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1.发明授权公开(公告)号：US06182569B2
公开(公告)日：2001-02-06
申请号：US09235933
申请日：1999-01-22
IPC分类号： B41N108
CPC分类号： B41C1/1033 , B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/12 , B41C2201/14 , B41C2210/02 , B41C2210/20 , B41C2210/24 , B41C2210/266
摘要： Provided is a positive working, wet lithographic printing member comprising a hydrophilic metal substrate having disposed thereon a hydrophilic layer, an ablative-absorbing, ink-accepting surface layer and, optionally, an ink-accepting overcoat layer that is not ablative-absorbing. Also provided are methods of preparing such lithographic printing plates, and methods of preparing imaged lithographic printing plates from such lithographic printing plates by imagewise exposure to a laser and a subsequent cleaning step to remove residual laser-induced debris and damaged areas from the hydrophilic layer. The use of water-dispersible carbon blacks with polar groups on the surface of the carbon black and water-based polymers, such as a polyvinyl alcohol, in the ablative-absorbing layer, with the optional addition of the durable, ink-accepting overcoat layer that is not ablative absorbing, improves the ease of the cleaning step and also improves the image resolution, adhesion, and durability upon imaging and use of the printing member.
摘要翻译： 本发明提供一种正性工作湿式平版印刷构件，其包括亲水性金属基底，其上设置有亲水层，烧蚀吸收性油墨接受表面层和任选的不是烧蚀吸收性的油墨接受性外涂层。 还提供了制备这种平版印刷版的方法，以及通过图像曝光于激光从这种平版印刷版制备成像的平版印刷版的方法和随后的清洁步骤，以从亲水层去除残余的激光诱发的碎片和损伤区域。 在烧蚀吸收层中使用碳黑和水基聚合物（如聚乙烯醇）的表面上具有极性基团的水分散性炭黑，可选地添加耐用的油墨接受性外涂层 这不是消融吸收，提高了清洁步骤的容易性，并且还提高了成像和使用印刷部件时的图像分辨率，粘附性和耐久性。
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公开(公告)号：US06598526B2
公开(公告)日：2003-07-29
申请号：US10046791
申请日：2002-01-15
IPC分类号： B41N108
CPC分类号： B41C1/1033 , B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/14 , B41C2210/02 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/266
摘要： Provided is a lithographic printing plate comprising a support substrate having disposed thereon an ablative-absorbing layer and, optionally, a durable, ink-accepting surface layer that is not ablative-absorbing. The ablative-absorbing layer may contain a high weight percent of an organic sulfonic acid component. The printing plate may further comprise a hydrophilic polymeric layer interposed between the ablative-absorbing layer and the substrate. The printing plate also comprises a primer layer underlying the ablative-absorbing layer with an adhesion-promoting agent, such as a zirconium compound, present in the primer layer. Also provided are methods of preparing such lithographic printing plates, and methods of preparing imaged lithographic printing plates from such lithographic printing plates by imagewise exposure to a laser and a subsequent cleaning step with water or with a cleaning solution.
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3.发明授权Lithographic printing members having secondary non-ablative layers for use with laser imaging apparatus 有权平版印刷构件具有用于激光成像设备的次级非烧蚀层公开(公告)号：US06192798B1
公开(公告)日：2001-02-27
申请号：US09235947
申请日：1999-01-22
IPC分类号： B41N114
CPC分类号： B41C1/1033 , B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/12 , B41C2201/14 , B41C2210/02 , B41C2210/20 , B41C2210/24 , B41C2210/266
摘要： Provided is a lithographic printing plate comprising a support substrate having disposed thereon an ablative-absorbing layer and, optionally, a durable, ink-accepting surface layer that is not ablative-absorbing. The ablative-absorbing layer contains a high weight percent of an organic sulfonic acid component. The printing plate may further comprise a hydrophilic polymeric layer interposed between the ablative-absorbing layer and the substrate. The printing plate may also comprise a primer layer underlying the ablative-absorbing layer with an adhesion-promoting agent present in the primer layer. Also provided are methods of preparing such lithographic printing plates, and methods of preparing imaged lithographic printing plates from such lithographic printing plates by imagewise exposure to a laser and a subsequent cleaning step with water or with a cleaning solution.
摘要翻译： 提供了一种平版印刷版，其包括在其上设置有消融吸收层的支撑基板和任选地不具有消融吸收性的耐用的受墨表面层。 烧蚀吸收层含有高重量百分比的有机磺酸组分。 印版还可以包括插入在消融吸收层和基底之间的亲水聚合物层。 印版还可以包括底漆层，其底层层位于烧蚀吸收层下方，并具有底漆层中存在的粘合促进剂。 还提供了制备这种平版印刷版的方法，以及通过成像曝光于激光从这种平版印刷版制备成像的平版印刷版的方法，以及随后用水或清洗溶液的清洗步骤。
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公开(公告)号：US06182570B2
公开(公告)日：2001-02-06
申请号：US09399905
申请日：1999-09-21
IPC分类号： B41N114
CPC分类号： B41C1/1033 , B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/14 , B41C2210/02 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/266
摘要： Provided is a lithographic printing plate comprising a support substrate having disposed thereon an ablative-absorbing layer and, optionally, a durable, ink-accepting surface layer that is not ablative-absorbing. The ablative-absorbing layer may contain a high weight percent of an organic sulfonic acid component. The printing plate may further comprise a hydrophilic polymeric layer interposed between the ablative-absorbing layer and the substrate. The printing plate also comprises a primer layer underlying the ablative-absorbing layer with an adhesion-promoting agent, such as a zirconium compound, present in the primer layer. Also provided are methods of preparing such lithographic printing plates, and methods of preparing imaged lithographic printing plates from such lithographic printing plates by imagewise exposure to a laser and a subsequent cleaning step with water or with a cleaning solution.
摘要翻译： 提供了一种平版印刷版，其包括在其上设置有消融吸收层的支撑基板和任选地不具有消融吸收性的耐用的受墨表面层。 烧蚀吸收层可含有高重量百分比的有机磺酸组分。 印版还可以包括插入在消融吸收层和基底之间的亲水聚合物层。 印刷版还包含存在于底漆层中的消光吸收层下面的底漆层和具有粘合促进剂如锆化合物的底漆层。 还提供了制备这种平版印刷版的方法，以及通过成像曝光于激光从这种平版印刷版制备成像的平版印刷版的方法，以及随后用水或清洗溶液的清洗步骤。
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公开(公告)号：US06357352B1
公开(公告)日：2002-03-19
申请号：US09704858
申请日：2000-11-02
IPC分类号： B41N114
CPC分类号： B41C1/1033 , B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/14 , B41C2210/02 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41C2210/266
摘要： Provided is a lithographic printing plate comprising a support substrate having disposed thereon an ablative-absorbing layer and, optionally, a durable, ink-accepting surface layer that is not ablative-absorbing. The ablative-absorbing layer may contain a high weight per cent of an organic sulfonic acid component. The printing plate may further comprise a hydrophilic polymeric layer interposed between the ablative-absorbing layer and the substrate. The printing plate also comprises a primer layer underlying the ablative-absorbing layer with an adhesion-promoting agent, such as a zirconium compound, present in the primer layer. Also provided are methods of preparing such lithographic printing plates, and methods of preparing imaged lithographic printing plates from such lithographic printing plates by imagewise exposure to a laser and a subsequent cleaning step with water or with a cleaning solution.
摘要翻译： 提供了一种平版印刷版，其包括在其上设置有消融吸收层的支撑基板和任选地不具有消融吸收性的耐用的受墨表面层。 烧蚀吸收层可以含有高重量百分比的有机磺酸组分。 印版还可以包括插入在消融吸收层和基底之间的亲水聚合物层。 印刷版还包含存在于底漆层中的消光吸收层下面的底漆层和具有粘合促进剂如锆化合物的底漆层。 还提供了制备这种平版印刷版的方法，以及通过成像曝光于激光从这种平版印刷版制备成像的平版印刷版的方法，以及随后用水或清洗溶液的清洗步骤。
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6.发明授权Infrared laser-imageable lithographic printing members and methods of preparing and imaging such printing members 有权红外激光可成像平版印刷构件以及制备和成像这种印刷构件的方法公开(公告)号：US06186067B1
公开(公告)日：2001-02-13
申请号：US09410230
申请日：1999-09-30
IPC分类号： B41C110
CPC分类号： B41C1/1033 , B41C2201/02 , B41C2210/02 , B41C2210/08
摘要： Provided are methods of imaging a wet positive working lithographic printing member comprising the steps of providing a positive working printing member comprising a substrate, a hydrophilic layer, an infrared-absorbing layer, and, optionally, an ink-accepting surface layer; exposing the printing member to infrared radiation in an imagewise pattern removing by ablation greater than 10% by weight, and most preferably none of the infrared-absorbing layer and optional ink-accepting surface layer; and removing with water the laser-exposed areas of the infrared-absorbing layer and optional ink-accepting surface layer to reveal the underlying hydrophilic layer. These methods are advantageous in reducing airborne debris and vapors during laser imaging, in increasing the speed of laser imaging, and in providing excellent cleanability and image quality. The printing member may further comprise a primer layer underlying the infrared-absorbing layer with an adhesion-promoting agent present in the primer layer. Also provided are methods of preparing a wet lithographic printing member and wet positive working lithographic printing members prepared according to the methods of this invention.
摘要翻译： 本发明提供一种湿式正性工作平版印刷部件的成像方法，包括以下步骤：提供包括基材，亲水层，红外线吸收层和任选的受墨表面层的正性印刷部件; 以大于10重量％的消融，通过消融成像图案去除红外辐射，最优选红外线吸收层和任选的受墨表面层中的任何一个; 并且用水去除红外线吸收层的激光曝光区域和任选的吸墨表面层，以露出下面的亲水层。 这些方法有利于在激光成像期间减少空气中的碎屑和蒸汽，增加激光成像的速度，以及提供优异的可清洁性和图像质量。 印刷构件还可以包含底层，其底层层位于红外线吸收层的下方，并具有底漆层中存在的粘合促进剂。 还提供了制备根据本发明的方法制备的湿式平版印刷构件和湿式正性平版印刷构件的方法。
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7.发明授权Multilayer photopolymeric printing plates with photoreactive diazo compounds and photopolymerizable compositions 失效具有光反应性重氮化合物和可光聚合组合物的多层光聚合印刷版
公开(公告)号：US4886731A
公开(公告)日：1989-12-12
申请号：US351262
申请日：1989-05-10
申请人： Maria T. Sypek , Thomas P. Rorke
发明人： Maria T. Sypek , Thomas P. Rorke
CPC分类号： G03F7/0955
摘要： Photopolymeric printing plates wherein an electrochemically etched, anodized and silicated aluminum plate has a plurality of coatings applied thereon and wherein at least one of the coatings include a solvent soluble diazo therein.
摘要翻译： 光聚合印刷版，其中电化学蚀刻的阳极氧化和硅酸盐的铝板具有涂覆在其上的多个涂层，并且其中至少一个涂层包括溶剂可溶的重氮。
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8.发明授权Lithographic printing members having secondary non-ablative layers for use with laser imaging apparatus 有权平版印刷构件具有用于激光成像设备的次级非烧蚀层公开(公告)号：US06497178B1
公开(公告)日：2002-12-24
申请号：US09699669
申请日：2000-10-30
IPC分类号： B41N108
CPC分类号： B41C1/1033 , B41C1/1008 , B41C1/1016 , B41C2201/04 , B41C2201/12 , B41C2201/14 , B41C2210/02 , B41C2210/20 , B41C2210/24 , B41C2210/266
摘要： Provided is a lithographic printing plate comprising a support substrate having disposed thereon a hydrophilic layer interposed between the substrate and an ink-accepting ablative-absorbing surface layer. The ink-accepting surface layer comprising a one or more polymers and a sensitizer characterized by absorption of laser radiation. The printing plate may also comprise a primer layer underlying the ink-accepting surface layer with an adhesion-promoting agent present in the primer layer. Also provided are methods of preparing such lithographic printing plates, and methods of preparing imaged lithographic printing plates from such lithographic printing plates by imagewise exposure to a laser and a subsequent cleaning step with water or with a cleaning solution.
摘要翻译： 提供了一种平版印刷版，其包括其上设置有介于基板和吸墨烧蚀吸收表面层之间的亲水层的支撑基板。 所述受墨表面层包含一种或多种聚合物和敏化剂，其特征在于吸收激光辐射。 印刷版还可以包含底漆层，其底层层位于接受油墨的表面层之下，并具有底漆层中存在的粘合促进剂。 还提供了制备这种平版印刷版的方法，以及通过成像曝光于激光从这种平版印刷版制备成像的平版印刷版的方法，以及随后用水或清洗溶液的清洗步骤。
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9.发明授权Infrared laser-imageable lithographic printing members and methods of preparing and imaging such printing members 有权红外激光可成像平版印刷构件以及制备和成像这种印刷构件的方法公开(公告)号：US06490975B1
公开(公告)日：2002-12-10
申请号：US09698802
申请日：2000-10-27
IPC分类号： B41C110
CPC分类号： B41C1/1033 , B41C2201/02 , B41C2210/02 , B41C2210/08
摘要： Provided are methods of imaging a wet positive working lithographic printing member comprising the steps of providing a positive working printing member comprising a substrate, a hydrophilic layer, an infrared-absorbing layer, and, optionally, an ink-accepting surface layer; exposing the printing member to infrared layer imaging in an imagewise pattern removing by ablation not greater than 10% by weight, and most preferably none of the infrared-absorbing layer and optional ink-accepting surface layer; and removing with water the laser-exposed areas of the infrared-absorbing layer and optional ink-accepting surface layer to reveal the underlying hydrophilic layer. These methods are advantageous in reducing airborne debris and vapors during laser imaging, in increasing the speed of laser imaging, and in providing excellent cleanability and image quality. The printing member may further comprise a primer layer underlying the infrared-absorbing layer with an adhesion-promoting agent present in the primer layer. Also provided are methods of preparing a wet lithographic printing member and wet positive working lithographic printing members prepared according to the methods of this invention.
摘要翻译： 本发明提供一种湿式正性工作平版印刷部件的成像方法，包括以下步骤：提供包括基材，亲水层，红外线吸收层和任选的受墨表面层的正性印刷部件; 将印刷部件以不大于10重量％的消融的图像去除图案化图案曝光于红外层成像中，最优选不包括红外线吸收层和任选的受墨表面层; 并且用水去除红外线吸收层的激光曝光区域和任选的吸墨表面层，以露出下面的亲水层。 这些方法有利于在激光成像期间减少空气中的碎屑和蒸汽，增加激光成像的速度，以及提供优异的可清洁性和图像质量。 印刷构件还可以包含底层，其底层层位于红外线吸收层的下方，并具有底漆层中存在的粘合促进剂。 还提供了制备根据本发明的方法制备的湿式平版印刷构件和湿式正性平版印刷构件的方法。
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