公开(公告)号：US08017713B2

公开(公告)日：2011-09-13

申请号：US12304791

申请日：2007-03-29

申请人： Kazuyuki Takahashi ,  Ryuuji Uchimura ,  Toshiyuki Hamano ,  Masaaki Miyamoto ,  Kodama Miyamoto, legal representative ,  Taro Miyamoto, legal representative ,  Hideo Miyamoto, legal representative ,  Hanae Miyamoto, legal representative

发明人： Kazuyuki Takahashi ,  Ryuuji Uchimura ,  Toshiyuki Hamano ,  Masaaki Miyamoto

IPC分类号： C08G63/00 ,  C08G63/02

CPC分类号： C08G64/205 ,  C08G64/307

摘要： An apparatus of a polycarbonate resin having polymerization tanks is provided. In supplying a molten reactant to a liquid phase in a polymerization tank, or supplying the molten reactant to a gas phase in the polymerization tank by an insertion pipe, in at least one polymerization tank, and/or producing a polycarbonate resin by an ester exchange reaction between an aromatic dihydroxy compound and a carbonic diester by using three vertical polymerization tanks and one horizontal polymerization tank, a wall surface temperature T of a distillation pipe is set higher than a boiling point t1 of by-produced phenol such that the relationship of the boiling point t1 of the by-produced phenol under a pressure in at least a third vertical polymerization tank, the wall surface temperature T of the distillation pipe and an inner temperature t2 of the third vertical polymerization tank satisfies t1

摘要翻译： 提供了具有聚合槽的聚碳酸酯树脂的装置。 在熔融反应物供应到聚合槽中的液相时，或者通过插入管，在至少一个聚合槽中将熔融反应物供应到聚合槽中的气相，和/或通过酯交换生产聚碳酸酯树脂 通过使用三个垂直聚合槽和一个卧式聚合槽，芳族二羟基化合物和碳酸二酯之间的反应，将蒸馏管的壁面温度T设定为高于副产物苯酚的沸点t1，使得 在至少第三垂直聚合槽中的压力下副产物苯酚的沸点t1，蒸馏管的壁面温度T和第三垂直聚合槽的内部温度t2满足t1

公开(公告)号：US07999056B2

公开(公告)日：2011-08-16

申请号：US12375136

申请日：2007-05-22

申请人： Ryuuji Uchimura ,  Toshiyuki Hamano ,  Kazuyuki Takahashi ,  Masaaki Miyamoto ,  Kodama Miyamoto, legal representative ,  Taro Miyamoto, legal representative ,  Hideo Miyamoto, legal representative ,  Hanae Miyamoto, legal representative

发明人： Ryuuji Uchimura ,  Toshiyuki Hamano ,  Kazuyuki Takahashi ,  Masaaki Miyamoto

IPC分类号： C08G64/00 ,  C08G63/02

CPC分类号： C08G64/205 ,  B01J19/1856 ,  B01J19/1862 ,  B01J19/20 ,  B01J2219/00083 ,  B01J2219/00094 ,  C08G64/307

摘要： The object of the present invention is to provide a method of producing plural kinds of aromatic polycarbonates by a melt process without changeover loss and quality deterioration. The present invention relates to a production method of an aromatic polycarbonate, comprising supplying a molten mixture of raw materials of an aromatic dihydroxy compound and/or a carbonic diester prepared in the absence of an ester exchange catalyst to polycondensation steps of two lines each equipped with three vertical reactors connected in series and one horizontal reactor, and at the same time, continuously conducting polycondensation reaction in the presence of an ester exchange catalyst.

摘要翻译： 本发明的目的是提供一种通过熔融方法生产多种芳族聚碳酸酯的方法，而不会导致转换损耗和质量劣化。 本发明涉及一种芳族聚碳酸酯的制造方法，其特征在于，将在不存在酯交换催化剂的情况下制备的芳族二羟基化合物和/或碳酸二酯的原料的熔融混合物供给到两个配有 串联连接的三个垂直反应器和一个水平反应器，同时在酯交换催化剂存在下连续进行缩聚反应。