Etherified melamine/formaldehyde condensates having a high solid content and low viscosity
    6.
    发明授权
    Etherified melamine/formaldehyde condensates having a high solid content and low viscosity 有权
    具有高固体含量和低粘度的醚化三聚氰胺/甲醛缩合物

    公开(公告)号:US09039927B2

    公开(公告)日:2015-05-26

    申请号:US12096502

    申请日:2006-12-07

    IPC分类号: C09K3/00 C08F2/00 C08G12/42

    CPC分类号: C08G12/427

    摘要: Process for the preparation of etherified melamine/formaldehyde condensates, in which first a methylolation of melamine with a formaldehyde component in the molar ratio of from 1:6 to 1:15, preferably at a pH of >7, is carried out. This is followed by an etherification of the resulting hydroxymethylation intermediate in the presence of a C1-C20-alkyl, preferably of a C1-C6-alcohol, particularly preferably of a C1-C4-alcohol, at a pH of 9.5 being established before, during and/or after the distillation. According to the invention, a plurality of hydroxymethylation, etherification and distillation steps follow in order to achieve an etherified melamine/formaldehyde condensate which is distinguished by a high degree of hydroxymethylation, a high solids content and a low viscosity.

    摘要翻译: 用于制备醚化的三聚氰胺/甲醛缩合物的方法,其中首先以摩尔比为1:6至1:15,优选pH为> 7的三聚氰胺与甲醛组分的羟甲基化反应。 然后在pH <4.​​5的情况下在所得羟甲基化中间体在C1-C20烷基,优选C1-C6醇,特别优选C1-C4-醇的存在下进行醚化,随后 通过至少一个蒸馏步骤以从体系中除去特别是甲醇,在蒸馏之前,期间和/或之后建立pH> 9.5。 根据本发明,为了实现醚化的三聚氰胺/甲醛缩合物,通过高度羟甲基化,高固体含量和低粘度来区分多个羟甲基化,醚化和蒸馏步骤。