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1.发明授权Glycerol ester-free functionalized vegetable oil derivatives and their latex compounds 失效不含甘油酯的官能化植物油衍生物及其胶乳化合物公开(公告)号：US08450414B2
公开(公告)日：2013-05-28
申请号：US12331115
申请日：2008-12-09
IPC分类号： C08F2/22
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 脂肪酰胺（甲基）丙烯酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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公开(公告)号：US07999030B2
公开(公告)日：2011-08-16
申请号：US11345653
申请日：2006-02-01
IPC分类号： C08L37/00
CPC分类号： C09D5/02 , C08H3/00 , C08L91/00 , C09D191/00
摘要： An ethylenically unsaturated vegetable oil is modified by the addition of an enophile or dienophile having an acid, ester or anhydride functionality. The modified vegetable oil is then reacted with a polyethylene glycol (PEG) derivative along with a functional vinyl monomer or a polyethylene glycol derivative that contains a vinyl functionality to form a vegetable oil derivative. The vegetable oil derivative is useful in forming latexes and coatings.
摘要翻译： 烯属不饱和植物油通过加入具有酸，酯或酸酐官能团的亲合子或亲二烯体来改变。 然后将改性植物油与聚乙二醇（PEG）衍生物一起与功能性乙烯基单体或含有乙烯基官能团的聚乙二醇衍生物反应形成植物油衍生物。 植物油衍生物可用于形成胶乳和涂料。
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3.发明申请Glycerol ester-free functionalized vegetable oil derivatives and their latex compositions 审中-公开不含甘油酯的官能化植物油衍生物及其胶乳组成公开(公告)号：US20080183000A1
公开(公告)日：2008-07-31
申请号：US11699693
申请日：2007-01-30
IPC分类号： C07C237/02 , C11B1/10
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl(meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide(meth)acrylate monomer. The increased hydrophilicity of the fatty amide(meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 脂肪酰胺（甲基）丙烯酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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4.发明申请Glycerol Ester-Free Functionalized Vegetable Oil Derivatives and Their Latex Compounds 失效甘油无酯官能化植物油衍生物及其胶乳化合物公开(公告)号：US20090143527A1
公开(公告)日：2009-06-04
申请号：US12331115
申请日：2008-12-09
IPC分类号： C08F2/32
CPC分类号： C07C271/24 , C08L33/02 , C08L77/08 , C09D133/02 , C09D177/08 , C08L2666/04 , C08L2666/20
摘要： The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.
摘要翻译： 本发明涉及脂肪酰胺（甲基）丙烯酸酯单体，制备单体的方法和包含脂肪酰胺（甲基）丙烯酸酯单体的胶乳聚合物。 单体是通过使不饱和植物油与乙醇胺或取代的乙醇胺反应得到的。 然后将植物油衍生物与（甲基）丙烯酰氯或（甲基）丙烯酸反应形成脂肪酰胺（甲基）丙烯酸酯单体或与异佛尔酮二异氰酸酯反应的羟乙基（甲基）丙烯酸酯反应形成氨基甲酸酯 （甲基）丙烯酸脂肪酸酯单体。 脂肪酰胺（甲基）丙烯酸酯单体的增加的亲水性促进了通过水相的扩散。 单体合成设计为无甘油酯，以增加单体和聚合物的长期稳定性。
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5.发明申请公开(公告)号：US20060211795A1
公开(公告)日：2006-09-21
申请号：US11345653
申请日：2006-02-01
申请人： Shelby Thames , James Rawlins , David Delatte , Sandipan Dutta
发明人： Shelby Thames , James Rawlins , David Delatte , Sandipan Dutta
IPC分类号： C08K5/15
CPC分类号： C09D5/02 , C08H3/00 , C08L91/00 , C09D191/00
摘要： An ethylenically unsaturated vegetable oil is modified by the addition of an enophile or dienophile having an acid, ester or anhydride functionality. The modified vegetable oil is then reacted with a polyethylene glycol (PEG) derivative along with a functional vinyl monomer or a polyethylene glycol derivative that contains a vinyl functionality to form a vegetable oil derivative. The vegetable oil derivative is useful in forming latexes and coatings.
摘要翻译： 烯属不饱和植物油通过加入具有酸，酯或酸酐官能团的亲合子或亲二烯体来改变。 然后将改性植物油与聚乙二醇（PEG）衍生物一起与功能性乙烯基单体或含有乙烯基官能团的聚乙二醇衍生物反应形成植物油衍生物。 植物油衍生物可用于形成胶乳和涂料。
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