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公开(公告)号:US08101786B2
公开(公告)日:2012-01-24
申请号:US12914595
申请日:2010-10-28
CPC分类号: C01B6/15 , C01B6/19 , C01B35/061
摘要: The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.
摘要翻译: 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时,B-H化合物为B 2 H 6,并且其电还原电位或通过甲酸盐的热解提供还原电位。
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公开(公告)号:US20110105706A1
公开(公告)日:2011-05-05
申请号:US12914595
申请日:2010-10-28
IPC分类号: C08F130/04 , C07F5/02 , C07F7/22
CPC分类号: C01B6/15 , C01B6/19 , C01B35/061
摘要: The reaction of halo-boron compounds (B—X compounds, compounds having one or more boron-halogen bonds) with silanes provides boranes (B—H compounds, compounds having one or more B—H bonds) and halosilanes. Inorganic hydrides, such as surface-bound silane hydrides (Si—H) react with B—X compounds to form B—H compounds and surface-bound halosilanes. The surface bound halosilanes are converted back to surface-bound silanes electrochemically. Halo-boron compounds react with stannanes (tin compounds having a Sn—H bond) to form boranes and halostannanes (tin compounds having a Sn—X bond). The halostannanes are converted back to stannanes electrochemically or by the thermolysis of Sn-formate compounds. When the halo-boron compound is BCl3, the B—H compound is B2H6, and where the reducing potential is provided electrochemically or by the thermolysis of formate.
摘要翻译: 卤代硼化合物(B-X化合物,具有一个或多个硼 - 卤键的化合物)与硅烷的反应提供硼烷(B-H化合物,具有一个或多个B-H键的化合物)和卤代硅烷。 无机氢化物,例如表面结合的硅烷氢化物(Si-H)与B-X化合物反应以形成B-H化合物和表面结合的卤代硅烷。 表面结合的卤代硅烷在电化学上转化回表面结合的硅烷。 卤代硼化合物与锡烷(具有Sn-H键的锡化合物)反应形成硼烷和卤代烷(具有Sn-X键的锡化合物)。 卤代烷腈通过电化学方法或通过Sn-甲酸酯化合物的热解转化回锡烷。 当卤代硼化合物为BCl 3时,B-H化合物为B 2 H 6,并且其还原电位通过电化学方法或通过甲酸盐的热解提供。
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公开(公告)号:US20090318575A1
公开(公告)日:2009-12-24
申请号:US12549021
申请日:2009-08-27
申请人: Bryan S. Pivovar , David L. Thorn
发明人: Bryan S. Pivovar , David L. Thorn
IPC分类号: C08J5/22
CPC分类号: C08G65/40 , C08G79/025 , C08J5/2256
摘要: Anion-conducing polymers and membranes with enhanced stability to aqueous alkali include a polymer backbone with attached sulfonium, phosphazenium, phosphazene, and guanidinium residues. Compositions also with enhanced stability to aqueous alkali include a support embedded with sulfonium, phosphazenium, and guanidinium salts.
摘要翻译: 具有增强的碱水溶液稳定性的阴离子导电聚合物和膜包括具有连接的锍,磷腈鎓,磷腈和胍残基的聚合物主链。 具有增强的碱水溶液稳定性的组合物包括含有锍,磷腈鎓和胍盐的载体。
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公开(公告)号:US20090023845A1
公开(公告)日:2009-01-22
申请号:US12283143
申请日:2008-09-04
申请人: Bryan S. Pivovar , David L. Thorn
发明人: Bryan S. Pivovar , David L. Thorn
CPC分类号: C08G65/40 , C08G79/025 , C08J5/2256
摘要: Anion-conducing polymers and membranes with enhanced stability to aqueous alkali include a polymer backbone with attached sulfonium, phosphazenium, phosphazene, and guanidinium residues. Compositions also with enhanced stability to aqueous alkali include a support embedded with sulfonium, phosphazenium, and guanidinium salts.
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公开(公告)号:US08063111B2
公开(公告)日:2011-11-22
申请号:US12917041
申请日:2010-11-01
申请人: Bryan S. Pivovar , David L. Thorn
发明人: Bryan S. Pivovar , David L. Thorn
CPC分类号: C08G65/40 , C08G79/025 , C08J5/2256
摘要: Anion-conducing polymers and membranes with enhanced stability to aqueous alkali include a polymer backbone with attached sulfonium, phosphazenium, phosphazene, and guanidinium residues. Compositions also with enhanced stability to aqueous alkali include a support embedded with sulfonium, phosphazenium, and guanidinium salts.
摘要翻译: 具有增强的碱水溶液稳定性的阴离子导电聚合物和膜包括具有连接的锍,磷腈鎓,磷腈和胍残基的聚合物主链。 具有增强的碱水溶液稳定性的组合物包括含有锍,磷腈鎓和胍盐的载体。
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公开(公告)号:US20110129411A1
公开(公告)日:2011-06-02
申请号:US12283462
申请日:2008-09-11
IPC分类号: C01B3/02
CPC分类号: C07D235/06 , C07D235/18
摘要: A method and system for storing and evolving hydrogen (H2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.
摘要翻译: 用于储存和演化氢气(H2)的方法和系统采用可被氢化以储存氢气并脱氢以放出氢气的化学化合物。 催化剂降低储存和放出氢气所需的能量。 该方法和系统可以为消耗氢气作为燃料的装置提供氢气。
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公开(公告)号:US07439369B2
公开(公告)日:2008-10-21
申请号:US11152525
申请日:2005-06-10
IPC分类号: C07D235/02
CPC分类号: C07D235/06 , C07D235/18
摘要: A method and system for storing and evolving hydrogen employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.
摘要翻译: 用于储存和演化氢的方法和系统采用可被氢化以储存氢气并脱氢以释放氢的化学化合物。 催化剂降低储存和放出氢气所需的能量。 该方法和系统可以为消耗氢气作为燃料的装置提供氢气。
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公开(公告)号:US08470933B2
公开(公告)日:2013-06-25
申请号:US13042687
申请日:2011-03-08
CPC分类号: C08F136/22 , C08F136/20 , G01M3/12 , G01N31/22 , Y10T442/689
摘要: A coating is used to detect a fluid leak.
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公开(公告)号:US07915047B2
公开(公告)日:2011-03-29
申请号:US11986213
申请日:2007-11-19
IPC分类号: G01N31/22
CPC分类号: C08F136/22 , C08F136/20 , G01M3/12 , G01N31/22 , Y10T442/689
摘要: A coating is used to detect a fluid leak.
摘要翻译: 使用涂层来检测流体泄漏。
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公开(公告)号:US20110046246A1
公开(公告)日:2011-02-24
申请号:US12917041
申请日:2010-11-01
申请人: Bryan S. Pivovar , David L. Thorn
发明人: Bryan S. Pivovar , David L. Thorn
IPC分类号: B01J41/12
CPC分类号: C08G65/40 , C08G79/025 , C08J5/2256
摘要: Anion-conducing polymers and membranes with enhanced stability to aqueous alkali include a polymer backbone with attached sulfonium, phosphazenium, phosphazene, and guanidinium residues. Compositions also with enhanced stability to aqueous alkali include a support embedded with sulfonium, phosphazenium, and guanidinium salts.
摘要翻译: 具有增强的碱水溶液稳定性的阴离子导电聚合物和膜包括具有连接的锍,磷腈鎓,磷腈和胍残基的聚合物主链。 具有增强的碱水溶液稳定性的组合物包括含有锍,磷腈鎓和胍盐的载体。
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