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公开(公告)号：US4617416A
公开(公告)日：1986-10-14
申请号：US713603
申请日：1985-03-19
申请人： Renato Ugo , Stefano Campolmi , Vittorio Carletti
发明人： Renato Ugo , Stefano Campolmi , Vittorio Carletti
IPC分类号： C07B61/00 , B01J31/00 , C07C67/00 , C07C325/00 , C07C333/02 , C07C333/04 , C07C333/06 , C07C333/20 , C07C333/22 , C07C155/02
CPC分类号： C07C333/02
摘要： There is disclosed a process for the preparation of thiocarbamates having the following general formula: ##STR1## wherein: R represents alkyl C.sub.1 -C.sub.4 optionally substituted with one or more halogen atoms, alkenyl C.sub.2 -C.sub.4 optionally substituted with one or more halogen atoms, phenyl optionally substituted with one or more halogen atoms, benzyl optionally substituted with one or more halogen atoms on the phenyl ring;R.sup.1 and R.sup.2, equal or different from one another, represent alkyl C.sub.1 -C.sub.4 or cycloalkyl;consisting in reacting organic dithiocarbonates with organic carbamoyl halides, in the presence of an aqueous solution of an inorganic base and a phase transfer catalyst, at a temperature of 10.degree. to 50.degree. C. for time periods of 5 to 10 hours.The thiocarbamates obtained are used as herbicides, fungicides, etc., and in general in various fields of "fine chemicals".
摘要翻译： 公开了制备具有以下通式的硫代氨基甲酸酯的方法：其中：R表示任选被一个或多个卤素原子取代的C 1 -C 4烷基，任选被一个或多个卤素原子取代的烯基C 2 -C 4，苯基 任选地被一个或多个卤素原子取代，苯基上任选被一个或多个卤素原子取代的苄基; R1和R2彼此相同或不同，表示烷基C1-C4或环烷基; 在有机二硫代碳酸酯与有机氨基甲酰卤反应的条件下，在无机碱和相转移催化剂的水溶液存在下，在10〜50℃的温度下反应5〜10小时。 所得的硫代氨基甲酸酯用作除草剂，杀真菌剂等，一般用于“精细化学品”的各个领域。
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公开(公告)号：US4333882A
公开(公告)日：1982-06-08
申请号：US234842
申请日：1981-02-17
IPC分类号： C07C381/04 , C07C20060101 , C07C67/00 , C07C325/00 , C07C119/18
CPC分类号： C07C327/58
摘要： A process is disclosed for preparing N-methylcarbamate of methylthioacetaldoxime, characterized in that an aqueous suspension of methylthioacetaldoxime is additioned, in one step only, with gaseous phosgene and aqueous methylamine in the presence of an inorganic alkaline base substantially at room temperature and pressure.The product obtained, known commercially as "Methomyl", is an important active principle in the field of insecticides.
摘要翻译： 公开了一种制备甲基硫代乙醛肟的N-甲基氨基甲酸酯的方法，其特征在于在无机碱性碱存在下，基本上在室温和高压下，仅在一个步骤中仅加入甲基硫代乙醛肟的水性悬浮液与气体光气和甲胺水溶液。 获得的商品名为“甲氧基”，是杀虫剂领域的重要活性成分。
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公开(公告)号：US4390733A
公开(公告)日：1983-06-28
申请号：US263598
申请日：1981-05-14
CPC分类号： C07C43/23
摘要： The mono-methallyl ether of pyrocatechin of formula (I): ##STR1## is prepared by reacting pyrocatechin of formula (II): ##STR2## with a methallyl halide of formula (III): ##STR3## in a homogeneous dissolving medium, e.g., alcohols, aliphatic polyalcohols and monoethers thereof, or water, in the presence of an organic or inorganic base.The mono-methallyl ether of pyrocatechin is used as an intermediate for organic syntheses and, in particular for synthesizing the product of formula (IV); ##STR4## which is marketed under the tradename "Carbofuran" and is a compound which is the active principle in soil insecticides of different overall compositions which are available on the market.
摘要翻译： 式（I）的焦儿子的单 - 甲代烯丙基醚：通过使式（II）的焦儿茶素：II（II）与式（III）的甲代烯丙基酯反应制备： III）在有机或无机碱的存在下在均匀的溶解介质中，例如醇，脂族多元醇和其单醚或水。 焦儿茶酚的单甲代烯丙基醚用作有机合成的中间体，特别是用于合成式（IV）的产物;
（IV），以商品名“呋喃丹”销售，是市场上可获得的不同总成分的土壤杀虫剂的活性成分的化合物。 -
公开(公告)号：US5500285A
公开(公告)日：1996-03-19
申请号：US373441
申请日：1995-01-17
申请人： Vittorio Carletti , Gianfranco Longhini , Riccardo Po' , Roberto Podesta' , Anna M. Romano , Cecilia Querci
发明人： Vittorio Carletti , Gianfranco Longhini , Riccardo Po' , Roberto Podesta' , Anna M. Romano , Cecilia Querci
IPC分类号： C07F9/53 , C07F9/655 , C07F9/6584 , C08K5/00 , C08K5/52 , C08K5/5397 , D02G3/00
CPC分类号： C07F9/65517 , C07F9/532 , C07F9/6584 , C08K5/0066 , C08K5/5397 , Y10T428/2913
摘要： Phosphino oxide group containing compounds useful as flame retardant additives, having the general formula (I): ##STR1## wherein: X and X.sub.1 represent a hydrogen atom or, when taken jointly, they represent an NR.sub.1 moiety in which R.sub.1 stands for a hydrogen atom; a linear or branched aliphatic C.sub.1 -C.sub.5 moiety; a linear or branched C.sub.2 -C.sub.6 acyl moiety; a phenyl moiety;R represents a cyclic or polycyclic C.sub.4 -C.sub.9 moiety containing two carboxy groups, possibly esterified with univalent alcohols or glycols, or transformed into anhydrides, or two hydroxy groups.
摘要翻译： 含有氧化膦基团的化合物，可用作阻燃添加剂，具有通式（I）：其中：X和X 1表示氢原子，或共同表示NR 1部分，其中R1代表 氢原子; 直链或支链脂族C 1 -C 5部分; 直链或支链C 2 -C 6酰基部分; 苯基部分; R表示含有两个羧基的环状或多环C4-C9部分，可能用一价醇或二醇酯化，或转化成酸酐或两个羟基。
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公开(公告)号：US06034265A
公开(公告)日：2000-03-07
申请号：US64166
申请日：1998-04-22
申请人： Aldo Bosetti , Emanuele Cauchi , Vittorio Carletti , Pietro Cesti
发明人： Aldo Bosetti , Emanuele Cauchi , Vittorio Carletti , Pietro Cesti
IPC分类号： B01J31/04 , C07B61/00 , C07C269/04 , C07C271/26 , C07C271/28
CPC分类号： C07C269/04
摘要： A process for synthesizing aromatic urethanes, which entails:a) reacting an organic carbonate, in an amount which is equal to or greater than a stoichiometric amount, with an aromatic amine at a temperature of00 to 190.degree. C.; andb) recovering the aromatic urethane from the reaction mixture, wherein step a) is carried out by maintaining reaction alcohol in an amount of from 10 to 40 mol % based on a total quantity of alcohol coproduced during the reaction.
摘要翻译： 一种合成芳族氨基甲酸酯的方法，其包括：a）使具有等于或大于化学计量的量的有机碳酸酯与芳族胺在100至190℃的温度下反应; 和b）从反应混合物中回收芳族氨基甲酸酯，其中步骤a）通过将反应醇的维持量相对于反应期间共生产的醇的总量为10〜40摩尔％来进行。
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6.发明授权
公开(公告)号：US4239914A
公开(公告)日：1980-12-16
申请号：US40955
申请日：1979-05-21
摘要： There is disclosed an improved process for selectively preparing 2-(6'-methoxy-2'-naphthyl)-propionic acid in the active antipode (+) form by reacting 2-acetyl-6-methoxynaphthalene, in an organic solvent, with a system consisting of(a) a haloform selected from CHCl.sub.3 and CHBr.sub.3 ;(b) an aqueous solution of an inorganic base selected from NaOH and KOH; and(c) a crown-ether or hydrocarbyl salt of quaternary ammonium, or of phosphonium;and hydrogenating the 2-(6'-methoxy-2'-naphthyl)-acrylic acid thus formed to obtain 2-(6'-methoxy-2'-naphthyl)-propionic acid.
摘要翻译： 公开了一种通过使有机溶剂中的2-乙酰基-6-甲氧基萘与有机溶剂中的2-（6'-甲氧基-2'-萘基）丙酸与有机溶剂反应来选择性地制备活性对映体（+）形式的2-（6'-甲氧基-2'-萘基） 系统由（a）选自CHCl 3和CHBr 3的卤代基组成; （b）选自NaOH和KOH的无机碱的水溶液; 和（c）季铵或鏻的冠醚或烃基盐; 并氢化由此形成的2-（6'-甲氧基-2'-萘基） - 丙烯酸，得到2-（6'-甲氧基-2'-萘基） - 丙酸。
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