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公开(公告)号:US4681927A
公开(公告)日:1987-07-21
申请号:US866959
申请日:1986-05-27
申请人: Toshikazu Umemura , Isamu Masumoto , Yukihiro Iha
发明人: Toshikazu Umemura , Isamu Masumoto , Yukihiro Iha
CPC分类号: C08G2/18
摘要: A process for producing an oxymethylene copolymer by copolymerizing trioxane with at least one cyclic comonomer selected from the group consisting of cyclic ethers and cyclic formals, said process comprising (1) polymerizing trioxane alone or with a cyclic comonomer in the presence of a polymerization catalyst until the conversion of trioxane reaches 10 to 95%, and(2) thereafter adding a cyclic comonomer and a polymerization catalyst to the reaction system and continuing the polymerization.
摘要翻译: 一种通过将三恶烷与至少一种选自环醚和环状缩甲醛的环状共聚单体共聚制备甲醛共聚物的方法,所述方法包括(1)在聚合催化剂存在下单独或与环状共聚单体聚合三恶烷直到 三恶烷的转化率达到10〜95%,(2)向反应体系中加入环状共聚单体和聚合催化剂,继续聚合。
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公开(公告)号:US4814424A
公开(公告)日:1989-03-21
申请号:US120314
申请日:1987-11-13
申请人: Takeo Suzumori , Isamu Masumoto , Mitsuo Nakagawa , Yukihiro Iha
发明人: Takeo Suzumori , Isamu Masumoto , Mitsuo Nakagawa , Yukihiro Iha
CPC分类号: C08G2/36
摘要: An improved method of stabilizing a polyoxymethylene copolymer, which comprises(1) heat-melting a crude copolymer of trioxane and a cyclic ether and/or a cyclic acetal to form a first stabilized copolymer having a decomposition ratio (D.sub.220.sup.60), determined when it is heated at 220.degree. C. for 60 minutes in vacuum, of up to 2% by weight, and then(2) bringing the first stabilized copolymer into contact with steam containing 0.01 to 5% by weight of a basic compound at a temperature of at least 100.degree. C. but not exceeding the melting point of the copolymer to form a second stabilized copolymer.
摘要翻译: 一种稳定聚甲醛共聚物的改进方法,其包括(1)将三恶烷和环醚和/或环缩醛的粗共聚物加热熔融以形成具有分解比(D22060)的第一稳定共聚物,当其为 在220℃下真空加热60分钟,最多达2重量%,然后(2)使第一稳定的共聚物与含有0.01至5重量%碱性化合物的蒸汽在温度为 至少100℃,但不超过共聚物的熔点以形成第二稳定的共聚物。
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