公开(公告)号：US07410556B1

公开(公告)日：2008-08-12

申请号：US10130990

申请日：2000-11-27

申请人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

发明人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

IPC分类号： B01D3/10 ,  B01D3/28 ,  C07C51/44 ,  B01D1/22

CPC分类号： C07C51/44 ,  Y10S159/16 ,  C07C59/08

摘要： The invention relates to a method and a device for the purification of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C., which further has approximately 275 g carboxylate ions/1 or less, preferably 250 g carboxylate ions/1 or less, and preferably less than 1% by weight ionic impurities, calculated on the basis of the total solution. In particular, the invention relates to a method and a device for the continuous purification and concentration, on an industrial scale, of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C. According to the method, this solution is subjected to two or more distillation steps, the first distillation step being carried out at a temperature of from 80° to 150° C. and a pressure of from 50 to 250 mbar, and the second distillation step being carried out at a temperature of from 80° to 200° C. and a pressure of from 0.01 to 50 mbar.

摘要翻译： 本发明涉及一种纯化有机酸水溶液的方法和装置，所述水溶液的沸点在常压低于450℃，进一步具有约275g羧酸根离子/ 1或更少，优选250 g羧酸根离子/ 1个或更少，优选小于1重量％的离子杂质，基于总溶液计算。 具体地说，本发明涉及在大气压低于450℃的有机酸的水溶液中以工业规模连续净化和浓缩的方法和装置。根据该方法 ，将该溶液进行两个或更多个蒸馏步骤，第一蒸馏步骤在80℃至150℃的温度和50至250毫巴的压力下进行，第二蒸馏步骤在 温度为80℃至200℃，压力为0.01至50毫巴。

公开(公告)号：US20110089016A1

公开(公告)日：2011-04-21

申请号：US12973775

申请日：2010-12-20

申请人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

发明人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

IPC分类号： B01D3/10 ,  B01D3/14

CPC分类号： C07C51/44 ,  Y10S159/16 ,  C07C59/08

摘要： The invention relates to a method and a device for the purification of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C., which further has approximately 275 g carboxylate ions/l or less, preferably 250 g carboxylate ions/l or less, and preferably less than 1% by weight ionic impurities, calculated on the basis of the total solution. In particular, the invention relates to a method and a device for the continuous purification and concentration, on an industrial scale, of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C. According to the method, this solution is subjected to two or more distillation steps, the first distillation step being carried out at a temperature of from 80° to 150° C. and a pressure of from 50 to 250 mbar, and the second distillation step being carried out at a temperature of from 80° to 200° C. and a pressure of from 0.01 to 50 mbar.

摘要翻译： 本发明涉及一种纯化有机酸的水溶液的方法和装置，所述水溶液的沸点在常压下小于450℃，进一步具有约275g羧酸根离子/ l或更少，优选250 g羧酸根离子/ l以下，优选小于1重量％的离子性杂质，基于总溶液计算。 具体地说，本发明涉及在大气压低于450℃的有机酸的水溶液中以工业规模连续净化和浓缩的方法和装置。根据该方法 ，将该溶液进行两个或更多个蒸馏步骤，第一蒸馏步骤在80℃至150℃的温度和50至250毫巴的压力下进行，第二蒸馏步骤在 温度为80℃至200℃，压力为0.01至50毫巴。

公开(公告)号：US07875153B2

公开(公告)日：2011-01-25

申请号：US11780388

申请日：2007-07-19

申请人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Jose Maria Vidal Lancis ,  Margarita Camprubi Vila

发明人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Jose Maria Vidal Lancis ,  Margarita Camprubi Vila

IPC分类号： B01D1/22 ,  B01D3/10 ,  B01D3/28

CPC分类号： C07C51/44 ,  Y10S159/16 ,  C07C59/08

摘要： The invention relates to a method and a device for the purification of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C., which-further has approximately 275 g carboxylate ions/1 or less, preferably 250 g carboxylate ions/1 or less, and preferably less than 1% by weight ionic impurities, calculated on the basis of the total solution. In particular, the invention relates to a method and a device for the continuous purification and concentration, on an industrial scale, of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C. According to the method, this solution is subjected to two or more distillation steps, the first distillation step being carried out at a temperature of from 80° to 150° C. and a pressure of from 50 to 250 mbar, and the second distillation step being carried out at a temperature of from 80° to 200° C. and a pressure of from 0.01 to 50 mbar.

摘要翻译： 本发明涉及一种纯化有机酸的水溶液的方法和装置，所述水溶液的沸点在常压下小于450℃，其进一步具有约275g羧酸根离子/ 1或更少，优选 基于总溶液计算的250g羧酸根离子/ 1个或更少，优选小于1重量％的离子杂质。 具体地说，本发明涉及在大气压低于450℃的有机酸的水溶液中以工业规模连续净化和浓缩的方法和装置。根据该方法 ，将该溶液进行两个或更多个蒸馏步骤，第一蒸馏步骤在80℃至150℃的温度和50至250毫巴的压力下进行，第二蒸馏步骤在 温度为80℃至200℃，压力为0.01至50毫巴。

公开(公告)号：US20080308402A1

公开(公告)日：2008-12-18

申请号：US11780388

申请日：2007-07-19

申请人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

发明人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

IPC分类号： B01D3/10

CPC分类号： C07C51/44 ,  Y10S159/16 ,  C07C59/08

摘要： The invention relates to a method and a device for the purification of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C., which-further has approximately 275 g carboxylate ions/1 or less, preferably 250 g carboxylate ions/1 or less, and preferably less than 1% by weight ionic impurities, calculated on the basis of the total solution. In particular, the invention relates to a method and a device for the continuous purification and concentration, on an industrial scale, of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C. According to the method, this solution is subjected to two or more distillation steps, the first distillation step being carried out at a temperature of from 80° to 150° C. and a pressure of from 50 to 250 mbar, and the second distillation step being carried out at a temperature of from 80° to 200° C. and a pressure of from 0.01 to 50 mbar.

摘要翻译： 本发明涉及一种纯化有机酸的水溶液的方法和装置，所述水溶液的沸点在常压下小于450℃，其进一步具有约275g羧酸根离子/ 1或更少，优选 基于总溶液计算的250g羧酸根离子/ 1个或更少，优选小于1重量％的离子杂质。 具体地说，本发明涉及在大气压低于450℃的有机酸的水溶液中以工业规模连续净化和浓缩的方法和装置。根据该方法 ，将该溶液进行两个或更多个蒸馏步骤，第一蒸馏步骤在80℃至150℃的温度和50至250毫巴的压力下进行，第二蒸馏步骤在 温度为80℃至200℃，压力为0.01至50毫巴。

公开(公告)号：US06630603B1

公开(公告)日：2003-10-07

申请号：US09937219

申请日：2002-01-16

申请人： Jan Van Breugel ,  Jan Van Krieken ,  Agusti Cerda Baró ,  José Maria Vidal Lancis ,  Margarita Camprubi Vila

发明人： Jan Van Breugel ,  Jan Van Krieken ,  Agusti Cerda Baró ,  José Maria Vidal Lancis ,  Margarita Camprubi Vila

IPC分类号： C07C5142

CPC分类号： C07C51/43 ,  C07C51/44 ,  C07C59/08

摘要： The present invention relates to a method of industrial-scale purification of lactic acid, the method including the steps of: (a) reduced-pressure distillation of a concentrated lactic acid solution having a total acid content of at least 95 wt % and a content of monomeric lactic acid of at least 80 wt %, based on the concentrated lactic acid solution, the ratio between the lactic acid enantiomers in the concentrated lactic acid solution not being equal to 1; and (b) subjecting the concentrated lactic acid solution to a crystallization to form a pure lactic acid. The invention also relates to the lactic acid or the lactic acid solution obtained via this method, and the use thereof.

摘要翻译： 本发明涉及一种乳酸工业级纯化方法，该方法包括以下步骤：（a）将总酸含量至少为95重量％，浓度为95重量％的浓缩乳酸溶液进行减压蒸馏， 基于浓缩的乳酸溶液至少80重量％的单体乳酸，浓乳酸溶液中的乳酸对映异构体之比不等于1; 和（b）使浓缩的乳酸溶液进行结晶以形成纯的乳酸。本发明还涉及通过该方法获得的乳酸或乳酸溶液及其用途。

公开(公告)号：US07879197B2

公开(公告)日：2011-02-01

申请号：US12104302

申请日：2008-04-16

申请人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

发明人： Hendrik Martinus Winkelaar ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

IPC分类号： B01D3/02 ,  B01D3/28

CPC分类号： C07C51/44 ,  Y10S159/16 ,  C07C59/08

摘要： The invention relates to a method and a device for the purification of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C., which further has approximately 275 g carboxylate ions/l or less, preferably 250 g carboxylate ions/l or less, and preferably less than 1% by weight ionic impurities, calculated on the basis of the total solution. In particular, the invention relates to a method and a device for the continuous purification and concentration, on an industrial scale, of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C. According to the method, this solution is subjected to two or more distillation steps, the first distillation step being carried out at a temperature of from 80° to 150° C. and a pressure of from 50 to 250 mbar, and the second distillation step being carried out at a temperature of from 80° to 200° C. and a pressure of from 0.01 to 50 mbar.

摘要翻译： 本发明涉及一种纯化有机酸的水溶液的方法和装置，所述水溶液的沸点在常压下小于450℃，进一步具有约275g羧酸根离子/ l或更少，优选250 g羧酸根离子/ l以下，优选小于1重量％的离子性杂质，基于总溶液计算。 具体地说，本发明涉及在大气压低于450℃的有机酸的水溶液中以工业规模连续净化和浓缩的方法和装置。根据该方法 ，将该溶液进行两个或更多个蒸馏步骤，第一蒸馏步骤在80℃至150℃的温度和50至250毫巴的压力下进行，第二蒸馏步骤在 温度为80℃至200℃，压力为0.01至50毫巴。

公开(公告)号：US20080257710A1

公开(公告)日：2008-10-23

申请号：US12104302

申请日：2008-04-16

申请人： Hendrik Martinus WINKELAAR ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

发明人： Hendrik Martinus WINKELAAR ,  Jan Van Breugel ,  Margarita Camprubi Vila ,  Jose Maria Vidal Lancis

IPC分类号： B01D3/10

CPC分类号： C07C51/44 ,  Y10S159/16 ,  C07C59/08

摘要： The invention relates to a method and a device for the purification of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C., which further has approximately 275 g carboxylate ions/l or less, preferably 250 g carboxylate ions/l or less, and preferably less than 1% by weight ionic impurities, calculated on the basis of the total solution. In particular, the invention relates to a method and a device for the continuous purification and concentration, on an industrial scale, of an aqueous solution of an organic acid having a boiling point at atmospheric pressure of less than 450° C. According to the method, this solution is subjected to two or more distillation steps, the first distillation step being carried out at a temperature of from 80° to 150° C. and a pressure of from 50 to 250 mbar, and the second distillation step being carried out at a temperature of from 80° to 200° C. and a pressure of from 0.01 to 50 mbar.

摘要翻译： 本发明涉及一种纯化有机酸的水溶液的方法和装置，所述水溶液的沸点在常压下小于450℃，进一步具有约275g羧酸根离子/ l或更少，优选250 g羧酸根离子/ l以下，优选小于1重量％的离子性杂质，基于总溶液计算。 具体地说，本发明涉及在大气压低于450℃的有机酸的水溶液中以工业规模连续净化和浓缩的方法和装置。根据该方法 ，将该溶液进行两个或更多个蒸馏步骤，第一蒸馏步骤在80℃至150℃的温度和50至250毫巴的压力下进行，第二蒸馏步骤在 温度为80℃至200℃，压力为0.01至50毫巴。