公开(公告)号：US1445082A

公开(公告)日：1923-02-13

申请号：US47663321

申请日：1921-06-10

Applicant: E C KLIPSTEIN & SONS COMPANY

Inventor： HOWARD JACOBSON BERNARD

IPC: C01F7/58 ,  C01G1/06

CPC classification number: C01F7/58 ,  C01G1/06

公开(公告)号：US1405183A

公开(公告)日：1922-01-31

申请号：US29679219

申请日：1919-05-13

Applicant: STANDARD OIL CO

Inventor： LOUIS BURGESS

IPC: C01F7/58

CPC classification number: C01F7/58

公开(公告)号：US12227417B2

公开(公告)日：2025-02-18

申请号：US16915205

申请日：2020-06-29

Applicant: West Virginia University Research Corporation

Inventor： Alfred H. Stiller

IPC: C01B32/05 ,  B01J19/24 ,  C01B32/184 ,  C01B32/25 ,  C01B32/26 ,  C01B32/36 ,  C01B32/914 ,  C01B32/942 ,  C01F7/58 ,  C01F11/28

Abstract: The disclosure provides for methods of oxidizing carbide anions, or negative ions, from salt like carbides at low temperatures below about 600° C. In another aspect, the disclosure provides for reactions with intermediate transition metal carbides. In yet another aspect, the disclosure provides for a system of reactions where salt-like carbide anions and intermediate carbide anions are oxidized to produce pure carbon of various allotropes.

公开(公告)号：US20200325022A1

公开(公告)日：2020-10-15

申请号：US16915205

申请日：2020-06-29

Applicant: West Virginia University Research Corporation

Inventor： Alfred H. STILLER

IPC: C01B32/05 ,  C01B32/26 ,  C01B32/942 ,  C01B32/914 ,  B01J19/24 ,  C01F11/28 ,  C01F7/58 ,  C01B32/184 ,  C01B32/25 ,  C01B32/36

Abstract: The disclosure provides for methods of oxidizing carbide anions, or negative ions, from salt like carbides at low temperatures below about 600° C. In another aspect, the disclosure provides for reactions with intermediate transition metal carbides. In yet another aspect, the disclosure provides for a system of reactions where salt-like carbide anions and intermediate carbide anions are oxidized to produce pure carbon of various allotropes.

公开(公告)号：US20190119117A1

公开(公告)日：2019-04-25

申请号：US16140060

申请日：2018-09-24

Applicant: WEST VIRGINIA UNIVERSITY RESEARCH CORPORATION

Inventor： Alfred H. STILLER

IPC: C01B32/25 ,  C01B32/36 ,  C01B32/184 ,  C01B32/05 ,  C01B32/942 ,  C01F11/28 ,  C01B32/914 ,  C01B32/26 ,  C01F7/58

Abstract: The disclosure provides for methods of oxidizing carbide anions, or negative ions, from salt like carbides at low temperatures below about 600° C. In another aspect, the disclosure provides for reactions with intermediate transition metal carbides. In yet another aspect, the disclosure provides for a system of reactions where salt-like carbide anions and intermediate carbide anions are oxidized to produce pure carbon of various allotropes.

公开(公告)号：US09701539B2

公开(公告)日：2017-07-11

申请号：US14213533

申请日：2014-03-14

Applicant: West Virginia University Research Corporation

Inventor： Alfred Stiller

IPC: C01F11/28 ,  C01F7/58 ,  C01B31/06 ,  C01B31/02 ,  C01B31/04 ,  C01B31/32

CPC classification number: C01B32/25 ,  C01B32/05 ,  C01B32/184 ,  C01B32/26 ,  C01B32/36 ,  C01B32/914 ,  C01B32/942 ,  C01F7/58 ,  C01F11/28

Abstract: The disclosure provides for methods of oxidizing carbide anions, or negative ions, from salt like carbides at low temperatures below about 600° C. In another aspect, the disclosure provides for reactions with intermediate transition metal carbides. In yet another aspect, the disclosure provides for a system of reactions where salt-like carbide anions and intermediate carbide anions are oxidized to produce pure carbon of various allotropes.

公开(公告)号：US5286473A

公开(公告)日：1994-02-15

申请号：US11740

申请日：1993-02-01

Applicant: Nobuyasu Hasebe ,  Nobukatsu Hasebe

Inventor： Nobuyasu Hasebe ,  Nobukatsu Hasebe

IPC: C01B3/08 ,  C01D1/04 ,  C01D3/04 ,  C01F7/42 ,  C01F7/58 ,  C22B21/00

CPC classification number: C22B21/0069 ,  C01B3/08 ,  C01D1/04 ,  C01D3/04 ,  C01F7/42 ,  C01F7/58 ,  C25C1/02 ,  Y02E60/36 ,  Y02P10/212

Abstract: In accordance with the invention an alkali metal is reacted with an ionizable hydrogen compound selected from the group consisting of hydrochloric acid, water or mixtures thereof to produce hydrogen and an alkali metal chloride or alkali metal hydroxide, depending upon whether hydrochloric acid or water is used to react with the alkali metal. The alkali metal chloride produced directly as a by-product of the hydrogen production step, or subsequently from the alkali metal hydroxide, is heated in the presence of aluminum to produce the alkali metal for reuse in the process and aluminum chloride. The aluminum chloride is hydrolyzed to aluminum hydroxide and hydrochloric acid. The hydrochloric acid can be recycled to produce hydrogen by reaction directly with the alkali metal or can be used to convert the alkali metal hydroxide formed during the hydrogen production step to the alkali metal chloride which can be recycled back into the process. The aluminum hydroxide thus formed can be electrolyzed to aluminum metal and water to provide a method of recovering aluminum metal from aluminum scrap which previously has not be readily recyclable.

Abstract translation: 根据本发明，碱金属与选自盐酸，水或其混合物的可离子化氢化合物反应以产生氢和碱金属氯化物或碱金属氢氧化物，这取决于是使用盐酸还是水 与碱金属反应。 作为氢制造步骤的副产物或随后从碱金属氢氧化物中直接制备的碱金属氯化物在铝的存在下加热以产生碱金属以在该方法中再利用和氯化铝。 将氯化铝水解成氢氧化铝和盐酸。 盐酸可以通过与碱金属直接反应而再生生成氢，也可以用于将在氢气制备步骤中形成的碱金属氢氧化物转化成碱性金属氯化物，其可循环使用。 如此形成的氢氧化铝可以电解为铝金属和水，以提供从铝废料中回收铝金属的方法，其先前不易回收。

公开(公告)号：US4465566A

公开(公告)日：1984-08-14

申请号：US400198

申请日：1982-07-20

Applicant: Raouf O. Loutfy ,  James C. Withers

Inventor： Raouf O. Loutfy ,  James C. Withers

IPC: C01F7/58 ,  C25C3/06

CPC classification number: C25C3/22 ,  C01F7/58

Abstract: An improved process is provided for producing via ACH anhydrous aluminum chloride suitable for electrolytic reduction to aluminum wherein the feed ACH is acid leach derived. In a preferred embodiment the acid leach derived ACH is single stage crystallized.

Abstract translation: 提供了一种改进的方法，用于通过适用于电解还原成铝的ACH无水氯化铝生产，其中进料ACH是酸浸出的。 在优选的实施方案中，酸浸出物ACH是单阶段结晶的。

公开(公告)号：US4434149A

公开(公告)日：1984-02-28

申请号：US412926

申请日：1982-08-30

Applicant: James C. Withers ,  Raouf O. Loutfy

Inventor： James C. Withers ,  Raouf O. Loutfy

IPC: C01F7/58 ,  C01F7/60

CPC classification number: C01F7/58 ,  C01F7/60 ,  Y10S423/12

Abstract: A novel method of activating carbon is provided comprising contacting the carbon with low temperature aluminum chloride acid melts comprising at least 50 mole percent aluminum chloride and less than 50 mole percent of at least one halide salt capable of exhibiting a liquid state at atmospheric conditions, e.g., sodium chloride. Carbon activated according to the present invention is useful as a reductant of the chlorination of aluminous materials to produce anhydrous aluminum chloride.

Abstract translation: 提供了一种活化碳的新方法，包括使碳与低温氯化铝酸熔体接触，所述低熔点氯化铝酸熔体包含至少50摩尔％氯化铝和小于50摩尔％的至少一种能够在大气条件下显示液态的卤化物盐，例如 ， 氯化钠。 根据本发明的活化碳可用作铝材料的氯化还原剂以产生无水氯化铝。

公开(公告)号：US4415412A

公开(公告)日：1983-11-15

申请号：US309655

申请日：1981-10-08

Applicant: George F. Vandegrift ,  Michael Krumpelt ,  E. Philip Horwitz

Inventor： George F. Vandegrift ,  Michael Krumpelt ,  E. Philip Horwitz

IPC: C01F7/00 ,  C01F7/60 ,  C22B3/32 ,  C22B3/38 ,  C25C3/06 ,  C01F7/58

CPC classification number: C22B3/0062 ,  C01F7/00 ,  C01F7/60 ,  C22B3/0024 ,  C22B3/0066 ,  C22B3/0091 ,  C25C3/06 ,  Y02P10/214 ,  Y02P10/234

Abstract: A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

Abstract translation: 一种在多级萃取方法中由水性铝材料如氢氧化铝浆料制备无水氯化铝组合物的方法，其中首先将铝离子萃取到含有酸性萃取剂的有机液体中，然后从有机物萃取 进入碱金属氯化物或氯化物以形成含有碱金属和铝的氯化物的混合物的熔体。 在此过程中，可以循环使用有机液体。 此外，该方法有利地包括用于生产金属铝的电解槽，碱金属氯化物或氯化物可循环用于从有机相中提取铝。