公开(公告)号：US09205412B2

公开(公告)日：2015-12-08

申请号：US13781829

申请日：2013-03-01

Applicant: Clariant Corporation

Inventor： Aaron B. Miller ,  Malati Raghunath ,  Valery Sokolovskii ,  Claus G. Lugmair ,  Anthony F. Volpe, Jr. ,  Wenqin Shen ,  Wayne Turbeville

IPC: B01J23/72 ,  B01J23/89 ,  B01J23/86 ,  B01J23/889 ,  B01J21/06 ,  B01J21/18 ,  B01J23/755 ,  B01J23/83 ,  B01J23/835 ,  B01J23/843 ,  B01J37/02 ,  B82Y30/00 ,  C07C29/00 ,  B01J37/18 ,  B01J35/02

CPC classification number: B01J23/8993 ,  B01J21/066 ,  B01J21/18 ,  B01J21/185 ,  B01J23/755 ,  B01J23/83 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J23/866 ,  B01J23/868 ,  B01J23/8892 ,  B01J23/8926 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/18 ,  B82Y30/00 ,  C07C29/00 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205

Abstract: Ethylene glycol and propylene glycol may be made by hydrogenolysis of a polyol comprising the steps of reacting a polyol with hydrogen in the presence of a hydrogenolysis catalyst. The hydrogenolysis comprises nickel, one or more promoter, and one or more support. The promoter is selected from bismuth, silver, tin, antimony, gold, lead, thallium, cerium, lanthanum, and manganese. The support is selected from zirconia and carbon. A zirconia support comprises a zirconia textual promoter, which is selected from Cr, Mo, W, Nb, Ce, Ca, Mg, La, Pr, Nd, Al, and P. If the support comprises carbon, then the promoter is selected from bismuth and antimony. In another embodiment, if the support comprises carbon, then both the promoter is selected from bismuth and antimony, and the catalyst comprises copper. In another embodiment, the catalyst additionally comprises copper.

Abstract translation: 乙二醇和丙二醇可以通过多元醇的氢解制备，包括在氢解催化剂存在下使多元醇与氢反应的步骤。 氢解包括镍，一种或多种助催化剂和一种或多种载体。 助催化剂选自铋，银，锡，锑，金，铅，铊，铈，镧和锰。 载体选自氧化锆和碳。 氧化锆载体包括选自Cr，Mo，W，Nb，Ce，Ca，Mg，La，Pr，Nd，Al和P的氧化锆文本启动子。如果载体包含碳，则启动子选自 铋和锑。 在另一个实施方案中，如果载体包含碳，则促进剂都选自铋和锑，并且催化剂包括铜。 在另一个实施方案中，催化剂另外包含铜。

公开(公告)号：US20170190643A1

公开(公告)日：2017-07-06

申请号：US15463911

申请日：2017-03-20

Applicant: Clariant Corporation

Inventor： Wenqin Shen ,  Franz Petzold ,  Karen Libby ,  Wayne Turbeville ,  Matthew Purcell ,  Marc K. Born

IPC: C07C29/132 ,  B01J23/72 ,  B01J23/75 ,  B01J23/745 ,  B01J23/06 ,  B01J23/83 ,  B01J23/44 ,  B01J23/843 ,  B01J35/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/06 ,  B01J37/02 ,  B01J37/00 ,  B01J37/08 ,  B01J23/755

CPC classification number: C07C29/132 ,  B01J21/066 ,  B01J23/06 ,  B01J23/40 ,  B01J23/44 ,  B01J23/48 ,  B01J23/72 ,  B01J23/74 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/8435 ,  B01J23/892 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/088 ,  B01J37/18 ,  B01J2523/00 ,  C01G3/02 ,  C01G25/00 ,  C01G25/02 ,  C01G51/04 ,  C01G53/04 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/21 ,  C04B35/486 ,  C04B35/488 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3232 ,  C04B2235/3251 ,  C04B2235/3258 ,  C04B2235/3262 ,  C04B2235/327 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3277 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3293 ,  C04B2235/3294 ,  C04B2235/3409 ,  C04B2235/6021 ,  C04B2235/72 ,  C04B2235/721 ,  C04B2235/765 ,  C07C29/00 ,  C07C29/141 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/205 ,  C07C31/18 ,  C07C31/202 ,  C07C31/225 ,  B01J2523/3706 ,  B01J2523/48 ,  B01J2523/847

Abstract: The present disclosure relates generally to ceramic materials suitable for use as catalyst support materials, catalysts using such materials and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is a ceramic material including zirconium oxide and one or more metal oxides selected from nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide, the ceramic material being at least about 50 wt. % zirconium oxide. In certain embodiments, the ceramic material is substantially free of any binder, extrusion aid or additional stabilizing agent.

公开(公告)号：US20150031923A1

公开(公告)日：2015-01-29

申请号：US14306332

申请日：2014-06-17

Applicant: CLARIANT CORPORATION

Inventor： Wenqin Shen ,  Franz G. Petzold ,  Karen Libby ,  Wayne Turbeville

IPC: B01J23/889 ,  C07C29/17 ,  C07C29/60 ,  B01J23/34 ,  B01J23/656

CPC classification number: B01J23/8892 ,  B01J21/066 ,  B01J23/34 ,  B01J23/462 ,  B01J23/6562 ,  B01J23/72 ,  B01J23/755 ,  B01J23/8435 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/031 ,  B01J37/08 ,  C07C29/00 ,  C07C29/132 ,  C07C29/149 ,  C07C29/172 ,  C07C29/60 ,  C12P19/02 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C31/225 ,  C07C31/26

Abstract: The present disclosure relates generally to catalyst support materials, catalysts and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is catalyst support material including ZrO2 and one or more oxides of manganese (MnOx), the catalyst support material being at least about 50 wt % ZrO2 and MnOx. In certain embodiments, the weight ratio of ZrO2 to MnOx is within the range of about 1:1 to about 30:1; and/or the catalyst support material is substantially free of any binder, extrusion aid or additional stabilizing agent.

Abstract translation: 本公开一般涉及催化剂载体材料，催化剂和使用它们的方法，例如将糖，糖醇，甘油和生物可再生有机酸转化成商业上有价值的化学品和中间体的方法。 本发明的一个方面是包括ZrO 2和一种或多种锰氧化物（MnO x）的催化剂载体材料，催化剂载体材料为至少约50重量％的ZrO 2和MnO x。 在某些实施方案中，ZrO 2与MnO x的重量比在约1:1至约30:1的范围内; 和/或催化剂载体材料基本上不含任何粘合剂，挤出助剂或其它稳定剂。

公开(公告)号：US10065910B2

公开(公告)日：2018-09-04

申请号：US15463911

申请日：2017-03-20

Applicant: Clariant Corporation

Inventor： Wenqin Shen ,  Franz Petzold ,  Karen Libby ,  Wayne Turbeville ,  Matthew Purcell ,  Marc K. Born

IPC: C07C29/132 ,  B01J23/755 ,  B01J23/72 ,  B01J23/75 ,  B01J23/745 ,  B01J23/06 ,  B01J23/83 ,  B01J23/44 ,  B01J23/843 ,  B01J35/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/02 ,  B01J37/00 ,  B01J37/08 ,  B01J37/06

Abstract: The present disclosure relates generally to ceramic materials suitable for use as catalyst support materials, catalysts using such materials and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is a ceramic material including zirconium oxide and one or more metal oxides selected from nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide, the ceramic material being at least about 50 wt. % zirconium oxide. In certain embodiments, the ceramic material is substantially free of any binder, extrusion aid or additional stabilizing agent.

公开(公告)号：US09132418B2

公开(公告)日：2015-09-15

申请号：US14306332

申请日：2014-06-17

Applicant: CLARIANT CORPORATION

Inventor： Wenqin Shen ,  Franz G. Petzold ,  Karen Libby ,  Wayne Turbeville

IPC: C07C29/00 ,  B01J21/00 ,  B01J23/889 ,  B01J37/03 ,  B01J37/08 ,  B01J21/06 ,  B01J23/34 ,  B01J23/46 ,  B01J23/72 ,  B01J23/755 ,  B01J23/843 ,  B01J35/00 ,  B01J35/10 ,  C12P19/02 ,  B01J23/656 ,  C07C29/17 ,  C07C29/60 ,  C07C29/132 ,  C07C29/149

CPC classification number: B01J23/8892 ,  B01J21/066 ,  B01J23/34 ,  B01J23/462 ,  B01J23/6562 ,  B01J23/72 ,  B01J23/755 ,  B01J23/8435 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/031 ,  B01J37/08 ,  C07C29/00 ,  C07C29/132 ,  C07C29/149 ,  C07C29/172 ,  C07C29/60 ,  C12P19/02 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C31/225 ,  C07C31/26

Abstract: The present disclosure relates generally to catalyst support materials, catalysts and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is catalyst support material including ZrO2 and one or more oxides of manganese (MnOx), the catalyst support material being at least about 50 wt % ZrO2 and MnOx. In certain embodiments, the weight ratio of ZrO2 to MnOx is within the range of about 1:1 to about 30:1; and/or the catalyst support material is substantially free of any binder, extrusion aid or additional stabilizing agent.

Abstract translation: 本公开一般涉及催化剂载体材料，催化剂和使用它们的方法，例如将糖，糖醇，甘油和生物可再生有机酸转化成商业上有价值的化学品和中间体的方法。 本发明的一个方面是包括ZrO 2和一种或多种锰氧化物（MnO x）的催化剂载体材料，催化剂载体材料为至少约50重量％的ZrO 2和MnO x。 在某些实施方案中，ZrO 2与MnO x的重量比在约1:1至约30:1的范围内; 和/或催化剂载体材料基本上不含任何粘合剂，挤出助剂或其它稳定剂。