Chemical synthesis of stable and electroactive polypyrrole and related
polyheterocyclic compounds
    1.
    发明授权
    Chemical synthesis of stable and electroactive polypyrrole and related polyheterocyclic compounds 失效
    稳定和电活性聚吡咯及相关多环化合物的化学合成

    公开(公告)号:US4956444A

    公开(公告)日:1990-09-11

    申请号:US36497

    申请日:1987-04-09

    IPC分类号: C08G61/12

    CPC分类号: C08G61/123

    摘要: A simple chemical process for the simultaneous polymerization and oxidation of pyrrole, N-substituted pyrroles, and other heterocycles having five or six member rings by halogenic or organic electron acceptors. The polypyrrole-acceptor charge transfer complexes so produced are of high purity and are stable in the atmosphere, in the presence of moisture and at elevated temperatures. The conductivities of the complexes are controllable between 30 ohm.sup.-1 cm.sup.-1 and 10.sup.-3 ohm-1 cm-1, depending on the type of acceptor used and the process conditions.

    摘要翻译: 用于通过卤素或有机电子受体同时聚合和氧化吡咯,N-取代的吡咯和具有五个或六个成员环的其它杂环的简单化学方法。 如此生产的聚吡咯 - 受体电荷转移络合物具有高纯度,并且在大气中,在水分和高温下都是稳定的。 取决于所使用的受体的类型和工艺条件,络合物的电导率可在30 ohm-1 cm-1和10-3 ohm-1 cm-1之间控制。