Copolyamides and polyamide compositions, process of manufacture and
applications
    2.
    发明授权
    Copolyamides and polyamide compositions, process of manufacture and applications 失效
    共聚酰胺和聚酰胺组合物,制造和应用的过程

    公开(公告)号:US6143862A

    公开(公告)日:2000-11-07

    申请号:US156876

    申请日:1998-09-18

    CPC分类号: C08G69/14 C08G69/08

    摘要: Colpolyamides resulting from the polycondensation of a mixture of (a) dodecanelactam (L12) or of 12-aminododecanoic acid (A12) and of (b) 11-aminoundecanoic acid (A11) are characterized in that the monomer L12 or A12 represents 1 to 15% or 85 to 99% by weight of the mixture, and the copolyamides have melting points (mp) as a function of the composition, the units originating from the monomer A12 and L12 being in a majority or minority respectively:(1) A12 or L12 is a majority: mp (.degree. C.).gtoreq.176-0.567.times.(% A11)(2) A12 or L12 is a majority: mp (.degree.).gtoreq.187-0.5.times.(% A12 or L12),the melting points being determined by taking the peaks of the exotherm signals obtained in differential thermal analysis with a rate of heating of 10.degree. C./minute for the second heating run. Such copolyamides have a property of resilience at low temperature and a property of improved suppleness, especially when plasticizer is added to them. Their ductile/brittle transition temperature is shifted towards a lower temperature.

    摘要翻译: 由(a)十二内酰胺(L12)或12-氨基十二烷酸(A12)和(b)11-氨基十一烷酸(A11)的混合物缩聚得到的共聚酰胺的特征在于,单体L12或A12表示1〜15 %或85至99重量%,共聚酰胺具有作为组合物的函数的熔点(mp),源自单体A12和L12的单元分别为多数或少数:(1)A12或 L12为多数:mp(℃)> / = 176-0.567x(%A11)(2)A12或L12为多数:mp(℃)= 187-0.5倍(%A12或L12) 通过在差热分析中获得的放热信号的峰值以10℃/分钟的速率进行第二次加热运行来确定熔点。 这种共聚酰胺在低温下具有回弹性能,并具有改善柔软性的特性,特别是当添加增塑剂时。 它们的延性/脆性转变温度向较低的温度转移。

    Pipes, based on polyamide and polyolefin, for gas transmission and/or distribution
    3.
    发明授权
    Pipes, based on polyamide and polyolefin, for gas transmission and/or distribution 失效
    用于气体传输和/或分配的基于聚酰胺和聚烯烃的管道

    公开(公告)号:US06616191B2

    公开(公告)日:2003-09-09

    申请号:US08836522

    申请日:1997-09-22

    IPC分类号: F16L5500

    CPC分类号: F16L58/04 F16L11/04

    摘要: The present invention relates to pipes for the transmission and/or distribution of combustible gases, and liquefied gases, comprising a polyethylene layer and a polyamide inside and/or outside layer. These pipes may advantageously be connected together by adhesively bonded sleeves and thus form medium-pressure and low-pressure gas distribution and transmission networks or else they may be installed inside already existing metal pipes. These pipes may be manufactured by coextrusion.

    摘要翻译: 本发明涉及用于传输和/或分配可燃气体的管道和液化气体,其包括聚乙烯层和内层和/或外层中的聚酰胺。 这些管道可以有利地通过粘合的套筒连接在一起,从而形成中压和低压的气体分配和输送网络,或者它们可以安装在已经存在的金属管内。这些管可以通过共挤出来制造。

    Method of manufacturing polyamides
    4.
    发明授权
    Method of manufacturing polyamides 失效
    制造聚酰胺的方法

    公开(公告)号:US06228976B1

    公开(公告)日:2001-05-08

    申请号:US09158577

    申请日:1998-09-22

    IPC分类号: C08G6914

    CPC分类号: C08G69/18 C08G69/16

    摘要: The invention relates to a method of preparing polyamides, in which, in a first step, the anionic polymerization of at least one lactam is carried out and then, in a second step, a heat treatment is carried out on the polymer obtained, which has a distribution of the molar masses measured by SEC having a shape close to a Gaussian curve with a high-mass tail, at a high enough temperature and for a long enough time so as to obtain a unimodal distribution of the molar masses.

    摘要翻译: 本发明涉及一种制备聚酰胺的方法,其中在第一步中进行至少一种内酰胺的阴离子聚合,然后在第二步中对获得的聚合物进行热处理,所述聚合物具有 在足够高的温度和足够长的时间内,用具有高质量尾巴的形状接近高斯曲线的SEC测量的摩尔质量分布,并获得摩尔质量的单峰分布。