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1.发明授权Photochromic materials having extended pi-conjugated systems and compositions and articles including the same 有权具有延伸的π-共轭体系的光致变色材料和包含其的组合物和制品公开(公告)号：US08388872B2
公开(公告)日：2013-03-05
申请号：US13400734
申请日：2012-02-21
申请人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank F. Molock, Jr. , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
发明人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank F. Molock, Jr. , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
IPC分类号： G02B5/23 , C07D311/78 , C07D311/94
CPC分类号： C07D311/78 , C07D405/04 , C07D407/12 , C07D409/04 , C07D493/04 , C07D495/04 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1022 , C09K2211/1059 , C09K2211/1088 , C09K2211/1096 , G03C1/685 , G03C1/73 , Y10T428/31504
摘要： The present invention provides a photochromic material which is an indeno-fused naphthopyran of structural formulas I or II, having a pi-conjugation extending group bonded to the 11-position of the indeno-fused naphthopyran, the pi-conjugation extending group having at least one pendent halo-substituted group bonded thereto. The pi-conjugation extending group extends the pi-conjugation system of said indeno-fused naphthopyran. The 13-position of the indeno-fused naphthopyran is substantially free of spiro-substituents. The invention further provides photochromic materials of specified structure, photochromic compositions, photochromic articles and optical elements that include the photochromic material.
摘要翻译： 本发明提供一种光致变色材料，其是结构式I或II的茚并稠合萘并吡喃，其具有键合到茚并稠合萘并吡喃的11位的π-缀合延伸基团，该π-共轭延伸基团至少具有 一个侧链卤代基团与其键合。 π-共轭延伸基团扩展所述茚并稠合萘并吡喃的π-共轭体系。 茚并稠合萘并吡喃的13位基本上不含螺取代基。 本发明还提供了具有特定结构的光致变色材料，光致变色组合物，光致变色制品和包括光致变色材料的光学元件。
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2.发明授权Photochromic materials having extended pi-conjugated systems and compositions and articles including the same 有权具有延伸的π-共轭体系的光致变色材料和包含其的组合物和制品公开(公告)号：US08147725B2
公开(公告)日：2012-04-03
申请号：US12873735
申请日：2010-09-01
申请人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank Molock , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
发明人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank Molock , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
IPC分类号： G02B5/23 , C07D311/78 , C07D311/94
CPC分类号： C07D311/78 , C07D405/04 , C07D407/12 , C07D409/04 , C07D493/04 , C07D495/04 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1022 , C09K2211/1059 , C09K2211/1088 , C09K2211/1096 , G03C1/685 , G03C1/73 , Y10T428/31504
摘要： The present invention provides a photochromic material which is an indeno-fused naphthopyran having a pi-conjugation extending group bonded to the 11-position of the indeno-fused naphthopyran, the pi-conjugation extending group having at least one pendent halo-substituted group bonded thereto. The pi-conjugation extending group extends the pi-conjugation system of said indeno-fused naphthopyran. The 13-position of the indeno-fused naphthopyran is substantially free of spiro-substituents. The invention further provides photochromic materials of specified structure, photochromic compositions, photochromic articles and optical elements that include the photochromic material.
摘要翻译： 本发明提供了一种光致变色材料，其是茚并稠合萘并吡喃，其具有与茚并稠合萘并吡喃的11位键合的π结合延伸基团，所述π-缀合延伸基团具有至少一个侧挂的卤素取代基团键合 到此。 π-共轭延伸基团扩展所述茚并稠合萘并吡喃的π-共轭体系。 茚并稠合萘并吡喃的13位基本上不含螺取代基。 本发明还提供了具有特定结构的光致变色材料，光致变色组合物，光致变色制品和包括光致变色材料的光学元件。
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3.发明授权Photochromic optical articles prepared with reversible thermochromic materials 有权用可逆热变色材料制备的光致变色光学制品公开(公告)号：US08547625B2
公开(公告)日：2013-10-01
申请号：US12942184
申请日：2010-11-09
IPC分类号： G02F1/01
摘要： Provided is a photochromic optical article including: (a) an optical substrate; (b) a thermally reversible photochromic material; and (c) reversible thermochromic material capable of at least partially filtering UV/visible light at or below room temperature and becoming less capable of filtering UV/visible light at temperatures greater than room temperature. The reversible thermochromic material (c) is operable for filtering light in the range of from 300 to 450 nanometers.
摘要翻译： 本发明提供一种光致变色光学制品，其包括：（a）光学基片; （b）热可逆光致变色材料; 和（c）能够至少部分地过滤室温或室温以下的UV /可见光的可逆热变色材料，并且在大于室温的温度下变得较不能过滤UV /可见光。 可逆热变色材料（c）可用于过滤300至450纳米范围内的光。
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公开(公告)号：US20130065056A1
公开(公告)日：2013-03-14
申请号：US13417662
申请日：2012-03-12
申请人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowies , Frank F. Molock, JR. , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
发明人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowies , Frank F. Molock, JR. , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
IPC分类号： C07D311/94 , C07D413/14 , C07D413/10 , G02B5/23 , C07D405/10
CPC分类号： G02C7/049 , C07D311/94 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1059 , C09K2211/1088 , C09K2211/1096 , G02B1/041 , G02B1/043 , G02C7/102 , Y10T428/31504 , C08L101/14
摘要： The present invention provides ophthalmic devices comprising at least one photochromic material which is an indeno-fused naphthopyran having a pi-conjugation extending group bonded to the 11-position of the indeno-fused naphthopyran, the pi-conjugation extending group having at least one pendent halo-substituted group bonded thereto. The pi-conjugation extending group extends the pi-conjugation system of said indeno-fused naphthopyran. The 13-position of the indeno-fused naphthopyran is substantially free of spiro-substituents. The invention further provides photochromic materials of specified structure, photochromic compositions, photochromic articles and optical elements that include the photochromic materials. Other non-limiting embodiments relate to methods of making the ophthalmic devices comprising photochromic materials.
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5.发明授权Photochromic materials having extended pi-conjugated systems and compositions and articles including the same 有权具有延伸的π-共轭体系的光致变色材料和包含其的组合物和制品公开(公告)号：US08158037B2
公开(公告)日：2012-04-17
申请号：US12873793
申请日：2010-09-01
申请人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank F. Molock, Jr. , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
发明人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank F. Molock, Jr. , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
IPC分类号： G02B5/23 , C07D311/78 , C07D311/94
CPC分类号： G02C7/049 , C07D311/94 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1059 , C09K2211/1088 , C09K2211/1096 , G02B1/041 , G02B1/043 , G02C7/102 , Y10T428/31504 , C08L101/14
摘要： The present invention provides ophthalmic devices comprising at least one photochromic material which is an indeno-fused naphthopyran having a pi-conjugation extending group bonded to the 11-position of the indeno-fused naphthopyran, the pi-conjugation extending group having at least one pendent halo-substituted group bonded thereto. The pi-conjugation extending group extends the pi-conjugation system of said indeno-fused naphthopyran. The 13-position of the indeno-fused naphthopyran is substantially free of spiro-substituents. The invention further provides photochromic materials of specified structure, photochromic compositions, photochromic articles and optical elements that include the photochromic materials. Other non-limiting embodiments relate to methods of making the ophthalmic devices comprising photochromic materials.
摘要翻译： 本发明提供了包含至少一种光致变色材料的眼科装置，其是茚并稠合萘并吡喃，其具有与茚并稠合萘并吡喃的11位键合的π结合延伸基团，所述π-共轭延伸基团具有至少一个侧链 与其键合的卤素取代基。 π-共轭延伸基团扩展所述茚并稠合萘并吡喃的π-共轭体系。 茚并稠合萘并吡喃的13位基本上不含螺取代基。 本发明还提供了具有特定结构的光致变色材料，光致变色组合物，光致变色制品和包括光致变色材料的光学元件。 其它非限制性实施方案涉及制备包含光致变色材料的眼科装置的方法。
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6.发明授权Ophthalmic devices comprising photochromic materials having extended pi-conjugated systems 有权眼科装置包括具有延伸的π共轭系统的光致变色材料公开(公告)号：US08741188B2
公开(公告)日：2014-06-03
申请号：US13417662
申请日：2012-03-12
申请人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank F. Molock, Jr. , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
发明人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank F. Molock, Jr. , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
IPC分类号： G02B5/23 , C07D311/78 , C07D311/94
CPC分类号： G02C7/049 , C07D311/94 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1059 , C09K2211/1088 , C09K2211/1096 , G02B1/041 , G02B1/043 , G02C7/102 , Y10T428/31504 , C08L101/14
摘要： The present invention provides ophthalmic devices comprising at least one photochromic material which is an indeno-fused naphthopyran having a pi-conjugation extending group bonded to the 11-position of the indeno-fused naphthopyran, the pi-conjugation extending group having at least one pendent halo-substituted group bonded thereto. The pi-conjugation extending group extends the pi-conjugation system of said indeno-fused naphthopyran. The 13-position of the indeno-fused naphthopyran is substantially free of spiro-substituents. The invention further provides photochromic materials of specified structure, photochromic compositions, photochromic articles and optical elements that include the photochromic materials. Other non-limiting embodiments relate to methods of making the ophthalmic devices comprising photochromic materials.
摘要翻译： 本发明提供了包含至少一种光致变色材料的眼科装置，其是茚并稠合萘并吡喃，其具有与茚并稠合萘并吡喃的11位键合的π结合延伸基团，所述π-共轭延伸基团具有至少一个侧链 与其键合的卤素取代基。 π-共轭延伸基团扩展所述茚并稠合萘并吡喃的π-共轭体系。 茚并稠合萘并吡喃的13位基本上不含螺取代基。 本发明还提供了具有特定结构的光致变色材料，光致变色组合物，光致变色制品和包括光致变色材料的光学元件。 其它非限制性实施方案涉及制备包含光致变色材料的眼科装置的方法。
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7.发明申请PHOTOCHROMIC MATERIALS HAVING EXTENDED PI-CONJUGATED SYSTEMS AND COMPOSITIONS AND ARTICLES INCLUDING THE SAME 有权具有扩展的PI连接系统和组合物的光致变色材料和包括其的文章公开(公告)号：US20120145975A1
公开(公告)日：2012-06-14
申请号：US13400734
申请日：2012-02-21
申请人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank Molock , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
发明人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank Molock , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
IPC分类号： G02B5/23 , C07D413/14 , C07D413/12 , C07D311/94 , C07D405/10
CPC分类号： C07D311/78 , C07D405/04 , C07D407/12 , C07D409/04 , C07D493/04 , C07D495/04 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1022 , C09K2211/1059 , C09K2211/1088 , C09K2211/1096 , G03C1/685 , G03C1/73 , Y10T428/31504
摘要： The present invention provides a photochromic material which is an indeno-fused naphthopyran of structural formulas I or II, having a pi-conjugation extending group bonded to the 11-position of the indeno-fused naphthopyran, the pi-conjugation extending group having at least one pendent halo-substituted group bonded thereto. The pi-conjugation extending group extends the pi-conjugation system of said indeno-fused naphthopyran. The 13-position of the indeno-fused naphthopyran is substantially free of spiro-substituents. The invention further provides photochromic materials of specified structure, photochromic compositions, photochromic articles and optical elements that include the photochromic material.
摘要翻译： 本发明提供一种光致变色材料，其是结构式I或II的茚并稠合萘并吡喃，其具有键合到茚并稠合萘并吡喃的11位的π-缀合延伸基团，该π-共轭延伸基团至少具有 一个侧链卤代基团与其键合。 π-共轭延伸基团扩展所述茚并稠合萘并吡喃的π-共轭体系。 茚并稠合萘并吡喃的13位基本上不含螺取代基。 本发明还提供了具有特定结构的光致变色材料，光致变色组合物，光致变色制品和包括光致变色材料的光学元件。
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8.发明授权Photochromic optical articles prepared with reversible thermochromic materials 有权用可逆热变色材料制备的光致变色光学制品公开(公告)号：US07911676B2
公开(公告)日：2011-03-22
申请号：US12613827
申请日：2009-11-06
IPC分类号： G02F1/01
摘要： Provided is a photochromic optical articleincluding: (a) an optical substrate; (b) a thermally reversible photochromic material; and (c) reversible thermochromic material capable of at least partially filtering UV/visible light at or below room temperature and becoming less capable of filtering UV/visible light at temperatures greater than room temperature.
摘要翻译： 提供一种光致变色光学制品，包括：（a）光学基片; （b）热可逆光致变色材料; 和（c）能够至少部分地过滤室温或室温以下的UV /可见光的可逆热变色材料，并且在大于室温的温度下变得较不能过滤UV /可见光。
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9.发明申请PHOTOCHROMIC MATERIALS HAVING EXTENDED PI-CONJUGATED SYSTEMS AND COMPOSITIONS AND ARTICLES INCLUDING THE SAME 有权具有扩展的PI连接系统和组合物的光致变色材料和包括其的文章公开(公告)号：US20110042629A1
公开(公告)日：2011-02-24
申请号：US12873735
申请日：2010-09-01
申请人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank Molock , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
发明人： Anu Chopra , Jun Deng , Beon-Kyu Kim , David B. Knowles , Frank Molock , Victor A. Montes , Stephen D. Straight , Wenjing Xiao , Huayun Yu
IPC分类号： G02B5/23 , C07D311/78
CPC分类号： C07D311/78 , C07D405/04 , C07D407/12 , C07D409/04 , C07D493/04 , C07D495/04 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1022 , C09K2211/1059 , C09K2211/1088 , C09K2211/1096 , G03C1/685 , G03C1/73 , Y10T428/31504
摘要： The present invention provides a photochromic material which is an indeno-fused naphthopyran having a pi-conjugation extending group bonded to the 11-position of the indeno-fused naphthopyran, the pi-conjugation extending group having at least one pendent halo-substituted group bonded thereto. The pi-conjugation extending group extends the pi-conjugation system of said indeno-fused naphthopyran. The 13-position of the indeno-fused naphthopyran is substantially free of spiro-substituents. The invention further provides photochromic materials of specified structure, photochromic compositions, photochromic articles and optical elements that include the photochromic material.
摘要翻译： 本发明提供了一种光致变色材料，其是茚并稠合萘并吡喃，其具有与茚并稠合萘并吡喃的11位键合的π结合延伸基团，所述π-缀合延伸基团具有至少一个侧挂的卤素取代基团键合 到此。 π-共轭延伸基团扩展所述茚并稠合萘并吡喃的π-共轭体系。 茚并稠合萘并吡喃的13位基本上不含螺取代基。 本发明还提供了具有特定结构的光致变色材料，光致变色组合物，光致变色制品和包括光致变色材料的光学元件。
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公开(公告)号：US09028728B2
公开(公告)日：2015-05-12
申请号：US13314297
申请日：2011-12-08
申请人： Kevin E. Bancroft , Anu Chopra , Xiao-Man Dai , Beon-Kyu Kim , David B. Knowles , Jason R. Lewis , Victor A. Montes , Stephen D. Straight , Massimiliano Tomasulo , Barry Van Gemert , Robert W. Walters , Wenjing Xiao , Huayun Yu , Elizabeth A. Zezinka
发明人： Kevin E. Bancroft , Anu Chopra , Xiao-Man Dai , Beon-Kyu Kim , David B. Knowles , Jason R. Lewis , Victor A. Montes , Stephen D. Straight , Massimiliano Tomasulo , Barry Van Gemert , Robert W. Walters , Wenjing Xiao , Huayun Yu , Elizabeth A. Zezinka
IPC分类号： G02B5/23 , C07D405/04 , C07D405/10 , C07D407/12 , C07D409/04 , C07D493/04 , C07D495/04 , C09K9/02 , G03C1/73 , C07D311/78 , C07D311/94 , G03C1/00 , G03C1/685
CPC分类号： C07D405/04 , C07D311/78 , C07D311/94 , C07D405/10 , C07D407/12 , C07D409/04 , C07D493/04 , C07D495/04 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1022 , C09K2211/1033 , C09K2211/1059 , C09K2211/1088 , G02B5/23 , G03C1/685 , G03C1/73 , Y10T428/31504
摘要： The present invention relates to photochromic materials that include one or more indeno-fused naphthopyrans that have particular groups at the 7, 11, and 13 positions thereof, and at the position alpha to the oxygen of the pyran ring thereof. With some embodiments, hydrogen or an alkoxy group is bonded to the 7 position, an optionally substituted phenyl is bonded to the 11 position, two alkyl groups are bonded to the 13 position, and two optionally substituted phenyl groups are bonded to the position alpha to the oxygen of the pyran ring of the indeno-fused naphthopyran compound. The 13 position of the indeno-fused naphthopyrans is free of ether groups in which an ether oxygen is bonded to the 13 position, and hydroxyl. The present invention also relates to photochromic articles and compositions that include such indeno-fused naphthopyrans.
摘要翻译： 本发明涉及光致变色材料，其包括一种或多种茚并稠合的萘并吡喃，其在其7,11和13位具有特定基团，并且在其吡喃环的氧的位置。 在一些实施方案中，氢或烷氧基键合至7位，任选取代的苯基键合至11位，两个烷基键合至13位，并且两个任选取代的苯基键合至位置α 茚并稠合萘并吡喃化合物的吡喃环的氧。 茚并稠合萘并吡喃的13位没有醚基，其中醚氧与13位结合，羟基。 本发明还涉及包含这种茚并稠合萘并吡喃的光致变色制品和组合物。
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