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公开(公告)号：US06444862B1
公开(公告)日：2002-09-03
申请号：US09580107
申请日：2000-05-30
IPC分类号： C07C3130
摘要： A method for synthesizing highly soluble metal alkoxides includes the step of reacting a tertiary alcohol having the formula: wherein R1, R2, and R3 are, independently, the same or different, an alkyl group, an alkenyl, an alkynyl group or an aryl group, and at least one of R1, R2, and R3 is a group of at least 3 carbon atoms, with at least a stoichiometric amount of a metal reagent. The metal reagent is generally a group I metal, a group II metal, zinc, a metal alloy of a group I metal, a metal alloy of a group II metal, a metal alloy of zinc, a compound of a group I metal, a compound of a group II metal or a compound of zinc.
摘要翻译： 合成高度可溶性金属醇盐的方法包括使具有下式的叔醇反应的步骤：其中R1，R2和R3独立地相同或不同，为烷基，烯基，炔基或芳基 ，R 1，R 2和R 3中的至少一个为至少3个碳原子的基团，至少具有化学计量量的金属试剂。 金属试剂通常为I族金属，II族金属，锌，I族金属的金属合金，II族金属的金属合金，锌的金属合金，I族金属的化合物， II族金属或锌化合物的化合物。
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公开(公告)号：US06221331B1
公开(公告)日：2001-04-24
申请号：US09490982
申请日：2000-01-24
IPC分类号： C01B604
摘要： A synthetic route for forming lithium trisubstituted borohydride compounds comprises the step of reacting a processed lithium hydride reactant with a trisubstituted borane wherein the reaction is maintained for a period of time in a temperature range of approximately 15° C. to approximately 42° C. A method of synthesizing LiH comprises the step of reacting an alkyl lithium (for example, n-butyl lithium) with hydrogen in the presence of tetrahydrofuran. The reaction temperature is preferably maintained in the range of approximately −78° C. to approximately 25° C.
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3.发明授权公开(公告)号：US08013189B2
公开(公告)日：2011-09-06
申请号：US11859377
申请日：2007-09-21
IPC分类号： C07C209/30 , C07C209/24 , C07C29/136
CPC分类号： C07C29/147 , C07C29/143 , C07C209/48 , C07C209/50 , C07C209/52 , C07C31/12 , C07C33/22
摘要： In a process for the accelerated reduction of organic substrates, selected from the group consisting of esters, amides, nitriles, acids, ketones, imines or mixtures thereof, they are reacted with an amine borane, sulfide borane or ether borane complex as a borane source in the presence of organic accelerator compounds containing either Lewis acidic or Lewis basic sites in their structure, of which the Lewis acidic site can coordinate with the carbonyl or nitrile or imine group of the substrate or the Lewis basic site can coordinate with the borane.
摘要翻译： 在加速还原有机底物的方法中，选自酯，酰胺，腈，酸，酮，亚胺或其混合物，它们与胺硼烷，硫化硼烷或醚硼烷络合物作为硼烷源反应 在其结构中含有路易斯酸性或路易斯碱性位点的有机促进剂化合物的存在下，其中路易斯酸性位点可以与底物的羰基或腈或亚胺基团或路易斯碱性位点配位，可与硼烷配位。
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4.发明申请公开(公告)号：US20090082599A1
公开(公告)日：2009-03-26
申请号：US11859377
申请日：2007-09-21
IPC分类号： C07C209/30 , C07C209/24 , C07C29/136
CPC分类号： C07C29/147 , C07C29/143 , C07C209/48 , C07C209/50 , C07C209/52 , C07C31/12 , C07C33/22
摘要： In a process for the accelerated reduction of organic substrates, selected from the group consisting of esters, amides, nitriles, acids, ketones, imines or mixtures thereof, they are reacted with an amine borane, sulfide borane or ether borane complex as a borane source in the presence of organic accelerator compounds containing either Lewis acidic or Lewis basic sites in their structure, of which the Lewis acidic site can coordinate with the carbonyl or nitrile or imine group of the substrate or the Lewis basic site can coordinate with the borane.
摘要翻译： 在加速还原有机底物的方法中，选自酯，酰胺，腈，酸，酮，亚胺或其混合物，它们与胺硼烷，硫化硼烷或醚硼烷络合物作为硼烷源反应 在其结构中含有路易斯酸性或路易斯碱性位点的有机促进剂化合物的存在下，其中路易斯酸性位点可以与底物的羰基或腈或亚胺基团或路易斯碱性位点配位，可与硼烷配位。
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5.发明授权Method of synthesis of lithium substituted borohydride reagents and method of synthesis of reactive lithium hydride 有权锂取代硼氢化物试剂的合成方法和反应性氢化锂的合成方法公开(公告)号：US06268537B1
公开(公告)日：2001-07-31
申请号：US09318415
申请日：1999-05-25
IPC分类号： C07F502
摘要： A synthetic route for forming lithium trisubstituted borohydride compounds comprises the step of reacting a processed lithium hydride reactant with a trisubstituted borane wherein the reaction is maintained for a period of time in a temperature range of approximately 15° C. to approximately 42° C. A method of synthesizing LiH comprises the step of reacting an alkyl lithium (for example, n-butyl lithium) with hydrogen in the presence of tetrahydrofuran. The reaction temperature is preferably maintained in the range of approximately −78° C. to approximately 25° C.
摘要翻译： 用于形成锂三取代硼氢化物化合物的合成路线包括将加工的氢化锂反应物与三取代的硼烷反应的步骤，其中反应在约15℃至约42℃的温度范围内保持一段时间。 合成LiH的方法包括在四氢呋喃存在下使烷基锂（例如正丁基锂）与氢反应的步骤。 反应温度优选保持在约-78℃至约25℃的范围内
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