公开(公告)号：US20030149204A1

公开(公告)日：2003-08-07

申请号：US10351904

申请日：2003-01-27

申请人： Atofina

发明人： Eric Minaux ,  Lucedio Greci ,  Michael Buback ,  Paul Tordo ,  Thierry Senninger ,  Pierluigi Stipa ,  Patricia Carloni ,  Elisabetta Damiani ,  Giampaolo Tommasi

IPC分类号： C08F004/28 ,  C08F004/32

CPC分类号： C08F293/005 ,  C08F4/00 ,  C08F10/02 ,  C08F2438/02 ,  C08F2/40

摘要： A radical (co)polymerization of ethylene is carried out under high pressure in the presence of at least one initiating free radical (Znull) and of at least one controlling stable free radical (SFRnull) which comprises the indoline nitroxide backbone represented by the formula (I). Mention may be made, by way of examples, of the radicals (SFRnull) of formula (II). 1 A is a hydrocarbonaceous chain forming an aromatic ring with the two carbon atoms to which it is attached, this ring being able to carry substituents or being able to carry one or more rings placed side by side, which rings are aromatic or aliphatic and optionally substituted, the carbon atoms forming the nitrogenous ring and in the alpha- and beta-position with respect to the nitrogen atom being, able to carry hydrogen atoms or substituents; R1, R2, R3 and R4, which can be identical or different, each independently represent H; alkyl; alkenyl; aryl; aralkyl; OH; nullOR5, R5nullalkyl, alkenyl, aryl or aralkyl residue; nullCOOH; nullCOOR6, R6nullalkyl, alkenyl, aryl or aralkyl residue; or CN; it being possible for R3 and R4 to merge together into nullX, X representing O or nullNR7, R7nullalkyl, alkenyl, aryl or aralkyl residue; and it being possible for the alkyl, alkenyl, aryl or aralkyl residues coming within the definition of R1 to R6 to carry substituents.

摘要翻译： 乙烯的自由基（共）聚合在高压下在至少一种起始自由基（Z +）和至少一种控制稳定的自由基（SFR＆Circlef）的存在下进行，其包含由 式（I）。 可以通过实例提及式（II）的基团（SFR和环）。 A是形成具有与其连接的两个碳原子的芳香环的烃链，该环能够携带取代基或能够携带一个或多个并排放置的环，该环是芳族或脂族的并任选取代 相对于氮原子形成氮环且在α位和β位的碳原子能够携带氢原子或取代基; 可以相同或不同的R 1，R 2，R 3和R 4各自独立地表示H; 烷基; 烯基; 芳基; 芳烷基 哦; -OR5，R5 =烷基，烯基，芳基或芳烷基残基; -COOH; -COOR 6，R 6 =烷基，烯基，芳基或芳烷基残基; 或CN; R3和R4可以一起合并成= X，X表示O或= NR7，R7 =烷基，烯基，芳基或芳烷基残基; 并且在R1至R6的定义之内的烷基，烯基，芳基或芳烷基残基可能携带取代基。