公开(公告)号：US4013793A

公开(公告)日：1977-03-22

申请号：US571881

申请日：1975-04-25

申请人： Shigeo Kishino ,  Akio Kudamatsu ,  Iwao Takase ,  Kozo Shiokawa ,  Shin-ichi Yamaguchi

发明人： Shigeo Kishino ,  Akio Kudamatsu ,  Iwao Takase ,  Kozo Shiokawa ,  Shin-ichi Yamaguchi

IPC分类号： A01N57/14 ,  C07F9/18 ,  A01N9/36

CPC分类号： C07F9/18 ,  A01N57/14

摘要： O-ethyl-S-n-propyl-dithiophosphoric acid phenyl or naphthyl esters, i.e. O-ethyl-S-n-propyl-O- or S-optionally substituted phenyl or naphthyl-phosphorothionothiol- or dithiolates, of the formula ##STR1## in which X is an oxygen or sulfur atom, andZ is a group of the formula ##STR2## Y is a halogen atom or a lower alkyl, lower alkoxy, lower alkylmercapto, lower alkylsufinyl, nitro, cyano or phenyl group, andm is 0, 1, 2 or 3,Which possess insecticidal, acaricidal and nematocidal properties.

公开(公告)号：US5304261A

公开(公告)日：1994-04-19

申请号：US913468

申请日：1992-07-15

申请人： Nobukazu Yamamoto ,  Kouichi Matsumoto ,  Junjiro Nakajima ,  Hideo Maki ,  Hiromasa Hirakawa ,  Masahisa Inagaki ,  Iwao Takase ,  Nobuhiro Okazaki ,  Hideaki Ishizaki ,  Toraki Sakuma

发明人： Nobukazu Yamamoto ,  Kouichi Matsumoto ,  Junjiro Nakajima ,  Hideo Maki ,  Hiromasa Hirakawa ,  Masahisa Inagaki ,  Iwao Takase ,  Nobuhiro Okazaki ,  Hideaki Ishizaki ,  Toraki Sakuma

IPC分类号： C22F1/00 ,  C22F1/18 ,  C23F1/02 ,  G21C3/324 ,  G21C21/00

CPC分类号： G21C3/324 ,  C23F1/02 ,  G21Y2002/103 ,  G21Y2002/302 ,  G21Y2004/201 ,  G21Y2004/40 ,  Y02E30/40

摘要： In a method of fabricating a channel box for use in a nuclear reactor, Zr-alloy sheet material is formed into a tubular channel box. The method includes solution heat treatment of the Zr-alloy sheet material including quenching from a temperature at which .beta.-phase is present. After the solution heat treatment, portions of the Zr-alloy sheet are thinned relative to other portions by a non-stressing thinning process, such as chemical etching in a bath. The corrosion resistance imparted by heat treatment is retained, and the heat treatment itself is easily performed on material of uniform thickness.

摘要翻译： 在制造用于核反应堆的通道箱的方法中，将Zr合金板材形成为管状通道箱。 该方法包括：从存在（β）相的温度淬火的Zr合金片材的固溶热处理。 在固溶热处理之后，通过非应力变薄处理，例如在浴中的化学蚀刻，Zr合金板的部分相对于其它部分变薄。 通过热处理赋予的耐腐蚀性得到保持，并且易于对厚度均匀的材料进行热处理。

公开(公告)号：US4842814A

公开(公告)日：1989-06-27

申请号：US9477

申请日：1987-02-02

申请人： Iwao Takase ,  Masahisa Inagaki ,  Masayoshi Kanno ,  Toshimi Yoshida ,  Jiro Kuniya ,  Isao Masaoka ,  Tetsuo Yasuda ,  Hajime Umehara ,  Hideo Maki

发明人： Iwao Takase ,  Masahisa Inagaki ,  Masayoshi Kanno ,  Toshimi Yoshida ,  Jiro Kuniya ,  Isao Masaoka ,  Tetsuo Yasuda ,  Hajime Umehara ,  Hideo Maki

IPC分类号： G21C3/32 ,  G21C3/34

CPC分类号： G21C3/34 ,  G21C3/32 ,  Y02E30/40

摘要： A channel box and/or a spacer of a fuel assembly is a welded construction and made of a Zr-Nb-Sn alloy comprising 0.5-2.2 wt % Nb, 0.5-1.5 wt % Sn contained so as to satisfy the relation of Sn(wt %) 22.times.Nb(wt %)--3.0, and balance Zr or a Zr-Nb-Sn-Mo alloy comprising 0.5-2.2 wt % Nb, 0.5-1.5 wt % Sn contained so as to satisfy the relation of Sn(wt %).gtoreq.2.times.Nb(wt %)--0.3, 0.1-0.8 wt % Mo, and balance Zr. The welded portion, its heat affected zone and the unwelded portion of the channel box and/or the spacer have substantially the whole equilibrium phase structure.

摘要翻译： 燃料组件的通道箱和/或间隔件是焊接结构，由包含0.5-2.2重量％Nb，0.5-1.5重量％Sn的Zr-Nb-Sn合金制成，以满足Sn（ 重量％）22×Nb（重量％）-3.0，余量包含0.5-2.2重量％Nb，0.5-1.5重量％Sn的Zr或Zr-Nb-Sn-Mo合金，以满足Sn（wt％）的关系， ）> / = 2xNb（wt％）-0.3,0.1-0.8wt％Mo，余量为Zr。 焊接部分，其热影响区和通道箱和/或间隔件的未焊接部分具有基本上全部的平衡相结构。

公开(公告)号：US4689091A

公开(公告)日：1987-08-25

申请号：US704208

申请日：1985-02-22

申请人： Toshimi Yoshida ,  Hideo Maki ,  Hajime Umehara ,  Tetsuo Yasuda ,  Isao Masaoka ,  Iwao Takase ,  Masahisa Inagaki ,  Ryutarou Jimbow ,  Keiichi Kuniya

发明人： Toshimi Yoshida ,  Hideo Maki ,  Hajime Umehara ,  Tetsuo Yasuda ,  Isao Masaoka ,  Iwao Takase ,  Masahisa Inagaki ,  Ryutarou Jimbow ,  Keiichi Kuniya

IPC分类号： C22F1/18 ,  C21D8/00

CPC分类号： C22F1/186 ,  Y10S376/90

摘要： In a process for producing a zirconium-based alloy in which after the zirconium-based alloy is subjected to hot plastic working, it is subjected to cold plastic working and then to annealing and these steps are repeated at least twice, the present invention provides a process for producing a zirconium-based alloy characterized in that after the alloy is subjected to solid solution treatment in which it is heated to a temperature within the range including the .alpha. phase and the .beta. phase of the alloy, or within the range of the .beta. phase and is then quenched, cold plastic working is effected at least twice.

公开(公告)号：US5862194A

公开(公告)日：1999-01-19

申请号：US814337

申请日：1997-03-11

申请人： Tadashi Fujieda ,  Masahisa Inagaki ,  Iwao Takase ,  Junjiro Nakajima ,  Rinichi Asano ,  Takehiro Seto

发明人： Tadashi Fujieda ,  Masahisa Inagaki ,  Iwao Takase ,  Junjiro Nakajima ,  Rinichi Asano ,  Takehiro Seto

IPC分类号： C22C16/00 ,  C22F1/18 ,  G21C3/07 ,  G21C3/324 ,  C22F1/16

CPC分类号： C22C16/00 ,  C22F1/186 ,  G21C3/07 ,  G21Y2004/10 ,  Y02E30/40

摘要： The present invention provides a zirconium based alloy member which has very small deformation of elongation and bow occurring due to irradiation growth, a method of manufacturing it, and particularly an channel box for an atomic reactor fuel assembly. A zirconium based alloy plate member having a width of not less than 100 mm and a long length, containing not more than 5 wt % Nb and/or not more 5 wt % Sn, the member having (0001) orientation (Fl value) of hexagonal Zr with respect to longitudinal direction ranging from 0.20 to 0.35, the difference in Fl between the middle and the end being not more than the value calculated from (0.0935.times.Fl-0.00585) and an amount of bow at neutron irradiation of 35 GWd/t which bow occurs in the channel box for a reactor being not more than 2.16 mm.

摘要翻译： 本发明提供一种锆基合金构件，其由于照射生长而具有非常小的伸长变形和弓形，其制造方法，特别是用于原子反应堆燃料组件的通道箱。 一种宽度不小于100mm，长度不大于5重量％的Nb和/或不多于5重量％Sn的锆基合金板构件，具有（0001）取向（F1值）为 相对于纵向为0.20〜0.35的六方晶相，中间和末端之间的F1的差不大于由（0.0935xFl-0.00585）计算的值，中子照射下的弓的量为35GWd / t 在弯道出现弯道不大于2.16mm的反应堆。

公开(公告)号：US5225154A

公开(公告)日：1993-07-06

申请号：US391316

申请日：1989-08-02

申请人： Masayoshi Kanno ,  Masahisa Inagaki ,  Iwao Takase ,  Jiro Kuniya ,  Akira Maru ,  Tetsuro Yasuda ,  Hideo Maki

发明人： Masayoshi Kanno ,  Masahisa Inagaki ,  Iwao Takase ,  Jiro Kuniya ,  Akira Maru ,  Tetsuro Yasuda ,  Hideo Maki

IPC分类号： G21C3/07 ,  G21C3/20 ,  G21C3/30 ,  G21C3/34 ,  G21C3/356

CPC分类号： G21C3/34 ,  G21C3/07 ,  G21C3/20 ,  G21Y2002/102 ,  G21Y2002/103 ,  G21Y2002/104 ,  G21Y2004/10 ,  G21Y2004/201 ,  G21Y2004/202 ,  G21Y2004/30 ,  Y02E30/40

摘要： A fuel assembly for a nuclear reactor comprising a fuel cladding tube of three-layer structure having an outer surface in contact with reactor water of the nuclear reactor, an inner surface layer in contact with the nuclear fuel, and an intermediate layer interposed between the outer surface layer and the inner surface layer. the outer surface layer is made of a Zr-based alloy containing Nb, Sn and Mo. The inner surface layer is made of pure zirconium. The intermediate layer is made of a high ductility alloy which is higher in ductility than the outer surface layer and is higher in strength than the inner surface layer.

公开(公告)号：US4718949A

公开(公告)日：1988-01-12

申请号：US915555

申请日：1986-10-06

申请人： Iwao Takase ,  Toshimi Yoshida ,  Shinzo Ikeda ,  Isao Masaoka ,  Junjiro Nakajima

发明人： Iwao Takase ,  Toshimi Yoshida ,  Shinzo Ikeda ,  Isao Masaoka ,  Junjiro Nakajima

IPC分类号： C22C16/00 ,  C22F1/18 ,  G21C3/06 ,  G21C3/07

CPC分类号： G21C3/07 ,  Y02E30/40 ,  Y10S376/90

摘要： A method of producing cladding tube comprises a step of temperature-gradient annealing in which the inner surface of the tube is heated to a temperature higher than the recrystallization temperature thereof, while the outer surface of the tube is cooled, after the tube has been hot-extruded. The temperature-gradient annealing is effected while a temperature gradient is maintained between the inner surface and the outer surface of the cladding tube. While keeping the inner surface at a temperature higher than the recrystallization temperature, and the outer surface at a temperature lower than the recrystallization temperature. The cladding tube is obtained with the outer surface which has an excellent resistance to nodular corrosion and a soft inner surface which has an excellent resistance to stress corrosion cracking.

摘要翻译： 制造包层管的方法包括将管的内表面加热到高于其再结晶温度的温度的温度梯度退火步骤，同时管的外表面被冷却后，管被热 - 挤压。 在包覆管的内表面和外表面之间保持温度梯度的同时进行温度梯度退火。 同时将内表面保持在比再结晶温度高的温度，而外表面在低于再结晶温度的温度下。 获得具有优异的抗结块腐蚀性的外表面和具有优异的耐应力腐蚀开裂性的软内表面的包覆管。

公开(公告)号：US3947529A

公开(公告)日：1976-03-30

申请号：US471082

申请日：1974-05-17

申请人： Shigeo Kishino ,  Akio Kudamatsu ,  Iwao Takase ,  Kozo Shiokawa ,  Shin-Ichi Yamaguchi

发明人： Shigeo Kishino ,  Akio Kudamatsu ,  Iwao Takase ,  Kozo Shiokawa ,  Shin-Ichi Yamaguchi

IPC分类号： C07F9/18 ,  A01N9/36 ,  C07F9/12

CPC分类号： C07F9/18

摘要： O-ethyl-S-n-propyl-dithiophosphoric acid phenyl or naphthyl esters, i.e. O-ethyl-S-n-propyl-O- or S- optionally substituted phenyl or naphthyl-phosphorothionothiol-- or dithiolates, of the formula ##EQU1## in which X is an oxygen or sulfur atom, andZ is a group of the formula ##SPC1##Y is a halogen atom or a lower alkyl, lower alkoxy, lower alkylmercapto, lower alkylsulfinyl, nitro, cyano or phenyl group, andm is 0, 1, 2 or 3, which possess insecticidal, acaricidal and nematocidal properties.

摘要翻译： O-乙基-S-丙基 - 二硫代磷酸苯基或萘基酯，即O-乙基-S-丙基-O-或S-任选取代的苯基或萘基 - 硫代硫代硫代或二硫醇化物，其具有式S C2H5O（I）ANGLE PXZ nC 3H7S，其中X是氧或硫原子，Z是式Y的基团是卤素原子或低级烷基，低级烷氧基，低级烷基巯基，低级烷基亚磺酰基，硝基，氰基或苯基，M IS 0，1，2或3，哪些杀虫剂，杀虫剂和杀虫剂属性。

公开(公告)号：US5872826A

公开(公告)日：1999-02-16

申请号：US882335

申请日：1997-06-25

申请人： Tadashi Fujieda ,  Masahisa Inagaki ,  Iwao Takase ,  Yoshitaka Nishino ,  Junichi Yamashita ,  Akihiro Yamanaka ,  Kenichi Ito ,  Junjiro Nakajima ,  Takehiro Seto

发明人： Tadashi Fujieda ,  Masahisa Inagaki ,  Iwao Takase ,  Yoshitaka Nishino ,  Junichi Yamashita ,  Akihiro Yamanaka ,  Kenichi Ito ,  Junjiro Nakajima ,  Takehiro Seto

IPC分类号： G21C3/30 ,  G21C3/324 ,  G21C3/326 ,  G21C3/62 ,  G21C7/04

CPC分类号： G21C3/324 ,  G21C7/04 ,  G21Y2002/103 ,  G21Y2002/302 ,  G21Y2002/304 ,  G21Y2004/20 ,  G21Y2004/30 ,  G21Y2004/40 ,  Y02E30/39

摘要： A channel box for a nuclear-reactor fuel assembly (MOX fuel assembly) containing plutonium, capable of properly controlling the excess reactivity without mixing neutron absorber or burnable poison into a fuel rod, and a channel box for a nuclear-reactor fuel assembly which does not form any gap between the channel box and members containing burnable poison in the channel box and in which the burnable poison does not directly contact with reactor water.

摘要翻译： 用于含有钚的核反应堆燃料组件（MOX燃料组件）的通道箱，能够适当地控制过量反应性而不将中子吸收剂或可燃毒物混入燃料棒中，以及用于核反应堆燃料组件的通道箱 通道箱和通道箱中含有可燃毒物的物质之间不会形成任何间隙，其中可燃毒物不直接与反应堆水接触。

公开(公告)号：US5223211A

公开(公告)日：1993-06-29

申请号：US799151

申请日：1991-11-27

申请人： Masahisa Inagaki ,  Masayoshi Kanno ,  Iwao Takase ,  Toshitaka Kida ,  Noriyuki Ohnaka

发明人： Masahisa Inagaki ,  Masayoshi Kanno ,  Iwao Takase ,  Toshitaka Kida ,  Noriyuki Ohnaka

IPC分类号： C22C16/00 ,  C22F1/00 ,  C22F1/18 ,  G21C3/07 ,  G21C3/30 ,  G21C3/324

CPC分类号： C22F1/186 ,  G21C3/07 ,  G21Y2002/102 ,  G21Y2002/104 ,  G21Y2002/303 ,  G21Y2004/10 ,  G21Y2004/201 ,  G21Y2004/40 ,  Y02E30/40 ,  Y10S376/90

摘要： A zirconium based alloy plate of low irradiation growth, containing not more than 5 wt % Sn and/or not more 5 wt % Nb, and the balance Zr of not less than 90 wt %. The alloy plate has a texture that orientation (Fr value) with respect to direction perpendicular to the surface of the plate ranges from 0.20 to 0.50. This alloy plate is effective in being used to form a fuel channel box. Also a fuel assembly using this channel box is provided in which the crystal orientation of the zirconium alloy is made random by a heat treatment. Specifically, by the heat treatment, the Fr, Ft, and Fl values thereof are set to 0.25 to 0.50, 0.25 to 0.36, and 0.25 to 0.36, respectively.