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公开(公告)号:US10532009B2
公开(公告)日:2020-01-14
申请号:US15562497
申请日:2016-03-30
申请人: DENTSPLY SIRONA inc.
发明人: Joachim Klee , Maximilian Maier , Jacques Lalevee , Christoph P. Fik , Jean Pierre Fouassier , Fabrice Morlet-Savary , Celine Dietlin
摘要: Disclosed herein is a dental composition having a polymerization initiator system with an aromatic tertiary phosphine compound. Further disclosed is the use of the aromatic tertiary phospine compound for the preparation of a photocurable dental compositions.
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公开(公告)号:US10512594B2
公开(公告)日:2019-12-24
申请号:US15766397
申请日:2016-10-10
申请人: DENTSPLY SIRONA Inc.
发明人: Joachim E. Klee , Florian Szillat , Maximilian Maier , Helmut Ritter , Jacques Lalevee , Jean Pierre Fouassier , Fabrice Morlet-Savary , Celine Dietlin , Mariem Bouzrati-Zerelli , Christoph P Fik
摘要: The present invention relates to a dental composition comprising an initiator system comprising a sensitizer compound having an acylsilyl- or acylgermyl-group and a specific coinitiator compound. The present invention also relates to an initiator system consisting essentially of the sensitizer compound having an acylsilyl- or acylgermyl-group and a coinitiator compound wherein a C—H bond dissociation energy is less than 95 Kcal/mol. Furthermore, the present invention relates to the use of this initiator system for the preparation of a dental composition.
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公开(公告)号:US11166883B2
公开(公告)日:2021-11-09
申请号:US16092658
申请日:2017-04-07
申请人: DENTSPLY SIRONA inc.
发明人: Joachim E Klee , Maximilian Maier , Christoph P. Fik , Jacques Lalevee , Jean Pierre Fouassier , Fabrice Morlet-Savary , Celine Dietlin , Mariem Bouzrati-Zerelli
摘要: Dental composition comprising (a) a homogeneous phase comprising monomer combinations (i) and (ii), (i) and (iii), (ii) and (iii), or (i), (ii) and (iii), or comprising monomer (iii), wherein (i) represents one or more compounds having one or more radically polymerizable carbon-carbon double bonds; (ii) represents one or more compounds having one or more cationically polymerizable groups; and (iii) represents one or more compounds having a combination of one or more radically polymerizable carbon-carbon double bonds and one or more cationically polymerizable groups; (b) an initiator system comprising (iv) one or more radical polymerization initiator of the following formula (I): wherein M is Ge or Si; R1, R2 and R3 may be the same or different, independently represent an organic group, and R4 represents a hydrogen atom, an organic or organometallic group; provided that when R4 is a hydrogen atom, the initiator system further comprises a sensitizer compound having a light absorption maximum in the range from 300 to 600 nm; (v) a cationic polymerization initiator, which is a compound selected from the following formula (II), (III) and (IV): wherein R5 and R6, which may be the same or different, independently represent an aryl group which may have a substituent; and Y− represents an anion; wherein R7, R8 and R9 which may be the same or different, independently represent an aryl group which may have a substituent; and Y− represents an anion; R10, R11, R12, and R13 which may be the same or different, independently represent an alkyl or aryl group which may have a substituent; and Y− represents an anion.
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公开(公告)号:US10588830B2
公开(公告)日:2020-03-17
申请号:US15766382
申请日:2016-10-07
申请人: DENTSPLY SIRONA Inc.
发明人: Joachim E. Klee , Florian Szillat , Maximilian Maier , Helmut Ritter , Jacques Lalevee , Jean Pierre Fouassier , Fabrice Morlet-Savary , Celine Dietlin , Mariem Bouzrati-Zerelli , Christoph P Fik
摘要: The present invention relates to a dental composition comprising a specific polymerization initiator system comprising a compound having an acylsilyl- or acylgermanyl-group. The present invention also relates the use of the compound having an acylsilyl- or acylgermanyl group for the preparation of a dental composition.
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