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公开(公告)号：US4290815A
公开(公告)日：1981-09-22
申请号：US111290
申请日：1980-01-28
申请人： Charles L. Henry
发明人： Charles L. Henry
CPC分类号： C08J3/096 , C08K3/20 , C08K5/17 , C08K5/34 , C08J2301/02
摘要： This invention relates to the use of certain co-solvents in cellulose amine N-oxide solutions, which co-solvents increase the cellulose dissolution rate; lower the temperatures necessary to reasonably form a solution; lower the viscosity of the solution; provide solutions with improved color, amine oxide stability, and cellulose stability, provide a solution with improved flow characteristics; increase solution processability, e.g. wet spinning; permit the replacement of amine oxides by a less expensive co-solvent; and are recoverable and reusable in cellulose dissolution and processing.The co-solvents of the invention comprise compounds, miscible with cellulose-dissolving amine N-oxides, containing primary, or combinations of primary and secondary, amino groups wherein the amino groups are bonded to alkyl, alicyclic, dialkyl ether or alkyl/alicyclic radical(s) and wherein the number of carbon atoms divided by the number of primary amino groups is approximately equal to or less than 4; or#C/#NH.sub.2 .ltorsim.4and the number of primary amino groups divided by the number of secondary amine radicals is equal to or greater than 1; that is#NH.sub.2 /#NHR.gtoreq.1.
摘要翻译： 本发明涉及在纤维素胺N-氧化物溶液中使用某些助溶剂，其中共溶剂增加纤维素溶解速率; 降低合理形成溶液所需的温度; 降低溶液的粘度; 提供改进的颜色，氧化胺稳定性和纤维素稳定性的溶液，提供具有改善的流动特性的溶液; 提高溶液加工性，例如 湿纺; 允许用较便宜的助溶剂代替氧化胺; 并且在纤维素溶解和加工中是可回收和可重复使用的。 本发明的共溶剂包含与纤维素溶解胺N-氧化物混溶的化合物，其含有伯或仲氨基的组合，其中氨基与烷基，脂环族，二烷基醚或烷基/脂环族基团结合 并且其中碳原子数除以伯氨基数目近似等于或小于4; 或＃C /＃NH 2大约4，并且伯氨基的数目除以次级胺基的数量等于或大于1; 那就是＃NH2 /＃NHR> / = 1。
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2.发明授权
公开(公告)号：US4211678A
公开(公告)日：1980-07-08
申请号：US941621
申请日：1978-09-12
申请人： Charles L. Henry , James E. White
发明人： Charles L. Henry , James E. White
摘要： The invention relates to new copolyester polymers which are high molecular weight copolyesters of terephthalic acid, ethylene glycol, dimer acid and polyoxyethylene glycols and to films, fibers and filaments made from these copolyesters. The copolyesters contain about 2 to 4% by weight of dimer acid and about 1 to 3% by weight of polyoxyethylene glycol. Fibers and yarns processed from these copolyesters have markedly improved affinity for disperse dyes.
摘要翻译： 本发明涉及新型共聚酯聚合物，它们是对苯二甲酸，乙二醇，二聚酸和聚氧乙烯二醇的高分子量共聚酯，以及由这些共聚酯制成的薄膜，纤维和长丝。 共聚酯含有约2至4重量％的二聚酸和约1至3重量％的聚氧乙烯二醇。 从这些共聚酯加工的纤维和纱线对分散染料的亲和力明显提高。
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