Halogenated polymer compositions stabilized with the aid of an inorganic
additive
    82.
    发明授权
    Halogenated polymer compositions stabilized with the aid of an inorganic additive 失效
    无机添加剂稳定的氢化聚合物组合物

    公开(公告)号:US5234981A

    公开(公告)日:1993-08-10

    申请号:US865510

    申请日:1992-04-09

    CPC classification number: C08K5/098 C08K3/26 C08K5/138

    Abstract: The present invention relates to new stabilized compositions based on halogenated polymers and more specifically on chlorinated polymer. It relates more particularly to stabilized compositions based on chlorinated polymers, which are characterized in that they contain:a) an effective quantity of an organic zinc or cadmium compound,b) an effective quantity of an organic calcium, magnesium, barium or lanthanide compound, andc) an effective quantity of at least one essentially amorphous basic aluminum magnesium carbonate denoted by the formula (I):(MgO).sub.y.Al.sub.2 O.sub.3.(CO.sub.2).sub.x.(H.sub.2 O).sub.z (I).

    Abstract translation: 本发明涉及基于卤化聚合物的新型稳定化组合物,更具体地涉及氯化聚合物。 它更具体地涉及基于氯化聚合物的稳定化组合物,其特征在于它们包含:a)有效量的有机锌或镉化合物,b)有效量的有机钙,镁,钡或镧系元素化合物, 和(c)有效量的由式(I)表示的至少一种基本上无定形的碱式碳酸铝镁:(MgO)y.Al 2 O 3。(CO 2)x。(H 2 O)z(I)。

    Basic metal salts having improved color and stability and vinyl halide
polymers containing same
    85.
    发明授权
    Basic metal salts having improved color and stability and vinyl halide polymers containing same 失效
    具有改善的颜色和稳定性的碱金属盐和含有它们的含卤乙烯的聚合物

    公开(公告)号:US4665117A

    公开(公告)日:1987-05-12

    申请号:US811587

    申请日:1985-12-20

    Inventor: Robert E. Quinn

    CPC classification number: C08K5/138

    Abstract: In accordance with the present invention, it has been found that the color and stability of basic alkali and alkaline earth metal salts prepared from mixtures containing a phenol can be improved by conducting the reaction in the absence of free oxygen and thereafter post-treating the reaction product with at least one compound capable of displacing the hydrogen of the phenolic hydroxyl groups present in the mixture while maintaining oxygen free atmosphere. Generally, the metal salts will be alkaline earth metal salts of phenols such as calcium and barium salts. A preferred example of the compound capable of displacing the hydrogen of the phenolic hydroxyl group is an epoxide such as ethylene oxide and propylene oxide.

    Abstract translation: 根据本发明,已经发现,通过在不存在游离氧的情况下进行反应,然后后处理反应,可以提高由含有苯酚的混合物制备的碱性碱金属和碱土金属盐的颜色和稳定性 产物与至少一种能够置换混合物中存在的酚羟基的氢的化合物同时保持无氧气氛。 通常,金属盐将是酚类的碱土金属盐,例如钙和钡盐。 能够置换酚羟基的氢的化合物的优选实例是环氧化物如环氧乙烷和环氧丙烷。

    Ortho-substituted aryl phosphite additive composition
    87.
    发明授权
    Ortho-substituted aryl phosphite additive composition 失效
    正离子取代的亚磷酸芳基酯添加剂组合物

    公开(公告)号:US4348308A

    公开(公告)日:1982-09-07

    申请号:US226165

    申请日:1981-01-19

    CPC classification number: C08K5/1545 C08K5/098 C08K5/138 C08K5/526

    Abstract: An additive composition for improving the color stability of a vinyl chloride polymer stabilized with environmentally acceptable stabilizers comprises dehydroacetic acid or its Na, K., Li, Mg, Zn, Ba, Ca, Sn, or Sr salt and an organic phosphite having the formula ##STR1## wherein R.sub.1 is a t-butyl or t-amyl group, R.sub.2 is a hydrogen atom or an alkyl group having one to five carbon atoms, R.sub.3 is a hydrogen atom or a methyl group, and each of R.sub.4 and R.sub.5 independently is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, a cycloalkyl group having 5 to 20 carbon atoms, an aryl group having 6 to 12 carbon atoms, or an ether-substituted group having 3 to about 50 carbon atoms and 1 to about 40 ether oxygen atoms.

    Abstract translation: 用于改善用环境可靠稳定剂稳定的氯乙烯聚合物的颜色稳定性的添加剂组合物包括脱氢乙酸或其Na,K,Li,Mg,Zn,Ba,Ca,Sn或Sr盐和具有式 其中R1是叔丁基或叔戊基,R2是氢原子或具有1-5个碳原子的烷基,R3是氢原子或甲基,R4和R5各自独立地是 氢原子,碳原子数1〜18的烷基,碳原子数5〜20的环烷基,碳原子数6〜12的芳基,碳原子数3〜约50的醚取代基,1〜 约40个醚氧原子。

    Anti-yellowing composition
    88.
    发明授权
    Anti-yellowing composition 失效
    抗黄变组合物

    公开(公告)号:US4252698A

    公开(公告)日:1981-02-24

    申请号:US30731

    申请日:1979-04-17

    CPC classification number: C08K5/138 C08K5/07 C08K5/42

    Abstract: An anti-yellowing additive is provided for environmentally acceptable stabilized vinyl chloride polymer compositions from which arsenic, beryllium, cadmium, lead, mercury, and thallium are substantially excluded, comprising at least one overbased sulfonate or phenolate compound of lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, titanium, aluminum, zirconium, or tin, and a 1,3-diketone compound having 5 to 30 carbon atoms, which is a cyclic or open-chain 1,3-diketone or a lithium, sodium, potassium, magnesium, calcium, strontium, barium, zinc, aluminum, tin or zirconium salt thereof.

    Abstract translation: 为环境可接受的稳定的氯乙烯聚合物组合物提供了一种抗黄变添加剂,其中砷,铍,镉,铅,汞和铊基本上被排除在外,包含至少一种锂,钠,钾,镁的高碱性磺酸盐或酚盐化合物 ,钙,锶,钡,锌,钛,铝,锆或锡以及碳原子数为5〜30的1,3-二酮化合物,其为环状或开链1,3-二酮或锂, 钠,钾,镁,钙,锶,钡,锌,铝,锡或锆盐。

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