公开(公告)号：US20150166461A1

公开(公告)日：2015-06-18

申请号：US14628362

申请日：2015-02-23

Applicant: BASF SE

Inventor： Wolfgang MACKENROTH ,  Johannes BUETTNER ,  Eckhard STROEFER ,  Wolfgang VOIGT ,  Frank BOK

IPC: C07C201/08

CPC classification number: C07C201/08 ,  C07C205/06

Abstract: A process for the preparation of mononitroaromatics and dinitroaromatics, in which a hydrate melt of at least one metal nitrate M(NO3)3 is used as a nitrating medium, it being possible for M to be the metals Fe, Cr, Y, La, Ce, Al, Bi and In, and the metal nitrate having a water content of from 4 to 9 mol of water per M(NO3)3, leads to simplifications of the process and improved yields.

Abstract translation: 一种制备单硝基芳族化合物和二硝基溴化物的方法，其中使用至少一种金属硝酸盐M（NO 3）3的水合物熔融物作为硝化介质，M可以是金属Fe，Cr，Y，La， Ce，Al，Bi和In，每M（NO 3）3含水量为4〜9mol的金属硝酸盐导致工艺的简化和提高的产率。

公开(公告)号：US20140200370A1

公开(公告)日：2014-07-17

申请号：US14147805

申请日：2014-01-06

Applicant: BASF SE

Inventor： Oliver BEY ,  Andreas RAICHLE ,  Hartmut RIECHERS ,  Roland MUELLER ,  Wolfgang MACKENROTH ,  Peter ZEHNER

IPC: B01J19/26 ,  C07C209/36

CPC classification number: B01J19/26 ,  B01J4/002 ,  B01J8/006 ,  B01J8/226 ,  B01J8/228 ,  B01J10/00 ,  B01J19/246 ,  B01J19/2465 ,  B01J2208/00132 ,  B01J2208/00902 ,  B01J2219/00081 ,  C07C209/36 ,  C07C211/43

Abstract: The present invention relates to an apparatus of the loop Venturi reactor type for the continuous reaction of liquids with gases, in particular for hydrogenations, oxidations or acetylations, e.g. for the preparation of toluenediamine by hydrogenation of dinitrotoluene, and a process for the continuous reaction of liquid reactants with gaseous reactants in the apparatus. Here, the cooling medium surrounds the tubes of the heat exchanger of the apparatus of the invention whereas the reaction takes place in the tubes.

Abstract translation: 本发明涉及一种用于液体与气体的连续反应的文丘里反应器类型的装置，特别是用于氢化，氧化或乙酰化的反应。 用于通过二硝基甲苯的氢化制备甲苯二胺，以及在装置中液体反应物与气态反应物的连续反应的方法。 这里，冷却介质围绕本发明设备的热交换器的管，而反应发生在管中。