公开(公告)号：US4975472A

公开(公告)日：1990-12-04

申请号：US347851

申请日：1989-05-05

申请人： Tsuneo Motegi ,  Yasuji Matsumoto

发明人： Tsuneo Motegi ,  Yasuji Matsumoto

IPC分类号： C08F2/46 ,  C08K5/101 ,  C08K5/1515 ,  C08K5/544 ,  C08L83/04 ,  C08L83/06

CPC分类号： C08K5/101 ,  C08K5/544 ,  C08L83/04 ,  C08G77/16 ,  C08G77/70

摘要： A curable organopolysiloxane composition having condensation-curing properties and ultraviolet-curing properties, comprising (A) a diorganopolysiloxane having a viscosity of 50 to 200,000 cSt, both ends of each molecule thereof being blocked with a silanol group, (B) a silane compound, (C) an (alkyl)acrylic acid derivative, (D) a catalyst for condensation and (E) a sensitizer.

摘要翻译： 一种具有缩合固化性能和紫外线固化性能的可固化的有机基聚硅氧烷组合物，其包含（A）粘度为50至200,000cSt的二有机聚硅氧烷，其每个分子的两端用硅烷醇基封端，（B）硅烷化合物， （C）（烷基）丙烯酸衍生物，（D）用于冷凝的催化剂和（E）敏化剂。

公开(公告)号：US4921926A

公开(公告)日：1990-05-01

申请号：US271985

申请日：1988-11-16

申请人： Tsuneo Motegi ,  Yasuji Matsumoto ,  Kiyoshi Takeda ,  Shuji Chiba

发明人： Tsuneo Motegi ,  Yasuji Matsumoto ,  Kiyoshi Takeda ,  Shuji Chiba

IPC分类号： C08K5/14 ,  C08L83/04 ,  C08L83/06 ,  C08L83/07

CPC分类号： C08L83/04 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20

摘要： A curable polyorganosiloxane composition is disclosed, comprising: (A) 100 parts by weight of polyorganosiloxane having at least two hydroxyl groups or hydrolyzable groups bonded to a silicon atom in the molecule thereof and having a viscosity at 25.degree. C. of 10 to 1,000,000 cSt, (B) 0 to 2,000 parts by weight of polyorganosiloxane having at least two alkenyl groups bonded to a silicon atom in the molecule thereof and having a viscosity at 25.degree. C. of 10 to 1,000,000 cSt, (C) 0.5 to 20 parts by weight of an organosilicon compound having more than 2 (on the average) hydrolyzable groups bonded to a silicon atom in the molecule thereof, (D) 0 to 10 parts by weight of a catalyst for a condensation reaction, and (E) 0.1 to 5 parts by weight of an organic peroxide, wherein at least 0.01 mol % of all organic groups bonded to a silicon atom as contained in (A) to (C) is an alkenyl group. The composition has both condensation reaction curability and ultraviolet ray curability.

摘要翻译： 公开了一种可固化聚有机硅氧烷组合物，其包含：（A）100重量份具有至少两个羟基的聚有机硅氧烷或与其分子中的硅原子键合的可水解基团，并且在25℃下的粘度为10至1,000,000cSt ，（B）0〜2,000重量份具有至少两个与分子中的硅原子键合的烯基的聚有机硅氧烷，其在25℃下的粘度为10〜1,000,000cSt，（C）为0.5〜20份， （D）0〜10重量份用于缩合反应的催化剂的（E）0.1〜5（重量）的有机硅化合物， （A）〜（C）中所含的与硅原子键合的全部有机基团的至少0.01摩尔％为烯基的有机过氧化物。 该组合物具有缩合反应固化性和紫外线固化性。

公开(公告)号：US4721750A

公开(公告)日：1988-01-26

申请号：US25538

申请日：1987-03-13

申请人： Nobuo Nakamura ,  Tsuneo Motegi ,  Yasuji Matsumoto

发明人： Nobuo Nakamura ,  Tsuneo Motegi ,  Yasuji Matsumoto

IPC分类号： C09D143/04 ,  C08K5/10 ,  C08F8/42 ,  C08F130/08 ,  C08F230/08

CPC分类号： C09D143/04

摘要： A primer composition comprising:(A) 100 parts by weight of copolymer obtained by reacting(1) an acrylic compound represented by the following general formula: ##STR1## wherein R.sup.1 and R.sup.2 respectively represent groups selected from the group consisting of a hydrogen atom and monovalent substituted or non-substituted hydrocarbon group; with(2) a silane compound represented by the following formula: ##STR2## wherein R.sup.3 represents a group selected from the group consisting of a hydrogen atom and monovalent substituted or non-substituted hydrocarbon groups, R.sup.4 represents a monovalent substituted or non-substituted hydrocarbon group, and Q.sup.1 represents a divalent hydrocarbon group having 1 to 6 carbon atoms, in the weight ratio of 0.1 to 1,000 wt % with respect to the component (1), in the presence of a free-radical initiator;(B) 0.1 to 500 parts by weight of at least one compound selected from the group consisting of titanium alkoxides, titanium chelate compounds, aluminum alkoxides, aluminum chelate compounds, and iron salts of organic acids;(C) 0.1 to 500 parts by weight of organo silicon compound having at least one unsaturated carbon, attached to a silicon atom, in a molecule;(D) a platinum, palladium, or rhodium catalyst in an amount of 0.1 to 10,000 ppm in terms of each element of the platinum, palladium and rhodium with respect to the component (A); and(E) an organic solvent in an amount of 250 to 3,500 parts by weight with respect to the total amount of (A) through (D) converted into 100 parts by weight.

摘要翻译： 一种底漆组合物，其包含：（A）100重量份通过使（1）由以下通式表示的丙烯酸化合物：其中R1和R2分别表示选自氢原子和 一价取代或未取代的烃基; （2）由下式表示的硅烷化合物：其中R 3表示选自氢原子和一价取代或未取代的烃基的基团，R 4表示一价取代或未取代的烃 在自由基引发剂的存在下，Q1表示碳原子数为1〜6的2价烃基，重量比为0.1〜1000重量％，相对于成分（1） （B）0.1〜500重量份的选自钛醇盐，钛螯合物，铝醇盐，铝螯合物和有机酸的铁中的至少一种化合物; （C）0.1〜500重量份在分子中具有至少一个与硅原子连接的不饱和碳的有机硅化合物; （D）相对于组分（A）的铂，钯和铑的每种元素的量为0.1至10,000ppm的铂，钯或铑催化剂; 和（E）相对于（A）〜（D）的总量转化成100重量份的有机溶剂的量为250〜3,500重量份。

公开(公告)号：US4301269A

公开(公告)日：1981-11-17

申请号：US110060

申请日：1980-01-07

申请人： Mitsuyoshi Hashimoto ,  Kiyoshi Hosokawa ,  Tsuneo Motegi

发明人： Mitsuyoshi Hashimoto ,  Kiyoshi Hosokawa ,  Tsuneo Motegi

IPC分类号： C08L83/00 ,  C08L83/04 ,  C08G77/04

CPC分类号： C08K5/54 ,  C08G77/16 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/70

摘要： A storage-stable, room-temperature-curing polysiloxane composition comprising polydiorganosiloxane having silanol terminal radicals and from 0.5 to 25 parts by weight, per 100 parts by weight of said polydiorganosiloxane, of a curing agent containing from 1.5 to 100 wt. % of silane having the formula ##STR1## wherein R.sup.3 is a substituted or unsubstituted hydrocarbon radical, Q is alkylene or alkylidene, R.sup.4 is ##STR2## wherein R.sup.6 and R.sup.7 are substituted or unsubstituted hydrocarbon radicals, R.sup.5 is hydrogen or a substituted or unsubstituted hydrocarbon radical, n is 1 or 2, a is 0 or 1 and b is 1, 2, 3 or 4, and the balance of the curing agent is tri-acyloxysilane.

摘要翻译： 一种储存稳定的室温固化聚硅氧烷组合物，其包含具有硅烷醇末端基的聚二有机硅氧烷和每100重量份所述聚二有机硅氧烷为0.5至25重量份的含有1.5至100重量％ ％的具有式“IMAGE”的硅烷，其中R 3是取代或未取代的烃基，Q是亚烷基或亚烷基，R 4是其中R 6和R 7是取代或未取代的烃基，R 5是氢或取代或未取代的烃 基团，n为1或2，a为0或1，b为1,2,3或4，其余为固化剂为三酰氧基硅烷。

公开(公告)号：US5371164A

公开(公告)日：1994-12-06

申请号：US82461

申请日：1993-06-25

申请人： Fumihiko Kobayashi ,  Shigeki Matsushita ,  Kazuhisa Ono ,  Tsuneo Motegi

发明人： Fumihiko Kobayashi ,  Shigeki Matsushita ,  Kazuhisa Ono ,  Tsuneo Motegi

IPC分类号： C08L83/06 ,  C08G77/48 ,  C08G77/62 ,  C08K5/5419 ,  C08K5/544 ,  C08L83/04 ,  C08L83/14 ,  F28F9/013 ,  C08G77/06

CPC分类号： F28F9/013 ,  C08G77/485 ,  C08G77/62 ,  C08K5/5419 ,  C08K5/544 ,  C08L83/04 ,  C08L83/14 ,  C08G77/16 ,  C08G77/18 ,  Y10S528/901

摘要： A room-temperature curable polyorganosiloxane composition comprising the following components (A) to (C): (A) 100 parts by weight of (1) a mixture of a terminally reactive polyorganosiloxane represented by the formula R.sup.1.sub.a (R.sub.2 O).sub.3-a SiZ[R.sub.2 SiO].sub.n SiR .sup.1.sub.2 ZSi(OR.sup.2).sub.3-a R.sup.1.sub.a ; (2) a silane represented by the formula R.sup.3.sub.b Si(OR.sup.4).sub.4-b or a partially hydrolyzed condensation product thereof; the amount of (A) (1) being from 85 to 100 parts by weight; (B) from 0.01 to 20 parts by weight of a curing catalyst; and (C) from 0.5 to 20 parts by weight of a polycondensation reaction product of an amino group-containing silane represented by the formula X.sub.c Si(WNH.sub.2)Y.sub.3-c and a silazane represented by the formula X.sub.d Y.sub.3-d SiNHSiY.sub.3-d X.sub.d ; where all symbols are defined in the specification.

摘要翻译： 包含以下组分（A）至（C）的室温可固化聚有机硅氧烷组合物：（A）100重量份的（1）由式R 1a（R 2 O）3-aSiZ [R 2 SiO]表示的末端反应性聚有机硅氧烷 ] nSiR 12ZSi（OR 2）3-aR1a; （2）由式R3bSi（OR4）4-b表示的硅烷或其部分水解缩合产物; （A）（1）的量为85〜100重量份; （B）0.01〜20重量份的固化催化剂; 和（C）0.5〜20重量份由式XcSi（WNH 2）Y 3-c表示的含氨基硅烷的缩聚反应产物和由式XdY3-dSiNHSiY3-dXd表示的硅氮烷; 其中所有符号在规范中定义。