-
1.发明授权Thiuram disulphides containing phosphate or phosphonate functional groups, their preparation and their use in the manufacture of fireproofing vinyl polymers 失效含有磷酸盐或磷酸盐功能团的硫脲磺酸盐，其制备及其在制备聚烯烃聚合物中的应用
公开(公告)号：US5200545A
公开(公告)日：1993-04-06
申请号：US582897
申请日：1990-12-03
Applicant: Gilbert Clouet , C. P. Reghunadhan Nair
Inventor： Gilbert Clouet , C. P. Reghunadhan Nair
CPC classification number: C08F2/38 , C07F9/2458
Abstract: This compound (I) is prepared by reaction of a compound (II) with carbon disulphide in the presence of an oxidizing agent. It can be used as an agent performing the triple function of initiator, chain transfer agent and termination agent in the radical polymerization of vinyl monomers. The .alpha.,.omega.-difunctional vinyl oligomers and polymers thus obtained are fireproofing polymers or polymers which can be employed as additives in the preparation of fireproofing polymers. They can also be employed to manufacture block polymers by condensation of their end functional groups in the presence of at least one other functional oligomer or polymer, these block polymers also being fireproofing polymers. ##STR1## R.sub.1, R.sub.2 =especially C.sub.1 -C.sub.12 alkyl optionally interrupted by --0--or, ##STR2## cycloalkyl, aryl, --Y--R.sub.4 (Y=single bond, --0-- or --NR.sub.5); R.sub.4 =phosphate or phosphonate functional group; at least one of R.sub.1 and R.sub.2 consisting of or carrying at least one phosphate or phosphonate functional group.
Abstract translation: PCT No.PCT / FR89 / 00172 Sec。 371日期1990年12月3日第 102（e）1990年12月3日PCT PCT 1989年4月17日提交PCT。 出版物WO89 / 10371 该化合物（I）通过化合物（II）与二硫化碳在氧化剂存在下反应来制备。 在乙烯基单体的自由基聚合中，它可以用作起始剂，链转移剂和终止剂三重功能的试剂。 由此获得的α，ω-二官能乙烯基低聚物和聚合物是可用作防火聚合物制备中的添加剂的防火聚合物或聚合物。 它们也可用于通过在至少一种其它功能低聚物或聚合物的存在下通过其末端官能团的缩合制备嵌段聚合物，这些嵌段聚合物也是防火聚合物。 R1，R2 =特别是C1-C12烷基，任选地被-O-或环烷基，芳基，-Y-R 4（Y =单键，-O-或-NR 5）中断， ; R4 =磷酸酯或膦酸酯官能团; R1和R2中的至少一个由至少一个磷酸酯或膦酸酯官能团组成或携带至少一个磷酸酯或膦酸酯官能团
Search Results
1
records
(took 0.012 seconds)
