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1.发明申请SUPPORTED MO-O-K-MExOy CATALYST FOR THE SYNTHESIS OF METHANETHIOL FROM HIGH H2S-CONTAINING SYNGAS 有权用于从含H2S的合成方法合成甲基化的MO-O-K-MEXOY催化剂公开(公告)号：US20100286448A1
公开(公告)日：2010-11-11
申请号：US12810688
申请日：2008-11-28
申请人： Yiquan Yang , Yingjuan Hao , Aiping Chen , Qi Wang , Lingmei Yang , Qiaoling Li , Shenjun Dai , Weiping Fang , Jan-Olaf Barth , Christoph Wecbecker , Klaus Hutmacher
发明人： Yiquan Yang , Yingjuan Hao , Aiping Chen , Qi Wang , Lingmei Yang , Qiaoling Li , Shenjun Dai , Weiping Fang , Jan-Olaf Barth , Christoph Wecbecker , Klaus Hutmacher
IPC分类号： C07C319/06 , B01J23/02 , B01J23/10 , B01J23/883 , B01J23/881 , B01J23/882 , B01J21/08 , B01J21/06 , B01J29/04 , B01J27/19 , B01J23/28 , C07C319/02
CPC分类号： B01J23/28 , B01J21/063 , B01J23/002 , B01J23/8872 , B01J37/0207 , B01J37/16 , B01J2523/00 , C07C319/02 , C07C321/04 , B01J2523/13 , B01J2523/68
摘要： This invention is related to a preparation method of a supported catalyst Mo—O—K-MexOy for the synthesis of methanethiol from H2S-containing syngas. The catalyst comprises of an active component of Mo—O—K-based species, an active promoter and a support denoted as metal (or metals)-carrier. The support is prepared by electroless plating method in such a way that the metal or metals chosen are plated onto the surface of the carrier. Transition metal, especially Fe, Co or Ni are selected to be the plating metal, while SiO2, Al2O3 or TiO2 are selected to be carrier. The catalyst thus prepared is found to be efficient for the synthesis of methanethiol from H2S-containing syngasor carbon oxides/hydrogen mixtures, especially regarding a minor formation of the by-product CO2.
摘要翻译： 本发明涉及用于从含H2S的合成气合成甲硫醇的负载型催化剂Mo-O-K-MexOy的制备方法。 该催化剂包括Mo-O-K基活性组分，活性促进剂和表示为金属（或金属）载体的载体。 通过化学镀方法制备载体，使得所选择的金属或金属镀在载体的表面上。 选择过渡金属，特别是Fe，Co或Ni作为电镀金属，而选择SiO 2，Al 2 O 3或TiO 2作为载体。 发现如此制备的催化剂对于从含H2S的合成气碳氢氧化物/氢混合物合成甲硫醇是有效的，特别是对副产物CO 2的次要形成。
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2.发明授权Supported Mo—O—K—MexOy catalyst for the synthesis of methanethiol from high H2S-containing syngas 有权支持的Mo-O-K-Mex用于从高H 2 S的合成气合成甲硫醇的催化剂公开(公告)号：US09409153B2
公开(公告)日：2016-08-09
申请号：US12810688
申请日：2008-11-28
申请人： Yiquan Yang , Yingjuan Hao , Aiping Chen , Qi Wang , Lingmei Yang , Qiaoling Li , Shenjun Dai , Weiping Fang , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher
发明人： Yiquan Yang , Yingjuan Hao , Aiping Chen , Qi Wang , Lingmei Yang , Qiaoling Li , Shenjun Dai , Weiping Fang , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher
IPC分类号： B01J21/08 , B01J23/04 , B01J23/28 , B01J23/88 , B01J23/882 , B01J23/883 , B01J23/00 , B01J23/887 , B01J37/02 , B01J37/16 , C07C319/02 , B01J21/06
CPC分类号： B01J23/28 , B01J21/063 , B01J23/002 , B01J23/8872 , B01J37/0207 , B01J37/16 , B01J2523/00 , C07C319/02 , C07C321/04 , B01J2523/13 , B01J2523/68
摘要： This invention is related to a preparation method of a supported catalyst Mo—O—K-MexOy for the synthesis of methanethiol from H2S-containing syngas. The catalyst comprises of an active component of Mo—O—K-based species, an active promoter and a support denoted as metal (or metals)-carrier. The support is prepared by electroless plating method in such a way that the metal or metals chosen are plated onto the surface of the carrier. Transition metal, especially Fe, Co or Ni are selected to be the plating metal, while SiO2, Al2O3 or TiO2 are selected to be carrier. The catalyst thus prepared is found to be efficient for the synthesis of methanethiol from H2S-containing syngasor carbon oxides/hydrogen mixtures, especially regarding a minor formation of the by-product CO2.
摘要翻译： 本发明涉及用于从含H2S的合成气合成甲硫醇的负载型催化剂Mo-O-K-MexOy的制备方法。 该催化剂包括Mo-O-K基活性组分，活性促进剂和表示为金属（或金属）载体的载体。 通过化学镀方法制备载体，使得所选择的金属或金属镀在载体的表面上。 选择过渡金属，特别是Fe，Co或Ni作为电镀金属，而选择SiO 2，Al 2 O 3或TiO 2作为载体。 发现如此制备的催化剂对于从含H2S的合成气碳氢氧化物/氢混合物合成甲硫醇是有效的，特别是对副产物CO 2的次要形成。
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公开(公告)号：US07833929B2
公开(公告)日：2010-11-16
申请号：US12509120
申请日：2009-07-24
申请人： Yiquan Yang , Qi Wang , Renchun Lin , Hongbin Zhang , Youzhu Yuan , Weiping Fang , Quanxing Zheng , Shenjun Dai , Xingguo Yan , Aiping Chen , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher , Hubert Redlingshöfer , Sabine Ackermann
发明人： Yiquan Yang , Qi Wang , Renchun Lin , Hongbin Zhang , Youzhu Yuan , Weiping Fang , Quanxing Zheng , Shenjun Dai , Xingguo Yan , Aiping Chen , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher , Hubert Redlingshöfer , Sabine Ackermann
CPC分类号： B01J37/0203 , B01J23/28 , B01J23/8872 , B01J37/0201 , C07C319/02 , Y02P20/582 , C07C321/04
摘要： The present invention refers to a continuous process for the manufacture of methyl mercaptan using Mo—O—K-based catalysts. It is further described that the total selectivity of methylmercaptan can be increased by at least 1% by lowering the total gas hourly space velocity. The invention further refers to a process for the preparation of a solid, preformed catalyst system.
摘要翻译： 本发明涉及使用Mo-O-K系催化剂制造甲硫醇的连续方法。 进一步描述的是，通过降低总气体时空速度，甲基硫醇的总选择性可以增加至少1％。 本发明还涉及制备固体预成型催化剂体系的方法。
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公开(公告)号：US20070213564A1
公开(公告)日：2007-09-13
申请号：US10595333
申请日：2004-09-29
申请人： Yiquan Yang , Qi Wang , Renchun Lin , Hongbin Zhang , Youzhu Yuan , Weiping Fang , Quanxing Zheng , Shenjun Dai , Xingguo Yan , Aiping Chen , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher , Hubert Redlingshofer , Sabine Ackermann
发明人： Yiquan Yang , Qi Wang , Renchun Lin , Hongbin Zhang , Youzhu Yuan , Weiping Fang , Quanxing Zheng , Shenjun Dai , Xingguo Yan , Aiping Chen , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher , Hubert Redlingshofer , Sabine Ackermann
IPC分类号： C07C319/04 , B01J23/28 , C07C321/04
CPC分类号： B01J37/0203 , B01J23/28 , B01J23/8872 , B01J37/0201 , C07C319/02 , Y02P20/582 , C07C321/04
摘要： The present invention refers to a continuous process for the manufacture of methyl mercaptan using Mo-O—K-based catalysts. It is further described that the total selectivity of methylmercaptan can be increased by at least 1% by lowering the total gas hourly space velocity. The invention further refers to a process for the preparation of a solid, preformed catalyst system.
摘要翻译： 本发明涉及使用Mo-O-K系催化剂制造甲硫醇的连续方法。 进一步描述的是，通过降低总气体时空速度，甲基硫醇的总选择性可以增加至少1％。 本发明还涉及制备固体预成型催化剂体系的方法。
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公开(公告)号：US20100041548A1
公开(公告)日：2010-02-18
申请号：US12509120
申请日：2009-07-24
申请人： Yiquan YANG , Qi Wang , Renchun Lin , Hongbin Zhang , Youzhu Yuan , Weiping Fang , Quanxing Zheng , Shenjun Dai , Xingguo Yan , Aiping Chen , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher , Hubert Redlingshöfer , Sabine Ackermann
发明人： Yiquan YANG , Qi Wang , Renchun Lin , Hongbin Zhang , Youzhu Yuan , Weiping Fang , Quanxing Zheng , Shenjun Dai , Xingguo Yan , Aiping Chen , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher , Hubert Redlingshöfer , Sabine Ackermann
CPC分类号： B01J37/0203 , B01J23/28 , B01J23/8872 , B01J37/0201 , C07C319/02 , Y02P20/582 , C07C321/04
摘要： The present invention refers to a continuous process for the manufacture of methyl mercaptan using Mo—O—K-based catalysts. It is further described that the total selectivity of methylmercaptan can be increased by at least 1% by lowering the total gas hourly space velocity. The invention further refers to a process for the preparation of a solid, preformed catalyst system.
摘要翻译： 本发明涉及使用Mo-O-K系催化剂制造甲硫醇的连续方法。 进一步描述的是，通过降低总气体时空速度，甲基硫醇的总选择性可以增加至少1％。 本发明还涉及制备固体预成型催化剂体系的方法。
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公开(公告)号：US07569731B2
公开(公告)日：2009-08-04
申请号：US10595333
申请日：2004-09-29
申请人： Yiquan Yang , Qi Wang , Renchun Lin , Hongbin Zhang , Youzhu Yuan , Weiping Fang , Quanxing Zheng , Shenjun Dai , Xingguo Yan , Aiping Chen , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher , Hubert Redlingshöfer , Sabine Ackermann
发明人： Yiquan Yang , Qi Wang , Renchun Lin , Hongbin Zhang , Youzhu Yuan , Weiping Fang , Quanxing Zheng , Shenjun Dai , Xingguo Yan , Aiping Chen , Jan-Olaf Barth , Christoph Weckbecker , Klaus Huthmacher , Hubert Redlingshöfer , Sabine Ackermann
IPC分类号： C07C319/16
CPC分类号： B01J37/0203 , B01J23/28 , B01J23/8872 , B01J37/0201 , C07C319/02 , Y02P20/582 , C07C321/04
摘要： The present invention refers to a continuous process for the manufacture of methyl mercaptan using Mo—O—K-based catalysts. It is further described that the total selectivity of methylmercaptan can be increased by at least 1% by lowering the total gas hourly space velocity. The invention further refers to a process for the preparation of a solid, preformed catalyst system.
摘要翻译： 本发明涉及使用Mo-O-K系催化剂制造甲硫醇的连续方法。 进一步描述的是，通过降低总气体时空速度，甲基硫醇的总选择性可以增加至少1％。 本发明还涉及制备固体预成型催化剂体系的方法。
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