a magnetic field. The lights having passed through said space are separated into two beams of lights of polarization components perpendicular and parallel to the polarization of the incident lights. The perpendicular components are used as the signal lights, and the parallel components the reference lights. The signal lights and the reference lights are spectrally analyzed by a wavelength selector in which a signal light and a reference light of a wavelength to be selected are incident on an identical dispersive element. The signal lights and the reference lights are detected by respective detectors. Then, the ratios of the outputs of the signal light detectors to the outputs of the reference light detectors are obtained. By this construction the intensities of the scattered lights by atoms or molecules to be detected can precisely be measured.

摘要翻译： 用于通过利用由磁场中的原子或分子引起的双折射或偏振旋转的现象来检测或鉴定样品中包含的原子或分子的磁光分光光度计如下。 线偏振光入射到要检测的原子或分子存在于磁场中的空间。 已经穿过所述空间的光被分离成垂直并平行于入射光的偏振的两束偏振分量的光束。 垂直分量用作信号灯，并联组件参考灯。 通过波长选择器对信号灯和参考光进行光谱分析，其中信号光和要选择的波长的参考光入射到相同的色散元件上。 信号灯和参考灯由相应的检测器检测。 然后，获得信号光检测器的输出与参考光检测器的输出的比率。 通过这种结构，可以精确地测量被检测的原子或分子的散射光的强度。

公开(公告)号：US4718763A

公开(公告)日：1988-01-12

申请号：US848460

申请日：1986-04-07

申请人： Kounosuke Oishi ,  Masataka Koga ,  Kazuo Yasuda

发明人： Kounosuke Oishi ,  Masataka Koga ,  Kazuo Yasuda

IPC分类号： G01N21/31 ,  G01N21/72 ,  G01J3/42

CPC分类号： G01N21/3103 ,  G01N2021/3111

摘要： There is provided an atomic absorption spectrophotometer wherein a magnetic field having a suitable value is applied to a light source radiating the emission spectral light of the atom to be analyzed in the advance direction of the radiated light in order to cause the Zeeman effect so that the wavenumber of a component which is included in the spectra shifted in wavenumber and which is varied to have a smaller wavenumber may coincide with or approach the wavenumber whereat the absorption spectrum is maximized, thereby the sensitivity of the atomic absorption being raised, the linear region of the working curve being improved, and the emission spectral light being stabilized.

摘要翻译： 提供了一种原子吸收分光光度计，其中将具有适当值的磁场施加到辐射待辐射原子的发射光谱的光源，以便辐射光的前进方向，以便产生塞曼效应，使得 包含在波数偏移并且具有较小波数的光谱中的分量的波数可以与吸收光谱最大化的波数重合或接近，从而提高原子吸收的灵敏度，线性区域 工作曲线得到改善，发射光谱稳定。

公开(公告)号：US4298284A

公开(公告)日：1981-11-03

申请号：US969268

申请日：1978-12-14

申请人： Manabu Yamamoto ,  Seiichi Murayama ,  Masaru Ito ,  Kounosuke Oishi

发明人： Manabu Yamamoto ,  Seiichi Murayama ,  Masaru Ito ,  Kounosuke Oishi

IPC分类号： G01N21/21

CPC分类号： G01N21/21 ,  G01N2021/218

摘要： In measuring a change in the polarization state of light attributed to magnetooptic anisotropy, a means for generating optic anisotropy is added to a light source or onto an optical path extending from the light source to a polarization analyzer. This allows high precision analysis of the polarization state of light emergent from the polarization analyzer.

摘要翻译： 在测量归因于磁光各向异性的光的偏振态的变化时，将光学各向异性的装置添加到光源或从光源延伸到偏振分析器的光路上。 这允许从偏振分析仪出射的光的偏振状态的高精度分析。