公开(公告)号：US4182747A

公开(公告)日：1980-01-08

申请号：US862594

申请日：1977-12-20

Applicant: Guy Gravey ,  Jean Le Goff ,  Christian Gonin

Inventor： Guy Gravey ,  Jean Le Goff ,  Christian Gonin

IPC: C01G31/00 ,  C01F7/56 ,  C01F7/60 ,  C01G1/06 ,  C01G31/04 ,  C01G39/04 ,  C01G51/08 ,  C01G53/08 ,  C01G53/09 ,  C01B9/02

CPC classification number: C01G53/09 ,  C01G1/06 ,  C01G31/04 ,  C01G39/04 ,  C01G51/08

Abstract: A process is disclosed for recovering metallic constituents of spent or waste catalysts containing metallic compounds fixed on an aluminous support. The process is particularly applicable for the recovery of metals such as Al, Mo, V, Ni and Co, contained in spent catalyst. The process comprises transforming the metals to be recovered into volatile chlorides by carbochlorination and then separating the chlorides obtained by dry means and fixing them successively in a selective manner. The separation of AlCl.sub.3 is accomplished by passage through granules of anhydrous NaCl, and the separation of MoCl.sub.5 by passage through granules of crystallized KCl. The process is particularly suitable for the treatment of waste catalyst from the catalytic hydrocracking or hydrodesulfurization of oils.

Abstract translation: 公开了一种用于回收含有固定在铝基载体上的金属化合物的废催化剂或废催化剂的金属成分的方法。 该方法特别适用于废催化剂中所含的Al，Mo，V，Ni和Co等金属的回收。 该方法包括通过碳氯化将待回收的金属转化成挥发性氯化物，然后分离通过干法获得的氯化物并以选择性方式连续固定。 AlCl3的分离是通过通过无水NaCl的颗粒和通过结晶的KCl颗粒分离MoCl 5来实现的。 该方法特别适用于从油的催化加氢裂化或加氢脱硫处理废催化剂。