Abstract:
A solvent for non-aqueous electrolytic solution of lithium secondary battery including a non-fluorine-containing cyclic carbonate (I), a non-fluorine-containing chain carbonate (II) and 1,2-dialkyl-1,2-difluoroethylene carbonate (III). When the total amount of (I), (II) and (III) is taken as 100% by volume, the non-fluorine-containing cyclic carbonate (I) is contained in an amount of 10 to 50% by volume, the non-fluorine-containing chain carbonate (II) is contained in an amount of 49.9 to 89.9% by volume and the 1,2-dialkyl-1,2-difluoroethylene carbonate (III) is contained in an amount of not less than 0.1% by volume and less than 30% by volume. A non-aqueous electrolytic solution including the above-mentioned solvent and a lithium secondary battery using the non-aqueous electrolytic solution are also disclosed.
Abstract:
A power generation complex plant has a control switch, an overall control unit and a steam bypass facility. The overall control unit determines that a desired steam volume has reached a limit value of the volume of steam to be generated by a steam generating facility. A steam bypass facility control unit adds a bias value B1 to a control command value V4 of the steam bypass facility to generate a new control command value V5 when the desired steam volume is determined to have reached the limit value. The steam bypass facility control unit then controls the volume and pressure of steam passing through the steam bypass facility on the basis of the new control command value V5 so that no switch of control may be made in the control switch.
Abstract:
The present invention provides a lithium ion secondary cell excellent in high-temperature storage characteristics and high voltage cycle characteristics; and a nonaqueous electrolyte for the cell.The present invention relates to a lithium ion secondary cell, comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte containing nonaqueous solvents and an electrolyte salt, the nonaqueous solvents comprising a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2 (1) wherein Rf1 and Rf2 are the same as or different from each other, each being a C1-10 alkyl group or a C1-10 fluoroalkyl group; and at least one of Rf1 and Rf2 is a fluoroalkyl group, and the following compounds (I) and (II): (I) a fluorine-containing unsaturated compound; and (II) a hydroxy group-containing compound represented by the formula (2): Rf1OH (2) wherein Rf1 is the same as above, and the nonaqueous solvents comprising the compounds (I) and (II) in a total amount of 5000 ppm or less for the fluorine-containing ether.
Abstract:
The present invention aims to provide an electrochemical device excellent in high temperature storage characteristics and cycling characteristics at high voltages, and a nonaqueous electrolyte for the electrochemical device. The present invention relates to an electrochemical device including: a positive electrode; a negative electrode; and a nonaqueous electrolyte containing a nonaqueous solvent and an electrolyte salt, wherein the nonaqueous solvent contains a fluorinated linear carbonate represented by the formula (1): RfOCOOR (1) (wherein Rf represents a C1-4 fluorinated alkyl group and R represents a C1-4 alkyl group), and further contains following compounds of (I) to (III) in a total amount of not more than 5000 ppm relative to the fluorinated linear carbonate: (I) a compound represented by the formula (2) RfOH (2) (wherein Rf is defined as above); (II) a compound represented by the formula (3) ROH (3) (wherein R is defined as above); and (III) a compound represented by the formula (4) ROCOCl (4) (wherein R is defined as above).
Abstract:
The present invention aims to provide an electrochemical device excellent in high temperature storage characteristics and cycling characteristics at high voltages, and a nonaqueous electrolyte for the electrochemical device. The present invention relates to an electrochemical device including: a positive electrode; a negative electrode; and a nonaqueous electrolyte containing a nonaqueous solvent and an electrolyte salt, wherein the nonaqueous solvent contains a fluorinated linear carbonate represented by the formula (1): RfOCOOR (1) (wherein Rf represents a C1-4 fluorinated alkyl group and R represents a C1-4 alkyl group), and further contains following compounds of (I) to (III) in a total amount of not more than 5000 ppm relative to the fluorinated linear carbonate: (I) a compound represented by the formula (2) RfOH (2) (wherein Rf is defined as above); (II) a compound represented by the formula (3) ROH (3) (wherein R is defined as above); and (III) a compound represented by the formula (4) ROCOCl (4) (wherein R is defined as above).
Abstract:
The present invention provides a lithium ion secondary cell excellent in high-temperature storage characteristics and high voltage cycle characteristics; and a nonaqueous electrolyte for the cell.The present invention relates to a lithium ion secondary cell, comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte containing nonaqueous solvents and an electrolyte salt, the nonaqueous solvents comprising a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2 (1) wherein Rf1 and Rf2 are the same as or different from each other, each being a C1-10 alkyl group or a C1-10 fluoroalkyl group; and at least one of Rf1 and Rf2 is a fluoroalkyl group, and the following compounds (I) and (II): (I) a fluorine-containing unsaturated compound; and (II) a hydroxy group-containing compound represented by the formula (2): Rf1OH (2) wherein Rf1 is the same as above, and the nonaqueous solvents comprising the compounds (I) and (II) in a total amount of 5000 ppm or less for the fluorine-containing ether.
Abstract:
The present invention provides a solvent for a nonaqueous electrolyte solution enabling a lithium secondary battery to exhibit an excellent discharge capacity, load characteristics, and cycle characteristics even under high voltages, as well as a nonaqueous electrolyte solution that uses this solvent and a lithium secondary battery. This solvent for a nonaqueous electrolyte solution is a solvent for a nonaqueous electrolyte solution for a lithium secondary battery, wherein the solvent for a nonaqueous electrolyte solution contains a fluorine-free cyclic carbonate (I), a fluorine-free chain carbonate (II), and a 1,1-di(fluorinated alkyl)ethylene carbonate (III), and wherein with a sum of (I), (II), and (III) being 100 volume %, the fluorine-free cyclic carbonate (I) is 10 to 50 volume %, the fluorine-free chain carbonate (II) is 49.9 to 89.9 volume %, and the 1,1-di(fluorinated alkyl)ethylene carbonate (III) is from at least 0.1 volume % to not more than 30 volume %.
Abstract:
The present invention directs to a non-aqueous electrolyte solution, including (I) at least one compound selected from the group consisting of fluorinated linear sulfones and fluorinated linear sulfonic acid esters, and (II) an electrolyte salt. Such a non-aqueous electrolyte solution has high oxidation resistance, minimizes its decomposition even when hydrofluoric acid is produced. Also, the solution is less likely to cause, in the case of being used for a secondary cell, swelling of the cell and lowering of the battery performance.
Abstract:
A power generation complex plant has a control switch, an overall control unit and a steam bypass facility. The overall control unit determines that a desired steam volume has reached a limit value of the volume of steam to be generated by a steam generating facility. A steam bypass facility control unit adds a bias value B1 to a control command value V4 of the steam bypass facility to generate a new control command value V5 when the desired steam volume is determined to have reached the limit value. The steam bypass facility control unit then controls the volume and pressure of steam passing through the steam bypass facility on the basis of the new control command value V5 so that no switch of control may be made in the control switch.
Abstract:
In accordance with an embodiment, a plant control apparatus includes a deviation calculation unit, a velocity-type PID calculation unit, a plurality of integral calculation units, a plurality of overwrite units, and an automatic balance unit. The deviation calculation unit calculates a deviation between a process value from a plant with operation terminals and a set value corresponding to a control object, and generates a deviation signal. The velocity-type PID calculation unit generates a velocity-type operation amount command signal corresponding to the deviation. The integral calculation units generate position command signals as defined operation terminal position command signals. The overwrite units generate additional position command signals to perform overwrite processing and newly define operation terminal position command signals. The automatic balance unit calculates a deviation between the defined operation terminal position command signals, corrects the operation amount command signal and supplies the corrected operation amount command signal.