公开(公告)号：US10961177B2

公开(公告)日：2021-03-30

申请号：US16494970

申请日：2018-03-06

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Henning Althoefer ,  Harald Dietl

IPC: C07C51/235 ,  C09K5/20 ,  C23F11/12

Abstract: A process for preparing an anticorrosion component for an antifreeze by oxidizing an oxydiol of the formula (I) with molecular oxygen at a temperature of 20 to 100° C. and a partial oxygen pressure of 0.01 to 2 MPa in the presence of water and of a heterogeneous catalyst. The catalyst contains platinum to form an oxydicarboxylic acid of the formula (II) The process has the steps of conducting the oxidation (a) at a molar ratio of 0.002≤n(Pt)/[n(oxydiol (I))+n(oxydicarboxylic acid (II))]≤0.019; (b) at a concentration of water of 50% to 95% by weight in the liquid phase; and (c) at a pH of 1 to 7.

公开(公告)号：US11104634B2

公开(公告)日：2021-08-31

申请号：US16311198

申请日：2017-06-22

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Werner Pottgiesser ,  Henning Althoefer

IPC: C07C51/00 ,  C07C51/235 ,  B01J21/18 ,  B01J23/42

Abstract: A method for producing 2-methoxyacetic acid by oxidizing 2-methoxyethanol in a reaction device using oxygen at a temperature of 20 to 100° C. and an oxygen partial pressure of 0.01 to 2 MPa in the presence of water and a heterogeneous catalyst containing platinum, in which the method is carried out semi-continuously or continuously, and 2-methoxyethanol is added to the reaction device in a temporally and/or spatially distributed manner such that temporally and spatially, the mass ratio of 2-methoxyethanol to 2-methoxyethanol plus water per volume element in the reaction device is constantly ≤0.80 of the mass ratio of the added 2-methoxyethanol to the added 2-methoxyethanol plus water.

公开(公告)号：US10434503B2

公开(公告)日：2019-10-08

申请号：US15030754

申请日：2014-10-22

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Hans-Juergen Luetzel ,  Joaquim Henrique Teles ,  Dominic Riedel ,  Bianca Seelig ,  Daniel Urbanczyk ,  Ulrike Wegerle ,  Michael Hesse ,  Andreas Walch ,  Volker Bendig ,  Veit Stegmann ,  Henning Althoefer ,  Boris Gaspar ,  Frank Stallmach ,  Anne Kristin Pusch

IPC: B01J20/18 ,  B01J29/89 ,  C01B39/40 ,  B01J29/40 ,  B01J39/14 ,  B01J29/035 ,  B01J35/10 ,  B01J37/00 ,  C01B39/08 ,  C01B39/02 ,  B01J20/28 ,  B01J20/30 ,  B01J35/00 ,  B01J37/10 ,  B01J35/02

Abstract: The present invention relates to A process for the production of a molding, comprising (I) providing a zeolitic material; (II) mixing the zeolitic material provided in step (I) with one or more binders; (III) kneading of the mixture obtained in step (II); (IV) molding of the kneaded mixture obtained in step (III) to obtain one or more moldings; (V) drying of the one or more moldings obtained in step (IV); and (VI) calcining of the dried molding obtained in step (V); wherein the zeolitic material provided in step (I) displays a water adsorption ranging from 1 to 15 wt.-% when exposed to a relative humidity of 85%, as well as to a molding obtainable or obtained according to the inventive process in addition to a molding per se and to their respective use.