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公开(公告)号:US5126019A
公开(公告)日:1992-06-30
申请号:US655847
申请日:1991-02-15
摘要: This invention relates to methods and systems for purifying brine for electrolysis in chlor-alkali cells, especially membrane cells by reducing the sulfate ion concentration, while at the same time minimizing the concentration of other undesireable ions such as calcium and chlorate. The methods and systems employed are unique combinations of refrigeration and crystalization, and brine recirculation techniques in the systems for electrolyzing brine.
摘要翻译: 本发明涉及通过降低硫酸根离子浓度来净化氯碱细胞,特别是膜细胞中的电解盐水的方法和系统,同时使其它不需要的离子如钙和氯酸盐的浓度最小化。 所采用的方法和系统是制冷和结晶的独特组合,以及用于电解盐水的系统中的盐水再循环技术。
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公开(公告)号:US4459188A
公开(公告)日:1984-07-10
申请号:US417396
申请日:1982-09-13
摘要: This invention relates to a new and novel brine system for use in electrolyzing salt to chlorine, caustic soda and hydrogen in chlor-alkali cells employing an ion exchange membrane and, more particularly, to the efficient use of brine as the raw material to be electrolyzed in chlor-alkali membrane cells. This invention also relates to a process for the conversion of a diaphragm cell and evaporator plant to one employing membrane type cells while still utilizing the existing brine treatment and caustic evaporation equipment and the resultant plant installations.
摘要翻译: 本发明涉及一种新型和新型的盐水系统,用于使用离子交换膜在氯碱池中电解氯,苛性钠和氢气中的盐,特别是有效利用盐水作为电解原料 在氯碱膜细胞中。 本发明还涉及一种将隔膜电池和蒸发器设备转换为采用膜式电池的方法,同时仍利用现有的盐水处理和苛性蒸发设备以及所得的设备安装。
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公开(公告)号:US4596490A
公开(公告)日:1986-06-24
申请号:US589942
申请日:1984-03-15
IPC分类号: B65G5/00
CPC分类号: B65G5/00
摘要: This invention relates to a new and novel method for the underground storage of fluid materials including those which are readily soluable or reactive with water or brine such as concentrated caustic soda, ethylene dichloride or anhydrous ammonia within chambers developed in salt formations via solution mining and from which essentially all the brine has been removed; and the chambers thereby produced. More particularly this invention relates to methods for making underground storage chambers; of recovering the brine formed in the making of the chamber; isolating the contaminants, i.e., the insolubles mixed with brine resulting from the solution mining of the storage chamber, such that fluids soluable or reactive with water or brine can be stored therein; and also to a method for controlling the velocity of free fall of materials injected into the chamber for storage, such that erosion of the equipment employed is minimized.
摘要翻译: 本发明涉及一种用于地下储存流体材料的新颖和新颖的方法,包括那些易于溶解或与水或盐水反应的物质,例如通过溶液开采在盐层中开发的室内的浓缩苛性钠,二氯乙烷或无水氨, 其中基本上所有的盐水已被去除; 并由此产生室。 更具体地说,本发明涉及制作地下储藏室的方法; 回收在制造室中形成的盐水; 分离污染物,即与储存室的溶液开采产生的盐水混合的不溶物,使得可溶解或与水或盐水反应的流体可以储存在其中; 并且还涉及一种用于控制注入到室中用于储存的材料的自由下落速度的方法,使得所使用的设备的侵蚀最小化。
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公开(公告)号:US4186803A
公开(公告)日:1980-02-05
申请号:US938033
申请日:1978-08-30
申请人: Thomas C. Mondshine
发明人: Thomas C. Mondshine
IPC分类号: C09K8/08 , C09K8/20 , C09K8/50 , C09K8/504 , E21B33/138
CPC分类号: C09K8/206 , C09K8/08 , C09K8/203 , C09K8/50 , C09K8/5045 , C09K2208/18
摘要: A nondamaging work over and completion fluid having water soluble bridging agents includes a saturated brine solution having at least one water soluble salt which is insoluble in the saturated brine solution and having particle size range of about 5 microns to about 800 microns and wherein greater than about 5% of the particles are coarser than 44 microns. Viscosifier and suspension additive is added to provide the desired viscosity and assist in maintaining the water soluble sized salt suspended in the saturated brine solution. If desired or necessary a fluid loss control agent may be added to enhance the fluid loss control or filtration control of the completion fluid.The invention may be practiced by pumping or discharging the fluid or a slug or pill of the fluid into an oil, gas, water, injection or storage well where operations are to be conducted in which it is desired to temporarily plug the permeable zone while such operations are carried out. Thereafter, the water soluble bridging agents are removed by connate water from the permeable zone, or a nonsaturated brine wash, or ordinary water circulated in the well.
摘要翻译: 具有水溶性桥连剂的非破坏性工作和完成液包括具有至少一种不溶于饱和盐水溶液并具有约5微米至约800微米的粒度范围的至少一种水溶性盐的饱和盐水溶液,其中大于约 5%的颗粒比44微米粗。 加入粘度计和悬浮添加剂以提供所需的粘度,并有助于保持悬浮在饱和盐水溶液中的水溶性大小的盐。 如果需要或需要,可以加入流体损失控制剂以增强完成流体的流体损失控制或过滤控制。 本发明可以通过将流体或流体的液体或药丸泵送或排出到油,气体,水,注射或储存井中来实施,其中要进行的操作是要暂时堵塞可渗透区域, 执行操作。 此后,水溶性桥连剂通过合适的水从可渗透区域,或非饱和盐水洗涤物或在井中循环的普通水来除去。
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公开(公告)号:US5690820A
公开(公告)日:1997-11-25
申请号:US797880
申请日:1997-02-10
CPC分类号: C01D3/06 , Y10S210/912
摘要: This invention relates to methods, systems and apparatus for producing primary treated brine, i.e.
摘要翻译: 本发明涉及用于生产初级处理过的盐水的方法,系统和设备,即在以前的溶液开采操作下,通过其盐含量的消耗而形成的地下盐穴的井口,即<20ppm的钙,镁,锶和钡离子。 生产的纯化盐水保持在厌氧状态,并运送到氯碱设备中,用于生产氯,氢氧化钠和氢气的电解池。 在经营的盐水井口产生的原盐水与净化原盐水所需的处理化学品一起注入耗尽的盐穴。 提供了一种包括生产井或井的小型装置,耗尽的井洞或洞穴,以及用于生产初级处理的盐水的支持设施。 此外,采用特殊的井口注射管,用于将流体注入洞穴的混合器和径向分配器,其允许化学反应,沉淀,沉降和澄清操作发生在洞穴中的预先选择的反应区域中。 该沉积物用作沉淀反应器,沉淀器和澄清池以及用于储存沉淀物的沉积位点,这些沉淀物是纯化过程的无害固体副产物。 与其他地下尝试净化盐水相比,本发明的方法,系统,装置和设备与地表盐水处理设施和氯碱装置的操作相比,提供环境,投资成本和操作优势。
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公开(公告)号:US5669734A
公开(公告)日:1997-09-23
申请号:US563915
申请日:1995-11-29
CPC分类号: E21B43/281
摘要: A new method for making large underground storage caverns in bedded or domal salt deposits for the storage of fluid materials in areas where solution mining water temperatures are low by a process which significantly reduces the amount of time required to make equivalent sized underground storage caverns and which is economically feasible and friendly to the environment. The process includes the warm water solution mining of the underground salt deposits in a manner which conserves the heat contained in the supernatant brine from the underground cavity and employs this heat as a significant source for warming the water employed in the solution mining operation.
摘要翻译: 一种新的方法,用于通过一个过程大大减少制造等效大小的地下储存洞穴所需的时间,从而在床层或矿物盐沉积物中制造大型地下储存洞穴,以便储存溶液采矿水温低的地区, 在经济上是可行的,对环境友好。 该方法包括以保存地下空腔上清液盐水中所含的热量的方式对地下盐沉积物进行温水溶液开采,并采用这种热量作为在采矿作业中使用的水进行升温的重要来源。
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公开(公告)号:US4192756A
公开(公告)日:1980-03-11
申请号:US960057
申请日:1978-11-13
申请人: Thomas C. Mondshine
发明人: Thomas C. Mondshine
CPC分类号: C01D3/26 , B01J2/30 , Y10S507/925
摘要: Caking of potassium chloride and sodium chloride in the particle size range of 20 mesh and finer is inhibited by adding one or more alkaline earth or multi-valent metal salts of lignosulfonate in an amount by weight within the range of about 1% to about 20% to the potassium chloride or sodium chloride.
摘要翻译: 通过加入一种或多种木质素磺酸盐的碱土金属或多价金属盐,其重量含量在约1%至约20%的范围内,可以抑制粒度范围为20目以上的氯化钾和氯化钠的结晶, 到氯化钾或氯化钠。
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公开(公告)号:US3986964A
公开(公告)日:1976-10-19
申请号:US368568
申请日:1973-06-11
申请人: Cecil M. Smithey
发明人: Cecil M. Smithey
CPC分类号: E21B21/003 , C09K8/203
摘要: A non-damaging well drilling fluid contains a polysaccharide, a lignosulfonate, chrome sulfate, a pH modifier and, preferably, graded calcium carbonate and starch. The fluid is effective to seal off the well bore essentially immediately and is non-damaging in that it causes little permanent plugging of the formation by loss of the drilling fluid solids to the formation.
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公开(公告)号:US5637228A
公开(公告)日:1997-06-10
申请号:US367869
申请日:1995-01-03
CPC分类号: C01D3/06 , Y10S210/912
摘要: This invention relates to methods, systems and apparatus for producing primary treated brine, i.e.
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公开(公告)号:US5366514A
公开(公告)日:1994-11-22
申请号:US998927
申请日:1992-12-30
CPC分类号: B01D1/26 , B01D1/2803 , B01D1/285 , B01D1/2893 , C01D3/06 , C01D3/08 , Y02P20/129 , Y02P20/13
摘要: This invention relates to an evaporative salt plant installation including methods of operation and apparatus which produce high purity salt economically and in high yield comprising the combination of a gas turbine which drives a vapor compressor, whose exhaust gases are used to produce steam to drive a topping steam turbine generator, which in turn generates the electrical energy requirements of the plant, and wherein the discharge vapors from the steam turbine are combined with the discharge vapors from the vapor compressor, which is in turn in combination with a vapor compression evaporator and a purge evaporator, whereby both evaporators produce salt, and where the overhead vapors of the purge evaporator are used in a brine cooled condenser to preheat input cold brine, thereby producing water condensate which is recovered, along with evaporator steam chest condensate streams, and used in solution mining underground salt, thereby allowing for both the productive use and recovery of substantially all the raw material and energy inputs to the plant, and the friendly environmental operation of the plant.
摘要翻译: 本发明涉及一种蒸发盐植物装置,其包括操作方法和经济地和高收率地产生高纯度盐的装置,包括驱动蒸汽压缩机的燃气轮机的组合,其中废气用于产生蒸汽以驱动顶部 蒸汽涡轮发电机,其又产生设备的电能需求,并且其中来自蒸汽轮机的排出蒸汽与来自蒸汽压缩机的排放蒸汽组合,蒸汽压缩机又与蒸气压缩蒸发器和吹扫 蒸发器,由此两个蒸发器产生盐,并且其中清洗蒸发器的塔顶蒸气用于盐水冷却的冷凝器中以预热输入的冷盐水,从而产生回收的水冷凝物以及蒸发器蒸汽胸部冷凝物流,并用于溶液 挖掘地下盐,从而允许生产性利用和恢复 基本上所有的原材料和能源输入到工厂,以及工厂的友好环境运行。
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