公开(公告)号：US5585517A

公开(公告)日：1996-12-17

申请号：US420386

申请日：1995-04-12

Applicant: Ted Deisenroth ,  Robert Falk ,  Juerg Haase

Inventor： Ted Deisenroth ,  Robert Falk ,  Juerg Haase

IPC: C07C17/275 ,  C07C41/30 ,  C07C43/178 ,  C07C319/20 ,  C07C323/12 ,  C07C323/14 ,  C07F13/00 ,  C07C59/295

CPC classification number: C07C17/275 ,  C07C319/20 ,  C07C41/30

Abstract: A novel process is described for reacting a perfluoroalkyl iodide with an olefinic compound, which comprises carrying out a free-radical addition reaction of the perfluoroalkyl iodide to the olefin in the presence of azoic or peroxy initiator and a water-soluble salt selected from the group consisting of sulfites, bisulfites, metabisulfites and dithionites. The adducts are obtained in high yield and purity and are useful for the preparation of oil- and water repellent products for use on paper, textiles, metal, wood and the like, or as precursors for fluorinated surfactants.

Abstract translation: 描述了用于使全氟烷基碘与烯烃化合物反应的新方法，其包括在存在有或没有选自下组的水溶性盐的情况下进行全氟烷基碘与烯烃的自由基加成反应 由亚硫酸盐，亚硫酸氢盐，偏亚硫酸氢盐和连二亚硫酸盐组成。 以高产率和纯度获得加合物，可用于制备用于纸，纺织品，金属，木材等的防油和防水产品，或用作氟化表面活性剂的前体。