METHOD FOR PREPARING GLASS NANOSTRUCTURES AND NANOSTRUCTURED SUBSTRATES THEREOF

    公开(公告)号:US20250034027A1

    公开(公告)日:2025-01-30

    申请号:US18769772

    申请日:2024-07-11

    Abstract: A method of forming a nanostructure, comprising: providing a first polymeric brush structure attached to at least one surface of a substrate, wherein the first polymeric brush structure comprises a pre-glass polymerizable precursor; and curing the first polymeric brush structure to form a nanostructure comprising glass. The first polymeric brush structure can be formed by reacting (i) at least one vinyl-containing group comprising a pre-glass precursor with (ii) a polymerization active group on the linker comprising a reversible addition-fragmentation chain-transfer (RAFT) agent or an atom transfer radical polymerization (ATRP) initiator. The present disclosure further relates to a substrate, comprising: a surface comprising a plurality of nanostructures comprising glass, wherein at least a portion of the nanostructures comprises a detectable amount of carbon by x-ray photoelectron spectroscopy (XPS).

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