Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
    1.
    发明申请
    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
    用于最小化可交联组合物焦烧的硝酸化合物

    公开(公告)号:US20090069469A1

    公开(公告)日:2009-03-12

    申请号:US12267909

    申请日:2008-11-10

    CPC classification number: C08F2/38 C08F4/00 C08K5/0025 C08K5/3435

    Abstract: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    Abstract translation: 在可交联聚合物(例如EPDM)的自由基交联期间,通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物,优选醚,酯或氨基甲酸酯衍生物的交联之前引入聚合物中,焦烧被抑制 ,例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下,本发明的焦烧抑制剂(如果不是更好)也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样,在焦烧抑制和最终交联度方面也表现出较低的挥发性, 聚合物组合物内迁移少。

    Nitroxide compounds for minimizing scorch in crosslinkable compositions
    2.
    发明授权
    Nitroxide compounds for minimizing scorch in crosslinkable compositions 失效
    用于最小化可交联组合物中焦化的硝酸氧化物

    公开(公告)号:US07465769B2

    公开(公告)日:2008-12-16

    申请号:US11539815

    申请日:2006-10-09

    CPC classification number: C08F2/38 C08F4/00 C08K5/0025 C08K5/3435

    Abstract: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    Abstract translation: 在可交联聚合物(例如EPDM)的自由基交联期间,通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物,优选醚,酯或氨基甲酸酯衍生物的交联之前引入聚合物中,焦烧被抑制 ,例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下,本发明的焦烧抑制剂(如果不是更好)也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样,在焦烧抑制和最终交联度方面也表现出较低的挥发性, 聚合物组合物内迁移少。

    Crosslinkable polyethylene composition, method of making the same, and articles made therefrom
    3.
    发明授权
    Crosslinkable polyethylene composition, method of making the same, and articles made therefrom 有权
    可交联聚乙烯组合物,其制造方法和由其制成的制品

    公开(公告)号:US08283420B2

    公开(公告)日:2012-10-09

    申请号:US12525688

    申请日:2008-01-25

    Abstract: The instant invention is a crosslinkable polyethylene composition obtained via a process comprising the steps of (1) providing a polyethylene component; (2) providing an organic peroxide crosslinking agent,(3) providing a crosslinking coagent which comprises at least two terminal carbon-carbon double bonds and is an alkadiene, alkatriene, or alkatetraene compound; (4) melt blending the polyethylene component, the crosslinking agent, and the crosslinking coagent at a temperature less than the decomposition temperature of the crosslinking agent; and (5) thereby forming the crosslinkable polyethylene composition. The crosslinkable polyethylene composition may further include a scorch inhibitor, a cure booster, a stable free radical, one or more conventional additives, and/or combinations thereof. The instant invention further includes articles comprising the crosslinked product of the crosslinkable polyethylene composition.

    Abstract translation: 本发明是通过包括以下步骤的方法获得的可交联聚乙烯组合物:(1)提供聚乙烯组分; (2)提供有机过氧化物交联剂,(3)提供交联助剂,其包含至少两个末端碳 - 碳双键,并且是二烯烃,三亚甲基或烷基四烯化合物; (4)在低于交联剂分解温度的温度下熔融共混聚乙烯组分,交联剂和交联助剂; 和(5),从而形成可交联聚乙烯组合物。 可交联聚乙烯组合物还可以包含焦烧抑制剂,固化促进剂,稳定的自由基,一种或多种常规添加剂和/或其组合。 本发明还包括包含可交联聚乙烯组合物的交联产物的制品。

    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions
    4.
    发明申请
    Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
    用于最小化可交联组合物焦烧的硝酸化合物

    公开(公告)号:US20080085973A1

    公开(公告)日:2008-04-10

    申请号:US11539815

    申请日:2006-10-09

    CPC classification number: C08F2/38 C08F4/00 C08K5/0025 C08K5/3435

    Abstract: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    Abstract translation: 在可交联聚合物(例如EPDM)的自由基交联期间,通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物,优选醚,酯或氨基甲酸酯衍生物的交联之前引入聚合物中,焦烧被抑制 ,例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下,本发明的焦烧抑制剂(如果不是更好)也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样,在焦烧抑制和最终交联度方面也表现出较低的挥发性, 聚合物组合物内迁移少。

    CROSSLINKABLE POLYETHYLENE COMPOSITION, METHOD OF MAKING THE SAME, AND ARTICLES MADE THEREFROM
    5.
    发明申请
    CROSSLINKABLE POLYETHYLENE COMPOSITION, METHOD OF MAKING THE SAME, AND ARTICLES MADE THEREFROM 有权
    可交联聚乙烯组合物,其制备方法及其制备方法

    公开(公告)号:US20100016515A1

    公开(公告)日:2010-01-21

    申请号:US12525688

    申请日:2008-01-25

    Abstract: The instant invention is a crosslinkable polyethylene composition, a method of making the same, and articles made therefrom. The crosslinkable polyethylene composition according to instant invention includes a polyethylene component, a crosslinking agent, and a crosslinking coagent. The crosslinking agent is an organic peroxide, and the crosslinking coagent is an alkadiene, alkatriene, or alkatetraene compound comprising at least two terminal carbon-carbon double bonds. The crosslinkable polyethylene composition may, optionally, further include a scorch inhibitor, a cure booster, a stable free radical, one or more conventional additives, blends thereof, and/or combinations thereof. The method for producing a crosslinkable polyethylene composition according to instant invention includes the steps of: (1) providing a polyethylene component; (2) providing a crosslinking agent, wherein the crosslinking agent is an organic peroxide; (3) providing a crosslinking coagent, wherein the crosslinking coagent is an alkadiene, alkatriene, or alkatetraene compound comprising at least two terminal carbon-carbon double bonds; (4) melt blending the a polyethylene component, the crosslinking agent, and the crosslinking coagent at a temperature in the range of less than the decomposition temperature of the crosslinking agent; and (5) thereby forming the crosslinkable polyethylene composition. The article according to instant invention includes the crosslinked product of a polyethylene component; a crosslinking agent, wherein the crosslinking agent is an organic peroxide; and a crosslinking coagent, wherein the crosslinking coagent is an alkadiene, alkatriene, or alkatetraene compound comprising at least two terminal carbon-carbon double bonds.

    Abstract translation: 本发明是可交联聚乙烯组合物,其制备方法和由其制成的制品。 根据本发明的可交联聚乙烯组合物包括聚乙烯组分,交联剂和交联助剂。 交联剂是有机过氧化物,交联助剂是包含至少两个末端碳 - 碳双键的链二烯,亚烷基或烷基四烯化合物。 可交联聚乙烯组合物可以任选地进一步包括焦烧抑制剂,固化促进剂,稳定的自由基,一种或多种常规添加剂,其共混物和/或其组合。 根据本发明的可交联聚乙烯组合物的制造方法包括以下步骤:(1)提供聚乙烯组分; (2)提供交联剂,其中所述交联剂是有机过氧化物; (3)提供交联助剂,其中所述交联助剂是包含至少两个末端碳 - 碳双键的链二烯,亚烷基或烷基四烯化合物; (4)在小于交联剂的分解温度的范围内的温度下熔融共混聚乙烯组分,交联剂和交联助剂; 和(5),从而形成可交联聚乙烯组合物。 根据本发明的制品包括聚乙烯组分的交联产物; 交联剂,其中所述交联剂是有机过氧化物; 和交联助剂,其中所述交联助剂是包含至少两个末端碳 - 碳双键的链二烯,亚烷基或烷基四烯化合物。

    Nitroxide compounds for minimizing scorch in crosslinkable compositions
    6.
    发明授权
    Nitroxide compounds for minimizing scorch in crosslinkable compositions 失效
    用于最小化可交联组合物中焦化的硝酸氧化物

    公开(公告)号:US07842759B2

    公开(公告)日:2010-11-30

    申请号:US12267909

    申请日:2008-11-10

    CPC classification number: C08F2/38 C08F4/00 C08K5/0025 C08K5/3435

    Abstract: Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.

    Abstract translation: 在可交联聚合物(例如EPDM)的自由基交联期间,通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物,优选醚,酯或氨基甲酸酯衍生物的交联之前引入聚合物中,焦烧被抑制 ,例如4-羟基 - 四氢环丁基哌啶-1-基。 在类似的聚合物组合物和类似的条件下,本发明的焦烧抑制剂(如果不是更好)也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样,在焦烧抑制和最终交联度方面也表现出较低的挥发性, 聚合物组合物内迁移少。

    Immunomodulating Nanoparticulate Composition
    8.
    发明申请
    Immunomodulating Nanoparticulate Composition 审中-公开
    免疫调节纳米颗粒组成

    公开(公告)号:US20120231041A1

    公开(公告)日:2012-09-13

    申请号:US13413377

    申请日:2012-03-06

    CPC classification number: A61K47/48884 A61K9/0078 A61K47/6929

    Abstract: The present invention relates to a preferably nebulizable pharmaceutical composition comprising a pharmaceutically acceptable protein-based nanocarrier preferably in the size range 150 to 300 nm and a preventative or therapeutic amount of an active agent for use in the prevention and/or treatment of an allergic and/or inflammatory disease of the lower airways in a mammal. Preferably, the active agent is a CpG oligodeoxynucleotide (CpG-ODN), and preferably the composition exhibits a prolonged clinical effect.

    Abstract translation: 本发明涉及优选可喷雾的药物组合物,其包含优选地在150至300nm范围内的药学上可接受的基于蛋白质的纳米载体,以及预防或治疗量的用于预防和/或治疗过敏性和/ /或哺乳动物中下呼吸道的炎性疾病。 优选地,活性剂是CpG寡脱氧核苷酸(CpG-ODN),并且优选地,该组合物显示出延长的临床效果。

    Crosslinked Automotive Wire
    10.
    发明申请
    Crosslinked Automotive Wire 审中-公开
    交联汽车线

    公开(公告)号:US20080188604A1

    公开(公告)日:2008-08-07

    申请号:US11659579

    申请日:2005-08-22

    CPC classification number: H01B7/295 H01B3/441

    Abstract: The present invention is a crosslinked automotive wire comprising a metal conductor, a flame retardant insulation layer surrounding the metal conductor, and optionally, a wire jacket surrounding the insulation layer. The automotive wire passes the specifications of one or more several automotive cable testing protocols: (a) SAE J-1128, (b) ISO-6722, (c) LV 112, (d) Chrysler MS-8288, and (e) Renault 36-36-05009/-L. In particular, the flame retardant insulation layer is prepared from a crosslinkable thermo-plastic polymer and a metal carbonate. The flame retardant composition for making the insulation layer demonstrates economic and processing improvements over conventional solutions. The present invention is also a method for preparing a low tension primary automotive wire and the automotive wire made therefrom.

    Abstract translation: 本发明是一种交联汽车线,其包括金属导体,围绕金属导体的阻燃绝缘层,以及可选地围绕绝缘层的电线护套。 汽车电线通过一个或多个几种汽车电缆测试协议的规范:(a)SAE J-1128,(b)ISO-6722,(c)LV 112,(d)克莱斯勒MS-8288和(e)雷诺 36-36-05009 / -L。 特别地,阻燃绝缘层由可交联的热塑性聚合物和金属碳酸盐制备。 用于制造绝缘层的阻燃组合物显示出相对于常规溶液的经济和加工改进。 本发明也是一种制备低张力一次汽车线材的方法和由其制成的汽车线材。

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