公开(公告)号：US08557934B2

公开(公告)日：2013-10-15

申请号：US13000064

申请日：2009-07-02

申请人： Kazutaka Takeno ,  Toshiya Ohkubo ,  Kunio Naoi ,  Mitsugu Tsuruta

发明人： Kazutaka Takeno ,  Toshiya Ohkubo ,  Kunio Naoi ,  Mitsugu Tsuruta

IPC分类号： C08F246/00 ,  C08L101/14

CPC分类号： C09D113/02 ,  C08F236/04 ,  C08F255/08 ,  C08F257/00 ,  C08F265/04 ,  C08F265/08 ,  C08L13/02 ,  C09D5/02 ,  C09D151/04 ,  C08F2/22 ,  C08F220/44 ,  C08F236/06 ,  C08F220/06 ,  C08F212/08 ,  C08F220/14 ,  C08F220/26 ,  C08L2666/02

摘要： Disclosed is a copolymer latex obtained by emulsion polymerization of a monomer mixture containing (a) 30-70% by mass of a conjugated diene monomer, (b) 0.1-15% by mass of an ethylenically unsaturated carboxylic acid monomer and (c) 15-69.9% by mass of one or more other copolymerizable monomers. The copolymer latex is characterized in that the toluene in-soluble content in the dried product obtained by drying the copolymer latex is 95-100% by mass; the mass ratio of the toluene-swollen toluene insoluble content to the dried toluene insoluble content (the toluene swelling degree) is 3.0-6.5; the number average particle diameter of the copolymer latex is 180-400 nm; and the glass transition starting temperature of the dried copolymer latex is within the range from −70° C. to −20° C. and the glass transition ending temperature thereof is within the range from 10° C. to 100° C. in differential scanning calorimetry.

摘要翻译： 公开了通过将（a）30〜70质量％的共轭二烯单体，（b）0.1〜15质量％的烯属不饱和羧酸单体和（c）15 -69.9质量％的一种或多种其它可共聚单体。 共聚物胶乳的特征在于，通过干燥该共聚物胶乳获得的干燥产物中的甲苯溶解度为95〜100质量％ 甲苯溶胀甲苯不溶成分与干燥甲苯不溶成分质量比（甲苯溶胀度）为3.0-6.5; 共聚物胶乳的数均粒径为180-400nm; 干燥的共聚物胶乳的玻璃化转变起始温度在-70℃至-20℃的范围内，玻璃化转变终止温度在10℃至100℃的范围内 扫描量热法。

公开(公告)号：US20110092630A1

公开(公告)日：2011-04-21

申请号：US13000064

申请日：2009-07-02

申请人： Kazutaka Takeno ,  Toshiya Ohkubo ,  Kunio Naoi ,  Mitsugu Tsuruta

发明人： Kazutaka Takeno ,  Toshiya Ohkubo ,  Kunio Naoi ,  Mitsugu Tsuruta

IPC分类号： C09D109/10

CPC分类号： C09D113/02 ,  C08F236/04 ,  C08F255/08 ,  C08F257/00 ,  C08F265/04 ,  C08F265/08 ,  C08L13/02 ,  C09D5/02 ,  C09D151/04 ,  C08F2/22 ,  C08F220/44 ,  C08F236/06 ,  C08F220/06 ,  C08F212/08 ,  C08F220/14 ,  C08F220/26 ,  C08L2666/02

摘要： Disclosed is a copolymer latex obtained by emulsion polymerization of a monomer mixture containing (a) 30-70% by mass of a conjugated diene monomer, (b) 0.1-15% by mass of an ethylenically unsaturated carboxylic acid monomer and (c) 15-69.9% by mass of one or more other copolymerizable monomers. The copolymer latex is characterized in that the toluene in-soluble content in the dried product obtained by drying the copolymer latex is 95-100% by mass; the mass ratio of the toluene-swollen toluene insoluble content to the dried toluene insoluble content (the toluene swelling degree) is 3.0-6.5; the number average particle diameter of the copolymer latex is 180-400 nm; and the glass transition starting temperature of the dried copolymer latex is within the range from −70° C. to −20° C. and the glass transition ending temperature thereof is within the range from 10° C. to 100° C. in differential scanning calorimetry.

摘要翻译： 公开了通过将（a）30〜70质量％的共轭二烯单体，（b）0.1〜15质量％的烯属不饱和羧酸单体和（c）15 -69.9质量％的一种或多种其它可共聚单体。 共聚物胶乳的特征在于，通过干燥该共聚物胶乳获得的干燥产物中的甲苯溶解度为95〜100质量％ 甲苯溶胀甲苯不溶成分与干燥甲苯不溶成分质量比（甲苯溶胀度）为3.0-6.5; 共聚物胶乳的数均粒径为180-400nm; 干燥的共聚物胶乳的玻璃化转变起始温度在-70℃至-20℃的范围内，玻璃化转变终止温度在10℃至100℃的范围内 扫描量热法。